Availability of π–Cation Radical in the Oxidative Products of Oxidovanadium Porphyrin: Significance for DNA Binding and Antibacterial Activity DOI
Ijaz Ullah Muzaddadi, Arumugam Murugan, Shankhadeep Saha

и другие.

Applied Organometallic Chemistry, Год журнала: 2024, Номер 38(12)

Опубликована: Авг. 29, 2024

ABSTRACT Oxidovanadium meso ‐tetrakis(3,4,5‐trimethoxyphenyl) porphyrin [VO(T(OMe)3PP)] (Complex 1 ) was prepared. The oxidation product of Complex has been characterized by cyclic voltammetry (CV), UV–visible spectrophotometer, electron paramagnetic resonance (EPR) and nuclear magnetic (NMR) the addition SbCl 5 to . There is a one‐electron in that creates π–cation radicals CV data. This supported an IR spectrophotometer. Subsequent EPR spectra verified initiation monoradical, which subsequently transforms into triplet state where S = 1. DNA binding antibacterial analysis with have also analysed. In DNA‐binding analysis, data confirm interaction between DNA. Furthermore, fact more effective at killing bacteria shows metal ion's chelation ligand makes it lipophilic.

Язык: Английский

The role of corroles in modern cancer therapy: innovation and prospects DOI

Laiba Javaid,

Huma Hameed, Mahtab Ahmad Khan

и другие.

BioMetals, Год журнала: 2025, Номер unknown

Опубликована: Апрель 23, 2025

Язык: Английский

Процитировано

0
Availability of π–Cation Radical in the Oxidative Products of Oxidovanadium Porphyrin: Significance for DNA Binding and Antibacterial Activity DOI
Ijaz Ullah Muzaddadi, Arumugam Murugan, Shankhadeep Saha

и другие.

Applied Organometallic Chemistry, Год журнала: 2024, Номер 38(12)

Опубликована: Авг. 29, 2024

ABSTRACT Oxidovanadium meso ‐tetrakis(3,4,5‐trimethoxyphenyl) porphyrin [VO(T(OMe)3PP)] (Complex 1 ) was prepared. The oxidation product of Complex has been characterized by cyclic voltammetry (CV), UV–visible spectrophotometer, electron paramagnetic resonance (EPR) and nuclear magnetic (NMR) the addition SbCl 5 to . There is a one‐electron in that creates π–cation radicals CV data. This supported an IR spectrophotometer. Subsequent EPR spectra verified initiation monoradical, which subsequently transforms into triplet state where S = 1. DNA binding antibacterial analysis with have also analysed. In DNA‐binding analysis, data confirm interaction between DNA. Furthermore, fact more effective at killing bacteria shows metal ion's chelation ligand makes it lipophilic.

Язык: Английский

Процитировано

1