N-Bridged BODIPY Dimers: Exploring the Electron-Rich and Electron-Poor Coupling Limit via Pyrrole and Pyridine Annulation DOI
Sebastian H. Röttger, Lukas J. Patalag, Heinrich F. von Köller

и другие.

Organic Letters, Год журнала: 2024, Номер unknown

Опубликована: Дек. 17, 2024

A facile access to N-heteroaryl-fused bis-BODIPY scaffolds has been developed. BODIPY dimer with an α,α-amine linker serves as a starting material obtain pyrrole- and pyridine-fused BODIPYs, either by direct oxidation or oxidative condensation aldehyde building block. Both species mark antipodal conjugative coupling conditions that result in distinct spectral outcomes. In stark contrast the pyrrole fusion, pyridine-coupled show unique panchromatic absorption profiles.

Язык: Английский

N-Bridged BODIPY Dimers: Exploring the Electron-Rich and Electron-Poor Coupling Limit via Pyrrole and Pyridine Annulation DOI
Sebastian H. Röttger, Lukas J. Patalag, Heinrich F. von Köller

и другие.

Organic Letters, Год журнала: 2024, Номер unknown

Опубликована: Дек. 17, 2024

A facile access to N-heteroaryl-fused bis-BODIPY scaffolds has been developed. BODIPY dimer with an α,α-amine linker serves as a starting material obtain pyrrole- and pyridine-fused BODIPYs, either by direct oxidation or oxidative condensation aldehyde building block. Both species mark antipodal conjugative coupling conditions that result in distinct spectral outcomes. In stark contrast the pyrrole fusion, pyridine-coupled show unique panchromatic absorption profiles.

Язык: Английский

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