Plasma catalysis in ammonia production and decomposition: Use it, or lose it?

Current Opinion in Green and Sustainable Chemistry, Год журнала: 2024, Номер 47, С. 100916 - 100916

Опубликована: Март 29, 2024

Язык: Английский

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Non-thermal plasma assisted catalytic nitrogen fixation with methane at ambient conditions

Chemical Engineering Journal, Год журнала: 2023, Номер 471, С. 144748 - 144748

Опубликована: Июль 13, 2023

Язык: Английский

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Plasma-assisted ammonia synthesis under mild conditions for hydrogen and electricity storage: Mechanisms, pathways, and application prospects

Frontiers in Energy, Год журнала: 2024, Номер 18(4), С. 418 - 435

Опубликована: Июнь 20, 2024

Язык: Английский

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Plasma for nitrogen fixation by using N₂/O₂ mixture: Reaction pathway, energy flow, and plasma reactor

Plasma Processes and Polymers, Год журнала: 2023, Номер unknown

Опубликована: Окт. 3, 2023

Abstract When N 2 /O mixture is used for nitrogen fixation (NF), researchers believe that the Zeldovich mechanism main pathway NO formation. However, there still debate on whether participates in through vibrational excitation or electronic of (A) state. This ambiguity has led to uncertainty regarding which type plasma can achieve higher efficiency. Furthermore, most significant obstacle plasma‐assisted NF high energy consumption. Gaining a deeper understanding flow discharge process crucial improving efficiency future. Therefore, this paper provides an overview research these topics. Finally, various new devices reported recent years will also be discussed.

Язык: Английский

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Non-thermal plasma catalysis driven sustainable pyrolysis oil upgrading to jet fuel under near-ambient conditions

EES Catalysis, Год журнала: 2024, Номер 2(2), С. 647 - 663

Опубликована: Янв. 1, 2024

The integration of non-thermal plasma with a nanoclustered Ir catalyst achieves an 87% liquid oil yield from pyrolysis oil, showcasing the transformative impact plasma-catalysis synergies in activating methane and cleaving long-chain molecules.

Язык: Английский

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In‐Liquid Plasma Catalysis: Tools for Sustainable H₂‐free Heavy Oils Upgrading

ChemistrySelect, Год журнала: 2024, Номер 9(3)

Опубликована: Янв. 16, 2024

Abstract Non‐thermal plasma (NTP) catalysis, mirroring the trend towards non‐conventional electron‐mediated molecular activation, unfolds novel routes for chemical reactions. Operating at ambient pressure, lower temperatures, and energized by electricity that can powered renewable sources, NTP offers a cost‐effective efficient means of sustainable fuel production. This approach has potential to revolutionize oil gas industry, meeting current energy demands while circumventing challenges posed conventional thermal catalysis processes, thereby enhancing environmental sustainability security. Through an exploration synergistic effects between plasma, hydrocarbon molecules, this concept paper emphasizes significant advancements made in in‐liquid strategies production from heavy upgrading. We also provide insights into heterogeneous catalyst design role as additional achieving solutions. The prospects emphasizing its transformative shaping future, are discussed.

Язык: Английский

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Role of Reducible and Mobile Oxygens in Methane Partial Oxidation Within a Post‐Plasma Catalytic System

ChemistrySelect, Год журнала: 2025, Номер 10(12)

Опубликована: Март 1, 2025

Abstract This study examines methane oxidation in a post‐plasma catalysis (PPC) system. Using dielectric barrier discharge plasma with metal oxide‐supported catalysts (Cu/Al, Ni/Al, Fe/Al, and NaW/Al), the effects of reactant feed type, composition, catalyst oxygen species were evaluated for optimizing plasma‐catalytic performance. Key findings indicate that extended O 2 contact time, reduced CH 4 water addition to feed, use mobile oxygen‐enriched catalyst, is NaW/Al, positively influence extent partial oxidation. Notably, NaW/Al plays role improving yields products (CH 3 OH, HCOH, HCOOH) can be replenished through calcination within PPC

Язык: Английский

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Ammonia Synthesis via Nitrogen-Coupled Methane Conversion at Ambient Temperature and Plasma Conditions

Industrial & Engineering Chemistry Research, Год журнала: 2023, Номер 62(44), С. 18416 - 18426

Опубликована: Окт. 26, 2023

Ammonia synthesis has been coupled with methane conversion under plasma conditions by using Fe–Al composite metal oxides as the catalyst. The process for ammonia production starting from natural gas is thus shortened, and meanwhile, C2 hydrocarbons are generated a byproduct high selectivity. In order to overcome barrier activation of nitrogen, dielectric discharge (DBD) technology used input high-quality energy into reaction system. A thorough examination performance quite few 3d-metal oxides, SiO2, Al2O3 done screen out cheap, promising elements CH4–N2 conversion. Based on these results, oxide selected catalyst prepared hydrothermal method. Under condition SEI (specific input, kJ/L) = 12 kJ/L, CH4/N2 3:1, an optimal Al–Fe ratio 2:1, concentration reaches 1185.86 ppm. Upon further optimization specific feed ratio, 1:3 24 highest 3534.32 rate was 15.71% when kJ/L 1:5. products 1.74% 1:1 kJ/L. this condition, selectivity ethane, ethylene, acetylene, propane, propylene 52.83, 4.37, 2.71, 18.03, 0.59%, respectively. structure characterized XRD, XPS, TGA, BET.

Язык: Английский

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Plasma-Catalyzed Crude Oil Upgrading: A Pathway Toward Carbon-Neutral Solutions

Springer eBooks, Год журнала: 2024, Номер unknown, С. 1 - 36

Опубликована: Янв. 1, 2024

Язык: Английский

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