Synthesis and Electrochemical Performance Enhancement of Li2MnSiO4 Cathode Material for Lithium‐Ion Batteries via Mn‐Site Ni Doping DOI

Jing Guo,

Xin Yan,

Yuqi Yao

и другие.

Advanced Sustainable Systems, Год журнала: 2024, Номер unknown

Опубликована: Сен. 30, 2024

Abstract In exploring the potential of Li 2 MnSiO 4 as a cathode material for lithium‐ion batteries (LIBs), key challenges often involve enhancing electronic conductivity and diffusion rates. To address these issues, this paper proposes combination solid‐state doping two‐step calcination process to successfully prepare Mn 1−x Ni x SiO series materials, where substitutes at different amounts (x = 0, 0.02, 0.04, 0.06, 0.08). The use chemically equivalent 2+ ions replace is an effective method. Since ionic radius smaller than that , substitution can create more voids in lattice structure. These increased provide smoother channels transport electrons lithium ions, thereby improving material's electrical conductivity. At amount exhibits optimal electrochemical performance, achieving discharge capacity 155 mAh g −1 0.1 C, significantly superior undoped manganese silicate. sites with improves capabilities revealing tremendous strategies optimizing performance LIBs materials.

Язык: Английский

Integrated Lithium-Rich yLi2MnO3∙(1-y)LiNi1/3Co1/3Mn1/3O2 Layered Cathode Nanomaterials for Lithium-ion Batteries DOI Open Access
Ashraf E. Abdel-Ghany,

Rasha S. El-Tawil,

Ahmed M. Hashem

и другие.

International Journal of Molecular Sciences, Год журнала: 2025, Номер 26(3), С. 1346 - 1346

Опубликована: Фев. 5, 2025

Integrated Li- and Mn-rich layered cathodes yLi2MnO3∙(1-y)LiMO2 (M = Mn, Co, Ni) have shown their ability to deliver specific capacities close 300 mAh g−1, but significant drawbacks are capacity fading voltage decay during cycling. In this study, new stoichiometric high-voltage Li-rich oxides with y 0.0, 0.3, 0.5 synthesized in identical conditions using a sol–gel method. These compositions were analyzed determine optimal configuration understand extraordinary behavior. Their nanostructural properties investigated XRD Raman spectroscopy, while the morphology grain-size distribution of samples characterized by BET, SEM HRTEM analyses. The electrochemical performances integrated compounds evaluated through galvanostatic cycling impedance spectroscopy. best cathode material 0.5Li2MnO3∙0.5LiNi1/3Co1/3Mn1/3O2 had retention 83.6% after 100 cycles potential range 2.0–4.8 V vs. Li+/Li.

Язык: Английский

Процитировано

1

Hybrid heterojunction containing rich oxygen vacancies for suppressing lattice oxygen release of Li-rich Mn-based layered oxides cathodes DOI
Huai Chen,

Huachun Si,

Jun Ma

и другие.

Journal of Colloid and Interface Science, Год журнала: 2025, Номер unknown, С. 137392 - 137392

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

1

Surface and Interfacial Modulation of Lithium‐Rich Manganese Layered Oxide Cathode Materials: Progress and Challenges DOI Open Access
Tao Peng,

Yanshuo Zhao,

Qi Liu

и другие.

Small, Год журнала: 2025, Номер unknown

Опубликована: Март 27, 2025

Abstract Exhibiting exceptional energy density and capacity, lithium‐rich manganese‐based layered oxide (LLOs) cathode materials have garnered considerable attention are emerging as strong contenders for future lithium‐ion battery systems. However, the manner in which they employed practice is hindered by several challenges, such voltage fading, exhibiting a low initial coulombic efficiency, suboptimal cycling stability, mainly attributed to oxygen depletion phase transformation phenomena. The current review primarily centers on recent progress addressing these issues through surface interfacial modification techniques, including doping, coating, vacancy engineering. Other strategies, spinel engineering hybrid coating layers, also discussed potential solutions enhance electrochemical performance, capacity retention. Additionally, exploration advancements electrolyte design aimed at stabilizing LLOs/electrolyte interface, reducing side reactions, enabling development of stable solid interphase (CEI). concludes highlighting ongoing particularly improving long‐term proposes prospective research directions further unlocking LLOs practical applications.

