Coupling Plastic Upgrading and Photocatalysis: Catalytic Mechanisms and Design Principles
ACS Catalysis,
Год журнала:
2025,
Номер
unknown, С. 5339 - 5369
Опубликована: Март 17, 2025
Язык: Английский
Unveiling the reaction mechanism of photocatalytic H2 evolution coupled with selective bio-mass monosaccharide upgrading over single palladium atom-engineered carbon-rich graphitic carbon nitride
Journal of Colloid and Interface Science,
Год журнала:
2025,
Номер
686, С. 1055 - 1073
Опубликована: Фев. 6, 2025
Язык: Английский
Unveiling the Synergistic Coupling Between Nickel Phosphide and Graphitic Carbon Nitride for Sustainable Catalytic Transfer Hydrogenation of Quinoline: Ensemble and Ligand Effects
Advanced Sustainable Systems,
Год журнала:
2025,
Номер
unknown
Опубликована: Март 24, 2025
Abstract
In
recent
years,
metal
phosphide
catalysts
have
garnered
immense
attention
among
the
catalysis
community
due
to
their
facile
synthesis
and
excellent
catalytic
activity
but
promising
potential
in
field
of
organic
transformation
is
not
been
fully
explored.
The
synergistic
coupling
between
support
material
plays
a
crucial
role
enhancing
overall
as
well
recovery
catalyst.
Herein,
this
study
reports
nickel
(Ni
2
P)
graphitic
carbon
nitride
(GCN)
nanosheets
an
interfacial
catalyst
for
effective
efficient
transfer
hydrogenation
quinoline.
significance
developed
interface
Ni
P
GCN
revealed
by
detailed
spectroscopic
theoretical
investigations,
which
enhances
dissociation
hydrogen
source
substrate
interaction
with
surface
catalyst,
thereby
selective
quinoline
1,2,3,4‐tetrahydroquinoline.
proposed
protocol
quinoline,
formic
acid
utilized
bio‐renewable
source,
serves
replacement
molecular
hydrogen.
Further,
optimization
studies
are
carried
out
achieve
good
selectivity
product
yield
varying
reaction
parameters.
Therefore,
using
mechanistic
studies,
supported
on
P‐GCN)
provides
Язык: Английский
Ternary AgFe2O4/SBA-16/SO3H Heterojunction Photocatalyst for the Sustainable Production of 5-Hydroxymethylfurfural under Mild Conditions
Langmuir,
Год журнала:
2025,
Номер
unknown
Опубликована: Май 22, 2025
The
use
of
solar
energy
to
convert
biomass
and
its
derivatives
into
high-value
chemicals
has
garnered
significant
interest
as
a
sustainable
alternative
fossil
fuels.
However,
designing
high-performance
photocatalysts
that
can
selectively
catalyze
biobased
molecules
remains
challenge
in
this
field.
In
paper,
we
describe
the
application
ternary
AgFe2O4/SBA-16/SO3H
photocatalyst
photocatalytic
conversion
biomass-derived
sugars
5-hydroxymethylfurfural
(HMF)
using
deep
eutectic
solvents
(DESs)
green
reaction
media
under
visible
light
illumination.
was
prepared
by
facile
sonication
postmodification
method,
crystal
structure,
functional
groups,
surface
morphology,
optical
features
were
analyzed
through
various
characterization
techniques.
influence
numerous
essential
variables
on
production
HMF
from
fructose
over
examined.
ideal
parameters
found
be
20
mg
quantity
100
choline
chloride:glycerol
exposure
white
LED
(9
W)
at
80
°C,
afford
95%
yield
2
h.
recyclability
established
five
consecutive
cycles,
demonstrating
stability.
This
research
provides
an
idea
for
AgFe2O4-based
promising
catalytic
mode
mild
efficient
methodologies.
Язык: Английский
Insight into F-site enhanced interfacial H-bonding interaction and O2 activation for selective biomass photo-upgrading to lactic acid
Chemical Engineering Journal,
Год журнала:
2025,
Номер
unknown, С. 164210 - 164210
Опубликована: Май 1, 2025
Язык: Английский
Catalytic Efficiency of CoMnAl-Layered Double Hydroxide in Solvent-Free Synthesis of C16 Biofuel Precursors from Furfural and Cyclohexanone
Energy & Fuels,
Год журнала:
2025,
Номер
unknown
Опубликована: Июнь 5, 2025
Язык: Английский
Tailoring catalysis at the atomic level: trends and breakthroughs in single atom catalysts for organic transformation reactions
Nanoscale Horizons,
Год журнала:
2024,
Номер
10(3), С. 423 - 459
Опубликована: Дек. 5, 2024
This
review
analyzes
the
latest
advances
in
field
of
design
single
atom
catalysts
(SACs)
for
various
industrially
relevant
organic
transformation
reactions
along
with
challenges
and
their
possible
counter
measures.
Язык: Английский
Titanium Silicate‐1 Coupled with Sn and Er as Effective Catalysts for the Production of Lactic Acid from Saccharides
ChemCatChem,
Год журнала:
2024,
Номер
unknown
Опубликована: Сен. 16, 2024
Abstract
Biomass‐based
saccharide
valorization
to
produce
lactic
acid
(LaA)
via
chemocatalysis
has
emerged
as
a
promising
approach
meet
the
substantial
demand
of
global
LaA
market,
whereas
manufacture
prominent
heterogeneous
catalyst
is
still
challenging.
Herein,
we
fabricate
series
rare
earth
catalysts
and
indicate
that
Er
supported
onto
titanium
silicate‐1
(TS‐1)
exhibits
better
activity
than
other
for
glucose
transformation
towards
LaA.
Remarkably,
coupling
Sn
with
TS‐1
enabled
sharp
increment
yield,
3Sn15Er/TS‐1
outperformed
reported
date,
giving
high
82.2%
76.2%
yields
from
sorbose
glucose,
respectively.
The
characterization
demonstrated
coexistence
2
O
3
7
on
catalyst,
both
which
contributed
production.
doping
favored
formation
active
particles
in
smaller
size
increased
Lewis
acidic
sites
when
compared
single
15Er/TS‐1,
thereby
promoting
isomerization
retro‐aldol
reaction
C
intermediates.
also
showed
universal
diverse
biomass‐based
saccharides.
This
work
might
give
useful
insights
explore
superior
biomass
valorization.
Язык: Английский