P(V)-bis(amidophenolate) ligand cooperation: Stoichiometric C=O-bond cleavage in aldehydes and ketones DOI Creative Commons

Simon B. H. Karnbrock,

Christopher Golz, Manuel Alcarazo

и другие.

Chemical Communications, Год журнала: 2024, Номер 60(53), С. 6745 - 6748

Опубликована: Янв. 1, 2024

The cooperation between a geometrically constrained, highly electrophilic phosphorus(V) center, and an electronically rich tetradentate bis(amidophenolate) ligand enables the cleavage of CO bond from typical aldehydes ketones delivering iminio phosphoramidate species. amphiphilic nature these products, which is demonstrated through their reaction with Lewis acids bases, use as mild source silylium cations silanes, allowing selective reductive coupling to ethers under catalytic conditions.

Язык: Английский

Coordination complexes of Bipyridines (CCBs): Chemistry, bonding and applications DOI
Chandrabhan Verma, Ibrahim Y. Yaagoob,

Lipiar K.M.O. Goni

и другие.

Coordination Chemistry Reviews, Год журнала: 2025, Номер 529, С. 216433 - 216433

Опубликована: Янв. 13, 2025

Язык: Английский

Процитировано

3
P(V)-bis(amidophenolate) ligand cooperation: Stoichiometric C=O-bond cleavage in aldehydes and ketones DOI Creative Commons

Simon B. H. Karnbrock,

Christopher Golz, Manuel Alcarazo

и другие.

Chemical Communications, Год журнала: 2024, Номер 60(53), С. 6745 - 6748

Опубликована: Янв. 1, 2024

The cooperation between a geometrically constrained, highly electrophilic phosphorus(V) center, and an electronically rich tetradentate bis(amidophenolate) ligand enables the cleavage of CO bond from typical aldehydes ketones delivering iminio phosphoramidate species. amphiphilic nature these products, which is demonstrated through their reaction with Lewis acids bases, use as mild source silylium cations silanes, allowing selective reductive coupling to ethers under catalytic conditions.

Язык: Английский

Процитировано

0