Energy Advances,
Год журнала:
2024,
Номер
3(4), С. 741 - 764
Опубликована: Янв. 1, 2024
Phytochemical-based
additives
have
functional
groups
that
can
modulate
the
nucleation
and
crystallization
process
of
perovskite
films
resulting
in
improved
optoelectronic
degradation
resistance.
Journal of Materials Chemistry A,
Год журнала:
2024,
Номер
12(8), С. 4421 - 4440
Опубликована: Янв. 1, 2024
This
review
article
includes
dimensional
diversity
and
exploring
the
potential
of
mixed-dimensional
integrations
to
improve
stability
performance
PV
devices.
Chemical Society Reviews,
Год журнала:
2024,
Номер
53(11), С. 5626 - 5676
Опубликована: Янв. 1, 2024
Metalation
of
metal-organic
frameworks
(MOFs)
has
been
developed
as
a
prominent
strategy
for
materials
functionalization
pore
chemistry
modulation
and
property
optimization.
By
introducing
exotic
metal
ions/complexes/nanoparticles
onto/into
the
parent
framework,
many
metallized
MOFs
have
exhibited
significantly
improved
performance
in
wide
range
applications.
In
this
review,
we
focus
on
research
progress
metalation
during
last
five
years,
spanning
design
principles,
synthetic
strategies,
potential
Based
crystal
engineering
minor
change
MOF
composition
through
would
lead
to
leveraged
variation
properties.
This
review
starts
from
general
strategies
established
incorporation
species
within
MOFs,
followed
by
principles
graft
desired
functionality
while
maintaining
porosity
frameworks.
Facile
contributed
great
number
bespoke
with
excellent
performance,
summarize
their
applications
gas
adsorption
separation,
heterogeneous
catalysis,
detection
sensing,
energy
storage
conversion.
The
underlying
mechanisms
are
also
investigated
state-of-the-art
techniques
analyzed
gaining
insight
into
structure-property
relationships,
which
turn
facilitate
further
development
principles.
Finally,
current
challenges
opportunities
discussed,
promising
future
directions
customizing
next-generation
advanced
outlined
well.
Chemical Society Reviews,
Год журнала:
2024,
Номер
53(13), С. 6694 - 6734
Опубликована: Янв. 1, 2024
Delayed
luminescence
(DF),
including
phosphorescence
and
thermally
activated
delayed
fluorescence
(TADF),
circularly
polarized
(CPL)
exhibit
common
broad
application
prospects
in
optoelectronic
displays,
biological
imaging,
encryption.
Thus,
the
combination
of
is
attracting
increasing
attention.
The
encapsulation
guest
emitters
various
host
matrices
to
form
host-guest
systems
has
been
demonstrated
be
an
appealing
strategy
further
enhance
and/or
modulate
their
luminescence.
Compared
with
conventional
liquid
crystals,
polymers,
supramolecular
matrices,
porous
crystalline
frameworks
(PCFs)
metal-organic
(MOFs),
covalent-organic
(COFs),
zeolites
hydrogen-bonded
organic
(HOFs)
can
not
only
overcome
shortcomings
such
as
flexibility
disorder
but
also
achieve
ordered
guests
long-term
stability
chiral
structures,
providing
new
promising
platforms
for
development
DF
CPL.
In
this
review,
we
provide
a
comprehensive
critical
summary
recent
progress
photochemistry
Abstract
Metal–organic
frameworks
(MOFs)
have
attracted
immense
attention
as
efficient
heterogeneous
catalysts
over
other
solid
catalysts,
however,
their
chemical
environment
instability
often
limits
catalytic
potential.
Herein,
utilizing
a
flexible
unexplored
tetra‐acid
ligand
and
employing
the
mixed
approach,
3D
interpenetrated
robust
framework
is
strategically
developed,
IITKGP‐51
(IITKGP
stands
for
Indian
Institute
of
Technology
Kharagpur),
which
retained
its
crystallinity
wide
range
pH
solution
(4–12).
Having
ample
open
metal
sites
(OMSs),
explored
catalyst
in
one‐pot
Hantzsch
condensation
reaction,
with
low
loading
broad
substrates.
The
synthesis
drug
molecules
remains
one
most
significant
emergent
areas
organic
medicinal
chemistry.
Considering
such
practical
utility,
biologically
important
Nemadipine
B
Nifedipine
(calcium
channel
protein
inhibitor)
are
synthesized
first
time
by
using
this
fully
characterized
via
SC‐XRD
spectroscopic
methods.
This
report
inaugurates
usage
MOF
material
molecules.
Physical Chemistry Chemical Physics,
Год журнала:
2024,
Номер
26(5), С. 4166 - 4173
Опубликована: Янв. 1, 2024
PSCs
rely
on
valence
band
(VB)
and
conduction
(CB)
limits
of
perovskite
films.
Efficient
electron
injection
requires
a
higher
CB
edge
than
the
ETL's
CB,
while
hole
needs
lower
VB
HTL's
in
CsPbIBr
2
.