Batteries,
Год журнала:
2023,
Номер
9(3), С. 157 - 157
Опубликована: Март 1, 2023
Innovation
in
the
design
of
Li-ion
rechargeable
batteries
is
necessary
to
overcome
safety
concerns
and
meet
energy
demands.
In
this
regard,
a
new
generation
(LIBs)
form
all-solid-state
(ASSBs)
has
been
developed,
attracting
great
deal
attention
for
their
high-energy
density
excellent
mechanical-electrochemical
stability.
This
review
describes
current
state
research
development
on
ASSB
technology.
To
end,
study
literature
patents
as
well
market
analysis
over
last
two
decades
were
carried
out,
highlighting
how
scientific
achievements
have
informed
application
commercially
profitable
ASSBs.
Analyzing
registered
past
20
years
revealed
that
number
them
had
increased
exponentially-from
only
few
per
year
early
2000
more
than
342
2020.
Published
topic
declare
solid-state
electrolyte
(SSE)
be
main
component
ASSBs,
most
patented
examples
are
referred
solid
inorganic
electrolytes
(SIEs),
followed
by
polymer
(SPEs)
hybrid
(SHEs)
popularity.
Investigation
company
websites,
social
media
profiles,
reports,
academic
publications
identified
93
companies
associated
with
A
list
leading
businesses
battery
sector
was
compiled,
out
which
36
provided
information
units
product
portfolio
detailed
analysis.
Chemical Reviews,
Год журнала:
2022,
Номер
123(2), С. 558 - 612
Опубликована: Окт. 19, 2022
Polymers
are
extensively
exploited
as
active
materials
in
a
variety
of
electronics
and
energy
devices
because
their
tailorable
electrical
properties,
mechanical
flexibility,
facile
processability,
they
lightweight.
The
polymer
integrated
with
self-healing
ability
offer
enhanced
reliability,
durability,
sustainability.
In
this
Review,
we
provide
an
update
on
the
major
advancements
applications
polymers
devices,
including
electronic
components,
optoelectronics,
dielectrics.
differences
fundamental
mechanisms
healing
strategies
between
fracture
breakdown
underlined.
key
concepts
for
repairing
integrity
restoring
functions
device
performance
response
to
damage
outlined.
advantages
limitations
current
approaches
systematically
summarized.
Challenges
future
research
opportunities
highlighted.
Advanced Energy Materials,
Год журнала:
2022,
Номер
12(32)
Опубликована: Июль 14, 2022
Abstract
High‐voltage
lithium
polymer
cells
are
considered
an
attractive
technology
that
could
out‐perform
commercial
lithium‐ion
batteries
in
terms
of
safety,
processability,
and
energy
density.
Although
significant
progress
has
been
achieved
the
development
electrolytes
for
high‐voltage
applications
(>
4
V),
cell
performance
containing
these
materials
still
encounters
certain
challenges.
One
major
limitations
is
posed
by
poor
cyclability,
which
affected
low
oxidative
stability
standard
polyether‐based
electrolytes.
In
addition,
high
reactivity
structural
instability
common
cathode
chemistries
further
aggravate
this
review,
comprehensively
discussed,
along
with
key
sources
degradation,
provides
overview
fundamental
strategies
adopted
enhancing
their
cyclability.
regard,
a
statistical
analysis
provided
analyzing
186
publications
reported
last
17
years,
to
demonstrate
gap
between
state‐of‐the‐art
requirements
high‐energy
density
cells.
Furthermore,
essential
characterization
techniques
employed
prior
research
investigating
degradation
systems
discussed
highlight
prospects
limitations.
Based
on
derived
conclusions,
new
targets
guidelines
proposed
research.
Nature Communications,
Год журнала:
2023,
Номер
14(1)
Опубликована: Авг. 1, 2023
As
a
replacement
for
highly
flammable
and
volatile
organic
liquid
electrolyte,
solid
polymer
electrolyte
shows
attractive
practical
prospect
in
high-energy
lithium
metal
batteries.
However,
unsatisfied
interface
performance
ionic
conductivities
are
two
critical
challenges.
A
common
strategy
involves
introducing
solvents
or
plasticizers,
but
this
violates
the
original
intention
of
security
design.
