Electrochemical N-acylation and N-α-ketoacylation of sulfoximines via the selective decarboxylation and dehydration of α-ketoacids

Green Chemistry, Год журнала: 2023, Номер 25(21), С. 8838 - 8844

Опубликована: Янв. 1, 2023

We describe an electrochemical N -acylation and -α-ketoacylation of sulfoximines via the selective decarboxylation dehydration α-ketoacids using electricity as a “traceless” oxidant α-ketoacid “acyl” or “α-ketoacyl” source.

Язык: Английский

Oxidation of N-trifluoromethylthio sulfoximines using NaOCl·5H₂O

Organic & Biomolecular Chemistry, Год журнала: 2024, Номер 22(10), С. 2012 - 2020

Опубликована: Янв. 1, 2024

N -Trifluoromethylthio sulfoximines were oxidized using NaOCl·5H 2 O to the corresponding novel -trifluoromethylsulfaneylidene in high yields and with excellent green metrics.

Язык: Английский