Enhancing high rate performance of Lithium Titanium Oxide (LTO) anodes: A comprehensive review
A. Kazemi,
Reza Mostaani,
Meysam Karbakhsh Ravari
и другие.
Journal of Power Sources,
Год журнала:
2025,
Номер
630, С. 236051 - 236051
Опубликована: Янв. 8, 2025
Язык: Английский
Bimetal Fluorides with Adjustable Vacancy Concentration Reinforcing Ion Transport in Poly(ethylene oxide) Electrolyte
ACS Nano,
Год журнала:
2024,
Номер
unknown
Опубликована: Сен. 19, 2024
The
poor
ambient
ionic
transport
properties
of
poly(ethylene
oxide)
(PEO)-based
SPEs
can
be
greatly
improved
through
filler
introduction.
Metal
fluorides
are
effective
in
promoting
the
dissociation
lithium
salts
via
establishment
Li-F
bond.
However,
too
strong
interaction
would
impair
fast
migration
ions.
Herein,
magnesium
aluminum
fluoride
(MAF)
fillers
developed.
Experimental
and
simulation
results
reveal
that
bond
strength
could
readily
altered
by
changing
fluorine
vacancy
(V
Язык: Английский
Enhancing Zn Metal Anode Stability via Ti3C2Tx MXene/PEI Composite Coating
Small,
Год журнала:
2025,
Номер
unknown
Опубликована: Май 26, 2025
Abstract
Aqueous
Zn‐ion
batteries
(AZIBs)
are
considered
a
promising
candidate
for
large‐scale
energy
storage
application
owing
to
their
high
capacity,
good
safety,
low
cost,
and
environmental
friendliness.
However,
the
presence
of
active
water
leads
issues
such
as
corrosion,
dendrite
growth
hydrogen
evolution
reaction
on
Zn
metal
anodes,
severely
limiting
cycle
lifetime
reversibility
AZIBs.
To
address
these
challenges,
this
study
introduces
simple
drop‐casting
method
deposit
composite
protective
coating
2D
titanium
carbide
(Ti
3
C
2
T
x
)
MXene
polyethyleneimine
(PEI)
surface
foil,
i.e.,
MXene/PEI@Zn.
The
MXene/PEI
contains
polar
groups
−OH
that
can
regulate
deposition.
Additionally,
prevent
from
directly
contacting
surface.
results
show
MXene/PEI@Zn
anodes
over
2600
1100
h
at
corresponding
current
density
1
5
mA
cm
−2
(Areal
capacity:
mAh
).
When
paired
with
V
O
·1.6H
cathode,
it
contributes
evidently
improved
full‐cell
performance
85%
capacity
retention
after
4800
cycles
A
g
−1
.
This
work
provides
new
insights
into
practical
design
highly
reversible
anodes.
Язык: Английский
Tailoring Ce-Centered Metal–Organic Frameworks for Fast Li+ Transport in Composite Polymer Electrolyte
ACS Applied Materials & Interfaces,
Год журнала:
2024,
Номер
16(45), С. 62052 - 62063
Опубликована: Ноя. 1, 2024
Regulating
metal
nodes
to
innovate
the
metal–organic
framework
(MOF)
structure
is
of
great
interest
boost
performance
MOFs-incorporated
composite
solid
electrolytes.
Herein,
Ce4+
with
a
low-lying
4f
orbital
selected
as
center
coordinate
organic
ligand
prepare
MOF
Ce-UiO-66.
The
unsaturated
open
sites
and
defected
oxygen
vacancies
furnish
Ce-UiO-66
strengthened
Lewis
acidity,
which
promotes
interacting
effectively
both
poly(ethylene
oxide)
(PEO)
Li
salt
anions.
Accordingly,
additive
fillers
can
be
uniformly
dispersed
in
PEO
matrix
form
an
advanced
solid-state
electrolyte
(Ce-UiO@PEO)
accelerated
Li+
transport.
optimized
Ce-UiO@PEO
displays
boosted
ionic
conductivity
4.20
×
10–4
S
cm–1
improved
transference
number
0.39
at
60
°C,
are
highly
comparable
those
other
MOFs@PEO
Combined
mechanical
thermal
stabilities,
such
enables
Li/Li
symmetric
Li/LiFePO4
full
cells
superior
cycling
stability
rate
performance.
electrolytes
potential
applied
high-performance
lithium
batteries.
Язык: Английский