Cited by A “pre-constrained bimetallic” strategy for the preparation of efficient synergistic electrocatalytic hydrogen evolution catalysts

Hydrated molten salt electrolytes effectively promote electrocatalytic NH3 synthesis at low temperatures DOI

Wenwen Cai, Yuyao Sun, Yanyun Zhang

и другие.

Fuel, Год журнала: 2024, Номер 379, С. 133081 - 133081

Опубликована: Сен. 10, 2024

Язык: Английский

Процитировано

Advanced approach for active and durable proton exchange membrane fuel cells: Coupling synergistic effects of MNC nanocomposites DOI

Yeju Jang,

Seung Yeop Yi,

Jinwoo Lee

и другие.

EcoMat, Год журнала: 2024, Номер 6(10)

Опубликована: Окт. 1, 2024

Abstract Atomically dispersed metal and nitrogen co‐doped carbon (MNC) is a promising oxygen reduction reaction (ORR) catalyst for electrochemical energy storage conversion applications but typically suffers from low durability activity under the acidic conditions of practical polymer electrolyte exchange membrane fuel cells (PEMFCs). Recently, performance MNC nanocomposites ORR has been enhanced by exploiting synergistic coupling effects their constituents (single‐atom sites, nanoclusters, nanoparticles). The unique geometric structures formed diverse sites in these provide optimal electronic efficient pathways, thus resulting high long‐term durability. This work provides an overview as electrocatalysts PEMFC conditions, focusing on enhancement methods highlighting strategies used to prepare electrocatalytically containing no or amounts platinum group metals. Progress development advanced catalysts discussed, pivotal role within explored together with characterization elucidate effects. Finally, challenges prospects developing next‐generation are presented. image

Язык: Английский

Процитировано

2 + 1 > 3: Trimetallic Sites on the Zn-IrP₂/FeP Electrode Trigger Synergistic Effect to Activate Industrial-Grade Performance for Hydrazine-Assisted Overall Water Splitting DOI

Xiaoli Sun, Jie Liu, Yunmei Du

и другие.

ACS Catalysis, Год журнала: 2024, Номер unknown, С. 17421 - 17433

Опубликована: Ноя. 12, 2024

Constructing multifunctional electrodes with high metal utilization by a one-step synthesis strategy is serious challenge. Herein, Zn-IrP2/FeP dual-functional activity induced trimetallic sites are constructed the "one-step phosphorization". Relevant characterizations and DFT calculations reveal that Ir Fe act as HER HzOR sites, respectively, promoting overall hydrazine splitting (OHzS) at industrial-level current. Specially Zn dopant, an auxiliary active site for Ir–Fe dual-active optimizes physical structure, electronic configuration, d-band center, adsorption intermediate capabilities of Zn-IrP2/FeP/IF electrode from multiple perspectives. As expected, only requires 223.0 382.0 mV to drive industrial-grade current density 1 A cm–2 HzOR, respectively. Notably, voltage OHzS reach 500 mA 1.38 V lower than OWS. In summary, exhibit synergetic electrocatalytic functions synergistically maximize efficiency. Moreover, multiactive mechanism dopant innovatively proposed in this work. This presents valuable idea designing multimetal catalysts efficiency in-depth investigation catalytic mechanisms.

Язык: Английский

Процитировано

A “pre-constrained bimetallic” strategy for the preparation of efficient synergistic electrocatalytic hydrogen evolution catalysts DOI

Hong Wu,

Lijie Zhou,

Xueting Song

и другие.

Journal of Alloys and Compounds, Год журнала: 2024, Номер unknown, С. 177834 - 177834

Опубликована: Ноя. 1, 2024

Язык: Английский

Процитировано