Here,
an
concept
called
without
any
small
molecular
is
proposed
safe
high-performance
batteries,
based
on
design
room-temperature
liquid-state
brush-like
as
sole
solvent
salts.
This
non-flammable
exhibits
high
conductivity
(1.09
[Formula:
see
text]
10
Energy & Environmental Science,
Год журнала:
2023,
Номер
16(5), С. 1907 - 1942
Опубликована: Янв. 1, 2023
A
panoramic
view
of
the
Li/CF
x
battery,
ranging
from
mechanism
to
materials
synthesis,
structure–performance
relationships
and
energy-guided
strategy
are
included.
Advanced Energy Materials,
Год журнала:
2023,
Номер
13(15)
Опубликована: Март 11, 2023
Abstract
Polymer
composite
electrolytes
(PCEs),
i.e.,
materials
combining
the
disciplines
of
polymer
chemistry,
inorganic
and
electrochemistry,
have
received
tremendous
attention
within
academia
industry
for
lithium‐based
battery
applications.
While
PCEs
often
comprise
3D
micro‐
or
nanoparticles,
this
review
thoroughly
summarizes
prospects
2D
layered
inorganic,
organic,
hybrid
nanomaterials
as
active
(ion
conductive)
passive
(nonion
fillers
in
PCEs.
The
synthetic
nanofillers
covered
here
include
graphene
oxide,
boron
nitride,
transition
metal
chalcogenides,
phosphorene,
MXenes.
Furthermore,
use
naturally
occurring
clay
minerals,
such
double
hydroxides
silicates,
is
also
detailed
considering
their
impact
on
cell
performance.
Despite
dominance
materials,
organic
counterparts,
covalent
frameworks
metal–organic
are
identified
tuneable
PCE.
Hence,
gives
an
overview
plethora
options
available
selective
development
both
resulting
PCEs,
which
can
revolutionize
field
polymer‐based
solid‐state
implementation
lithium
post‐lithium
batteries.
Chemical Society Reviews,
Год журнала:
2024,
Номер
53(10), С. 5264 - 5290
Опубликована: Янв. 1, 2024
The
energy
storage
and
vehicle
industries
are
heavily
investing
in
advancing
all-solid-state
batteries
to
overcome
critical
limitations
existing
liquid
electrolyte-based
lithium-ion
batteries,
specifically
focusing
on
mitigating
fire
hazards
improving
density.
All-solid-state
lithium-sulfur
(ASSLSBs),
featuring
earth-abundant
sulfur
cathodes,
high-capacity
metallic
lithium
anodes,
non-flammable
solid
electrolytes,
hold
significant
promise.
Despite
these
appealing
advantages,
persistent
challenges
like
sluggish
redox
kinetics,
metal
failure,
electrolyte
degradation,
manufacturing
complexities
hinder
their
practical
use.
To
facilitate
the
transition
of
technologies
an
industrial
scale,
bridging
gap
between
fundamental
scientific
research
applied
R&D
activities
is
crucial.
Our
review
will
address
inherent
cell
chemistries
within
ASSLSBs,
explore
advanced
characterization
techniques,
delve
into
innovative
structure
designs.
Furthermore,
we
provide
overview
recent
trends
investment
from
both
academia
industry.
Building
understandings
progress
that
has
been
made
thus
far,
our
objective
motivate
battery
community
advance
ASSLSBs
a
direction
propel
industrialized
process.
Polymers,
Год журнала:
2023,
Номер
15(4), С. 803 - 803
Опубликована: Фев. 5, 2023
Polymer
electrolytes
(PEs)
have
been
thoroughly
investigated
due
to
their
advantages
that
can
prevent
severe
problems
of
Li-ion
batteries,
such
as
electrolyte
leakage,
flammability,
and
lithium
dendrite
growth
enhance
thermal
electrochemical
stabilities.
Gel
polymer
(GPEs)
using
in
situ
polymerization
are
typically
prepared
by
or
UV
curing
methods
initially
impregnating
liquid
precursors
inside
the
electrode.
The
method
resolve
insufficient
interfacial
between
electrode
compared
with
ex
method,
which
could
led
a
poor
cycle
performance
high
resistance.
In
addition
abovementioned
advantage,
it
form
factor
bare
cells
since
precursor
be
injected
before
prior
solidification
desired
shapes.
These
suggest
gel
promising
material
for
lithium-ion
batteries.
