Elsevier eBooks, Год журнала: 2024, Номер unknown, С. 91 - 149
Опубликована: Авг. 16, 2024
Язык: Английский
Elsevier eBooks, Год журнала: 2024, Номер unknown, С. 91 - 149
Опубликована: Авг. 16, 2024
Язык: Английский
Research Square (Research Square), Год журнала: 2024, Номер unknown
Опубликована: Фев. 1, 2024
Язык: Английский
Процитировано
0European Journal of Organic Chemistry, Год журнала: 2024, Номер 27(20)
Опубликована: Март 20, 2024
Abstract Cyclopropylmethyl sulfides react with N ‐fluorosulfonimide (NFSI) or molecular iodine, enabling C−S cleavage to generate cyclopropylcarbinyl cations, which evolve through cyclopropane ring‐opening reactions into homoallyl cations suitable nucleophiles present in the reaction media. This desulfurative of cyclopropylmethyl thioethers under non‐acidic conditions facilitates homoallylation ‐based such as alkyl aryl amines well sulfonimides a one‐pot protocol one two steps depending on nucleophile. The is initiated by halogen‐sulfur bond that causes cleavage. Moreover, iodine proceeds iodide intermediates.
Язык: Английский
Процитировано
0Inorganic Chemistry Frontiers, Год журнала: 2024, Номер 11(13), С. 4019 - 4031
Опубликована: Янв. 1, 2024
Vertical electron transfer controls the thermodynamics of Cu( i ) photoredox catalysis. Structural relaxation indirectly enhances metal-centered reductions by preventing flattening distortions destabilizing oxidized ii species.
Язык: Английский
Процитировано
0Synthesis, Год журнала: 2024, Номер 56(19), С. 3019 - 3026
Опубликована: Июнь 19, 2024
Abstract The metal-free direct oxidative cross-dehydrogenative C–H bond amination of imidazopyridines with pyrazole in water as solvent has been developed under K2S2O8-promoted mild conditions. This strategy was applied to variable imidazoheterocycles give products moderate good yields. described protocol also offers scale-up synthesis for the construction C–N bonds, which makes it suitable biologically active compounds and pharmaceuticals.
Язык: Английский
Процитировано
0Elsevier eBooks, Год журнала: 2024, Номер unknown, С. 91 - 149
Опубликована: Авг. 16, 2024
Язык: Английский
Процитировано
0