Advanced Materials,
Год журнала:
2024,
Номер
unknown
Опубликована: Окт. 28, 2024
Abstract
The
rapid
development
of
wearable
and
intelligent
flexible
devices
has
posed
strict
requirements
for
power
sources,
including
excellent
mechanical
strength,
inherent
safety,
high
energy
density,
eco‐friendliness.
Zn‐ion
batteries
with
aqueous
quasi‐solid‐state
electrolytes
(AQSSEs)
various
functional
groups
that
contain
electronegative
atoms
(O/N/F)
tunable
electron
accumulation
states
are
considered
as
a
promising
candidate
to
the
tremendous
progress
been
achieved
in
this
prospering
area.
Herein,
review
proposes
comprehensive
summary
recent
achievements
using
AQSSE
by
focusing
on
significance
different
groups.
fundamentals
challenges
ZIBs
introduced
from
chemical
view
first
place.
Then,
mechanism
behind
stabilization
functionalized
is
summarized
explained
detail.
Then
regarding
enhanced
electrochemical
stability
classified
based
polymer
chain.
advanced
characterization
methods
briefly
following
sections.
Last
but
not
least,
current
future
perspectives
area
provided
authors'
point
view.
Green Energy and Intelligent Transportation,
Год журнала:
2023,
Номер
2(5), С. 100126 - 100126
Опубликована: Сен. 9, 2023
Due
to
their
potential
for
high
energy
density,
low
cost,
and
environmental
sustainability,
zinc-ion
batteries
(ZIBs)
have
emerged
as
a
promising
storage
technology.
The
performance,
safety,
overall
efficiency
of
ZIBs
are
significantly
impacted
by
the
properties
electrolyte,
such
ionic
conductivity,
electrochemical
stability
window,
viscosity,
compatibility
with
other
battery
components.
use
liquids
(ILs)
in
has
gained
extensive
attention
recent
years
due
desirable
properties,
thermal
stability,
volatility,
wide
tunable
physicochemical
properties.
Therefore,
this
paper
provides
bibliometric
analysis
advances
ILs
electrolytes
ZIBs.
Current
research
trends,
authorship
patterns,
publications
analyzed.
Our
review
reveals
growing
interest
ZIBs,
development
novel
tailored
meet
specific
requirements
is
focus.
This
insights
into
advancements
future
directions
field
Angewandte Chemie,
Год журнала:
2024,
Номер
136(9)
Опубликована: Янв. 3, 2024
Abstract
Quasi‐solid
zinc‐ion
batteries
using
hydrogel
electrolytes
show
great
potential
in
energy
storage
devices
owing
to
their
intrinsic
safety,
fewer
side
reactions
and
wide
electrochemical
windows.
However,
the
dendrite
issues
on
zinc
anodes
cannot
be
fundamentally
eliminated
anode‐electrolyte
interfacial
interspace
is
rarely
investigated.
Here,
we
design
a
dynamically
healable
gelatin‐based
electrolyte
with
highly
reversible
sol‐gel
transition,
which
can
construct
conformal
electrode‐electrolyte
interface
further
evolve
into
stable
solid‐solid
by
situ
solidification.
The
unique
helical
gelatin
chain
structure
provides
uniform
channel
for
ion
transport
bridging
effect
of
sulfate
groups.
As
consequence,
enables
dendrite‐free
repeatedly
repairs
interspaces
transition
retain
long‐lasting
protection
sustainable
batteries.
The
ever-increasing
demand
for
rechargeable
battery
systems
in
the
era
of
electric
vehicles
has
spurred
extensive
research
into
developing
polymeric
components
batteries,
such
as
separators,
polymer
electrolytes,
and
binders.
However,
current
rely
on
expensive
nonrenewable
resources,
which
potentially
have
a
negative
environmental
impact.
Therefore,
materials
derived
from
natural
resources
gained
significant
attention,
primarily
due
to
their
cost-effective
environmentally
sustainable
features.
Moreover,
feedstocks
often
possess
highly
polar
functional
groups
high
molecular
weights,
offering
desirable
electro-chemo-mechanical
features
when
applied
materials.
More
recently,
various
recycling
upcycling
strategies
also
been
proposed
given
substantial
waste
generation
end-of-life
batteries.
Recycling
includes
an
overall
process
recovering
spent
batteries
followed
by
regeneration
new
Polymer
involves
transforming
daily-used
plastic
high-value-added
components.
This
review
aims
give
state-of-the-art
overview
contemporary
methods
develop
recycling/upcycling
applications.
Advanced Materials,
Год журнала:
2024,
Номер
unknown
Опубликована: Окт. 28, 2024
Abstract
The
rapid
development
of
wearable
and
intelligent
flexible
devices
has
posed
strict
requirements
for
power
sources,
including
excellent
mechanical
strength,
inherent
safety,
high
energy
density,
eco‐friendliness.
Zn‐ion
batteries
with
aqueous
quasi‐solid‐state
electrolytes
(AQSSEs)
various
functional
groups
that
contain
electronegative
atoms
(O/N/F)
tunable
electron
accumulation
states
are
considered
as
a
promising
candidate
to
the
tremendous
progress
been
achieved
in
this
prospering
area.
Herein,
review
proposes
comprehensive
summary
recent
achievements
using
AQSSE
by
focusing
on
significance
different
groups.
fundamentals
challenges
ZIBs
introduced
from
chemical
view
first
place.
Then,
mechanism
behind
stabilization
functionalized
is
summarized
explained
detail.
Then
regarding
enhanced
electrochemical
stability
classified
based
polymer
chain.
advanced
characterization
methods
briefly
following
sections.
Last
but
not
least,
current
future
perspectives
area
provided
authors'
point
view.
