Industrial & Engineering Chemistry Research,
Год журнала:
2022,
Номер
62(11), С. 4628 - 4635
Опубликована: Дек. 27, 2022
This
review
describes
progress
in
the
design
and
synthesis
of
biomass-derived
carbon
materials
with
different
morphologies.
It
also
covers
respective
composites
their
applications
field
electrochemical
sensing
(bio)
chemical
species.
Generally,
carbon-based
have
paved
way
for
advanced
devices
because
unique
physical
properties.
Carbon
are
typically
created
from
precursor
materials;
however,
researchers
increasingly
focusing
on
fabricating
waste
biomass
resources
due
to
economic
environmental
constraints.
Compared
other
materials,
(BCMs)
more
environment-friendly
lower
toxicity.
In
this
review,
we
concentrated
providing
a
complete
overview
develop
an
alternative
strategy
improve
sensitivity
sensors
actual
samples
by
using
numerous
modified
electrodes.
summarizes
classification,
methods,
BCMs
composite
materials.
The
major
challenges
outlined,
future
research
avenues
BCM-based
highlighted.
Journal of Materials Chemistry A,
Год журнала:
2021,
Номер
9(44), С. 24759 - 24802
Опубликована: Янв. 1, 2021
Synthesis
and
formation
mechanisms
of
biomass-derived
carbonaceous
materials
are
critically
reviewed
in
terms
biomass
sources,
conversion
methods
additives
for
energy
environmental
applications.
Environmental Chemistry Letters,
Год журнала:
2023,
Номер
21(3), С. 1315 - 1379
Опубликована: Март 10, 2023
Abstract
The
energy
crisis
and
environmental
pollution
have
recently
fostered
research
on
efficient
methods
such
as
catalysis
to
produce
biofuel
clean
water.
Environmental
refers
green
catalysts
used
breakdown
pollutants
or
chemicals
without
generating
undesirable
by-products.
For
example,
derived
from
waste
inexpensive
materials
are
promising
for
the
circular
economy.
Here
we
review
photocatalysis,
biocatalysis,
electrocatalysis,
with
focus
catalyst
synthesis,
structure,
applications.
Common
include
biomass-derived
materials,
metal–organic
frameworks,
non-noble
metals
nanoparticles,
nanocomposites
enzymes.
Structure
characterization
is
done
by
Brunauer–Emmett–Teller
isotherm,
thermogravimetry,
X-ray
diffraction
photoelectron
spectroscopy.
We
found
that
water
can
be
degraded
an
efficiency
ranging
71.7
100%,
notably
heterogeneous
Fenton
catalysis.
Photocatalysis
produced
dihydrogen
(H
2
)
generation
rate
higher
than
100
μmol
h
−1
.
Dihydrogen
yields
ranged
27
88%
methane
cracking.
Biodiesel
production
reached
48.6
99%.
ACS Nano,
Год журнала:
2023,
Номер
17(20), С. 20525 - 20536
Опубликована: Окт. 10, 2023
The
emergence
of
green
flexible
aerogel
electronics
based
on
natural
materials
is
expected
to
solve
part
the
global
environmental
and
energy
crisis.
However,
it
still
challenging
achieve
large-scale
production
multifunctional
stable
applications
biomass
fiber
(BFA)
materials.
Herein,
we
exploit
interfacial
bridging
between
flower-type
titanium
dioxide
nanoarray
(FTNA)
substrates
modulate
electronic
structure
loss
mechanism
properties.
Specifically,
fibrous
substrate
with
wrinkled
features
induces
lattice
strain
in
titania
through
precise
bridging,
effectively
improving
intrinsic
properties
BFA
This
regulation
strategy
also
confirmed
by
X-ray
absorption
fine
spectroscopy
(XAS).
More
importantly,
construction
products
for
different
macroscopic
simple
processing
methods
will
facilitate
transition
from
electronics.
Therefore,
as-prepared
blanket-type
(TCBFA)
has
good
mechanical
properties,
electromagnetic
protection
thermal
stealth
high-temperature
flame
retardancy,
UV
resistance.
Meanwhile,
membrane-type
(TCBFAM)
wearable
device
exhibits
superior
flexibility,
efficient
Joule
heating
performance,
a
smart
response.
provides
another
concept
design
innovation
fiber-integrated
aerogels.