Язык: Английский

Процитировано

0

Progress and obstacles in electrode materials for lithium-ion batteries: a journey towards enhanced energy storage efficiency DOI Creative Commons
Rimsha Khalid, Afzal Shah,

Mohsin Javed

и другие.

RSC Advances, Год журнала: 2025, Номер 15(20), С. 15951 - 15998

Опубликована: Янв. 1, 2025

This review critically examines various electrode materials employed in lithium-ion batteries (LIBs) and their impact on battery performance.

Язык: Английский

Процитировано

0

Outlook of Doping Engineering in NMC and LMNO Cathode Materials for Next-Generation Li-Ion Batteries DOI

P. Kumari,

Rajen Kundu

Energy & Fuels, Год журнала: 2025, Номер unknown

Опубликована: Июнь 4, 2025

Язык: Английский

Процитировано

0

Enhanced performance of lithium-ion battery cathodes using a composite conductive network of CNTs, GQDs, and GNRs embedded in Li₁.₂Mn₀.₅₄Ni₀.₁₃Co₀.₁₃O₂ (LMNCO) DOI
Hamid Latif,

Noor Sabah,

Abdul Sattar

и другие.

Journal of Energy Storage, Год журнала: 2024, Номер 106, С. 114823 - 114823

Опубликована: Дек. 4, 2024

Язык: Английский

Процитировано

1

Recent developments strategies in high entropy modified lithium-rich layered oxides cathode for lithium-ion batteries DOI Creative Commons

Samuel O. Ajayi,

Tarekegn Heliso Dolla, Ismaila Taiwo Bello

и другие.

Inorganic Chemistry Communications, Год журнала: 2024, Номер 172, С. 113721 - 113721

Опубликована: Дек. 11, 2024

Язык: Английский

Процитировано

1

Suppression of High Spin State of Mn for the Improvement of Mn‐Based Materials in Rechargeable Batteries DOI

Jean Nguyen,

Youngil Lee, Yang Yang

и другие.

Small, Год журнала: 2024, Номер unknown

Опубликована: Дек. 27, 2024

Abstract Manganese‐based materials are essential for developing safe, cost‐effective, and environmentally sustainable rechargeable batteries, which critical advancing clean energy technologies. However, the high spin state of Mn cation triggers a pronounced Jahn–Teller effect phase transformations during cycling, leading to structural instability reduced electrochemical performance Mn‐based cathodes. This review provides fundamental understanding effect, highlights recent strategies mitigate Mn, offers insights into future research directions aimed at overcoming enhance next‐generation cathodes batteries.

Язык: Английский

Процитировано

1

Synthesis and Electrochemical Performance Enhancement of Li2MnSiO4 Cathode Material for Lithium‐Ion Batteries via Mn‐Site Ni Doping DOI

Jing Guo,

Xin Yan,

Yuqi Yao

и другие.

Advanced Sustainable Systems, Год журнала: 2024, Номер unknown

Опубликована: Сен. 30, 2024

Abstract In exploring the potential of Li 2 MnSiO 4 as a cathode material for lithium‐ion batteries (LIBs), key challenges often involve enhancing electronic conductivity and diffusion rates. To address these issues, this paper proposes combination solid‐state doping two‐step calcination process to successfully prepare Mn 1−x Ni x SiO series materials, where substitutes at different amounts (x = 0, 0.02, 0.04, 0.06, 0.08). The use chemically equivalent 2+ ions replace is an effective method. Since ionic radius smaller than that , substitution can create more voids in lattice structure. These increased provide smoother channels transport electrons lithium ions, thereby improving material's electrical conductivity. At amount exhibits optimal electrochemical performance, achieving discharge capacity 155 mAh g −1 0.1 C, significantly superior undoped manganese silicate. sites with improves capabilities revealing tremendous strategies optimizing performance LIBs materials.

Язык: Английский

Процитировано

0