Going Green: Sustainable Alternatives in Organic Synthesis DOI
Christopher B. Kelly, Jordan S. Compton, Marian C. Bryan

и другие.

Elsevier eBooks, Год журнала: 2024, Номер unknown

Опубликована: Янв. 1, 2024

Язык: Английский

Electrochemical Borylation of C−C and C−Het Bonds DOI Creative Commons
T. Cheung, Hairong Lyu

ChemElectroChem, Год журнала: 2025, Номер unknown

Опубликована: Фев. 19, 2025

Abstract Recently, electrochemical methods have been harnessed as a transition metal‐free strategy for borylation reactions in the synthesis of organoboron compounds. This article reviews C−C and C−Het bonds, offering systematic discussion C−C, C−N, C−O, C−S bond reactions. These transformations are applied to substrates including ammonium salts, aryl azo sulfones, carboxylic acids, arylhydrazines, nitroarenes, alcohols, thioethers, showcasing broad compatibility. Additionally, review discusses reaction mechanisms, scalability, practical applications these strategies. The concludes by outlining future research directions reactions, aiming at expending their incorporating boron into wider array organic compounds, challenging unactivated C−F borylations.

Язык: Английский

Процитировано

0

Photoinduced Electron Donor–Acceptor Complex‐Enabled Transformations Involving Boron‐Containing Compounds DOI

Jianzhong Lu,

Huayong Zhang, Guozhu Zhang

и другие.

ChemPhotoChem, Год журнала: 2025, Номер unknown

Опубликована: Май 25, 2025

Over the past decades, visible‐light‐driven reactions have emerged as a powerful tool in organic synthesis. Unlike traditional photoredox that require additional catalysts or photosensitizers, electron donor–acceptor (EDA) complex‐mediated photochemistry offers simpler and more cost‐effective approach to achieving diverse radical transformations without need for noble catalysts. Among these, use of boron‐containing compounds donors acceptors EDA complexes has garnered significant attention due their unique properties. This review highlights recent advances visible‐light‐induced involving compounds, focusing on applications constructing CC CB bonds elucidating underlying reaction mechanisms.

Язык: Английский

Процитировано

0

Formate‐Mediated Synthesis of β‐Hydroxysulfides from Olefins and Thiosulfonates via EDA Complex Strategy under Visible Light Irradiation in Air DOI

Qing Shen,

Xiaoyan Peng,

Jiahong Sui

и другие.

Chinese Journal of Chemistry, Год журнала: 2024, Номер 42(23), С. 3129 - 3134

Опубликована: Авг. 13, 2024

Comprehensive Summary A visible‐light‐induced and efficient one‐pot synthesis of β ‐hydroxysulfides from olefins, thiosulfonates HCOOCs using an EDA complex strategy under air atmosphere at room temperature has been disclosed. plausible radical involved mechanism is proposed. During the reaction process, formates play a crucial role: first, as donors in complex; second, providers hydrogen source; third, by generating CO 2 •– to reduce peroxide intermediates, leading formation ‐hydroxysulfides. In contrast previously reported thiol‐oxygen co‐oxidation reactions, this simple sustainable approach features mild conditions, operational simplicity, odorless excellent functional group tolerance.

Язык: Английский

Процитировано

3

A Computational Study of Photoinduced Borylation for Selected Boron Sources DOI Creative Commons

Ka Wa Fan,

Hoi Ling Luk, David Lee Phillips

и другие.

ChemistryOpen, Год журнала: 2024, Номер 13(7)

Опубликована: Март 8, 2024

Abstract This research article uses density functional theory (DFT) to study photoinduced borylation. work examined the electron donor‐acceptor complex (EDA) of bis(catecholato)diboron with different redox‐active leaving groups and bis(pinacol)diboron aryl N‐hydroxyphthalimide. The results these DFT studies show ratio B 2 cat N, N‐dimethylacetamide (DMA) should be 1 : which is consistent experimental in literature. We further proposed a reaction mechanism calculated energies associated each step.

Язык: Английский

Процитировано

1

Going Green: Sustainable Alternatives in Organic Synthesis DOI
Christopher B. Kelly, Jordan S. Compton, Marian C. Bryan

и другие.

Elsevier eBooks, Год журнала: 2024, Номер unknown

Опубликована: Янв. 1, 2024

Язык: Английский

Процитировано

0