Visible-light induced direct C(sp3)–H functionalization: recent advances and future prospects
Organic Chemistry Frontiers,
Год журнала:
2024,
Номер
11(18), С. 5278 - 5305
Опубликована: Янв. 1, 2024
This
review
summarizes
the
latest
methodological
advances
in
photocatalytic
C(sp
3
)–H
functionalization,
with
a
particular
emphasis
on
formation
of
C–P,
C–B,
C–S
bonds,
etc
.,
and
some
prominent
efforts
asymmetric
C–H
functionalization.
Язык: Английский
Minisci-Type Dehydrogenative Coupling of C(sp3)–H and N-Heteroaromatics Enabled by Photoelectrochemical Hydrogen Atom Transfer
Organic Letters,
Год журнала:
2024,
Номер
26(27), С. 5805 - 5810
Опубликована: Июль 1, 2024
Minisci-type
dehydrogenative
coupling
of
C(sp3)–H
and
N-heteroaromatics
was
performed
with
N-hydroxysuccinimide
as
a
hydrogen
atom
transfer
catalyst
in
photoelectrochemical
cell
composed
mesoporous
BiVO4
photoanode
Pt
electrode.
In
the
absence
metal
catalysts
chemical
oxidants,
range
N-heteroarenes
(e.g.,
quinolines,
isoquinolines,
quinoxaline)
can
undergo
various
partners
to
form
corresponding
products
excellent
yields.
Язык: Английский