Photoinduced Electron Donor–Acceptor Complex‐Enabled Transformations Involving Boron‐Containing Compounds DOI

Jianzhong Lu,

Huayong Zhang, Guozhu Zhang

и другие.

ChemPhotoChem, Год журнала: 2025, Номер unknown

Опубликована: Май 25, 2025

Over the past decades, visible‐light‐driven reactions have emerged as a powerful tool in organic synthesis. Unlike traditional photoredox that require additional catalysts or photosensitizers, electron donor–acceptor (EDA) complex‐mediated photochemistry offers simpler and more cost‐effective approach to achieving diverse radical transformations without need for noble catalysts. Among these, use of boron‐containing compounds donors acceptors EDA complexes has garnered significant attention due their unique properties. This review highlights recent advances visible‐light‐induced involving compounds, focusing on applications constructing CC CB bonds elucidating underlying reaction mechanisms.

Язык: Английский

Electron-Donor-Mediated Divergent Transformation of Br–RF via EDA Complex for the Synthesis of Fluorine-Containing Oxindoles and Amides DOI
Shupeng Zhang,

Jin-Xin Lan,

Mei-Ling Yang

и другие.

Organic Letters, Год журнала: 2024, Номер 26(46), С. 9990 - 9995

Опубликована: Ноя. 11, 2024

We have developed an unprecedented electron-donor-controlled divergent reaction between

Язык: Английский

Процитировано

5
Recent Progress in C–S Bond Formation via Electron Donor-Acceptor Photoactivation DOI
Sichang Wang, Liting Wang, Jin Cui

и другие.

Organic & Biomolecular Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

This review summarizes recent progress in EDA complex-promoted C–S bond formation using various sulfur-containing substrates under mild conditions via visible light irradiation.

Язык: Английский

Процитировано

0
Deep-blue emitting 9,10-bis(perfluorobenzyl)anthracene DOI Creative Commons

Long K. San,

Sebastian Balser, Brian J. Reeves

и другие.

Beilstein Journal of Organic Chemistry, Год журнала: 2025, Номер 21, С. 515 - 525

Опубликована: Март 7, 2025

A new deep-blue emitting and highly fluorescent anthracene (ANTH) derivative containing perfluorobenzyl (Bn F ) groups, 9,10-ANTH(Bn 2 , was synthesized in a single step reaction of ANTH or ANTH(Br) with Bn I, using either high-temperature Cu-/Na S O 3 -promoted via room-temperature photochemical reaction. Its structure elucidated by NMR spectroscopy crystal X-ray diffractometry. The latter revealed no π–π interaction between neighboring cores. combination high photoluminescence quantum yield (PLQY) 0.85 for its significantly improved photostability compared to 9,10-ANTH derivatives, simple synthetic access makes it an attractive material as OLED emitter efficient probe.

Язык: Английский

Процитировано

0
Study of tamoxifen derived perfluoroalkylated olefins in breast cancer treatment DOI Creative Commons
Wojciech Chaładaj, María C. Arufe, Fátima Lucio‐Martínez

и другие.

Bioorganic Chemistry, Год журнала: 2025, Номер 161, С. 108525 - 108525

Опубликована: Апрель 25, 2025

Язык: Английский

Процитировано

0
Photoinduced Electron Donor–Acceptor Complex‐Enabled Transformations Involving Boron‐Containing Compounds DOI

Jianzhong Lu,

Huayong Zhang, Guozhu Zhang

и другие.

ChemPhotoChem, Год журнала: 2025, Номер unknown

Опубликована: Май 25, 2025

Over the past decades, visible‐light‐driven reactions have emerged as a powerful tool in organic synthesis. Unlike traditional photoredox that require additional catalysts or photosensitizers, electron donor–acceptor (EDA) complex‐mediated photochemistry offers simpler and more cost‐effective approach to achieving diverse radical transformations without need for noble catalysts. Among these, use of boron‐containing compounds donors acceptors EDA complexes has garnered significant attention due their unique properties. This review highlights recent advances visible‐light‐induced involving compounds, focusing on applications constructing CC CB bonds elucidating underlying reaction mechanisms.

Язык: Английский

Процитировано

0