Journal of Materials Chemistry A,
Год журнала:
2023,
Номер
11(18), С. 9721 - 9747
Опубликована: Янв. 1, 2023
Metal–organic
frameworks
(MOFs)
have
become
popular
precursors
for
the
construction
of
porous
carbon
nanomaterials
(CNMs)
with
inherited
characteristics
and
advantages,
showing
great
potential
in
environment
energy
applications.
Carbon Energy,
Год журнала:
2022,
Номер
4(4), С. 491 - 505
Опубликована: Апрель 30, 2022
Abstract
A
versatile
use
of
a
sulfur
self‐doped
biochar
derived
from
Camellia
japonica
(camellia)
flowers
is
demonstrated
as
multifunctional
catalyst
for
overall
water
splitting
and
supercapacitor.
The
native
content
in
the
camellia
flower
facilitates
situ
self‐doping
sulfur,
which
highly
activates
camellia‐driven
(SA‐Came)
with
enhanced
electron‐transfer
ability
long‐term
durability.
For
splitting,
an
SA‐Came‐based
electrode
stable
shows
reaction
activities
both
hydrogen
oxygen
evolution
reactions,
overpotentials
154
362
mV
at
10
mA
cm
−2
,
respectively.
supercapacitors,
SA‐Came
achieves
specific
capacitance
125.42
F
g
−1
2
high
cyclic
stability
three‐electrode
system
1
M
KOH
electrolyte.
It
energy
density
34.54
Wh
kg
power
1600
W
symmetric
hybrid
supercapacitor
device
wide
working
potential
range
0–1.6
V.
Abstract
Lithium
metal,
as
the
“Holy
Grail”
of
lithium
battery
anodes,
is
promising
to
be
used
in
next‐generation
high‐energy‐density
storage
devices.
However,
serious
safety
risk
and
poor
cycle
performance
are
inevitable
when
bare
foil
anode
material,
due
uncontrolled
growth
dendrites,
unstable
solid
electrolyte
interface,
infinite
volume
expansion
during
cycling,
which
largely
hinder
further
commercial
application
metal
batteries
(LMBs).
The
utilization
up‐to‐date
current
collectors
with
specific
composition
structure
believed
effective
overcome
these
shortcomings.
a
systematic
evaluation
merit
different
collector
materials
for
realizing
high‐performance
anodes
still
lacking.
This
review
summarizes
fashionable
advanced
long‐life
LMBs
recent
years.
superiorities
related
electrochemical
performances
by
using
discussed
detail.
It
expected
that
this
may
promote
rational
choice
appreciatory
unique
designs
extend
life
achieving
LMBs.
Advanced Functional Materials,
Год журнала:
2022,
Номер
32(35)
Опубликована: Июнь 28, 2022
Abstract
It
is
a
natural
choice
to
realize
the
vision
of
wood‐inspired
functional
materials
for
energy
engineering.
Apart
from
being
naturally
abundant,
renewable,
and
biodegradable,
wood‐based
devices
possess
hierarchically
porous
structures,
mechanical
integrity
flexibility,
tunable
functionalities,
holding
potential
significantly
push
boundaries
efficient
storage
conversion.
Meanwhile,
hunting
batteries
with
superior
energy/power
output
redeem
ever‐growing
demand
has
ignited
thick
electrode
conception,
which
deemed
as
burgeoning
technic
maneuver
maximum
active
material
loading
at
device‐scale.
As
an
integrated
carbonaceous
scaffold
hierarchical
architecture
aligned
channels,
wood
ameliorates
ion/electron
conductivities
strengthen
charge
transfer
kinetics.
In
this
review,
rational
design
unique
prospects
in
construction
electrodes
that
concerns
over
structural
optimization
low‐tortuosity
cell
configuration
are
summarized.
To
trap
structure‐feature‐performance
interplays,
advanced
opens
avenue
emerging
chemistries
such
supercapacitors,
lithium‐ion/metal
post‐rechargeable
also
spotlighted
standpoint
on
task‐tailored
modification.
Ultimately,
blueprint
ongoing
challenges
upcoming
opportunities
wood‐structured
drawn
broaden
their
brand‐new
talents.