Environmental Technology Reviews,
Год журнала:
2024,
Номер
13(1), С. 544 - 571
Опубликована: Авг. 1, 2024
Advancement
of
reliable
and
eco-friendly
approaches
for
nanoparticles
growth
is
a
basic
key
to
the
regulation
nanotechnology.
For
decade,
various
have
been
constantly
evaluated
used
different
applications.
In
particular,
bismuth
(Bi)
are
receiving
great
interest
due
properties
such
as
low
band
gap
(which
lies
in
UV
region)
non-toxicity
compared
other
metal
nanoparticles.
Use
poisonous
chemicals
or
physical
chemical
methods
has
increased;
therefore,
green
approach
plants,
bacteria,
viruses,
fungi
biomolecules
preferred
synthesis
This
review
focused
on
rather
than
Bi
their
numerous
applications
including
biological
(antimicrobial),
biomedical
(imagining,
Drug
delivery
photothermal
therapy
cancer
therapy),
photocatalytic
hydrogen
storage.
As
articles
often
serve
references
newcomers
field,
this
report
directs
readers
showcasing
significant
advancements
Bi-based
nanoparticle
research.
The
objectives
study
include
highlighting
non-toxic
effective
antimicrobial
agents
potential
alternatives
antibiotics,
outlining
limitations
in-vitro
in-vivo
nanoparticles,
comparing
efficiency
with
types
applications,
providing
recommendations
future
research
endeavours.
Advanced Functional Materials,
Год журнала:
2023,
Номер
34(4)
Опубликована: Окт. 20, 2023
Abstract
Graphdiyne
(GDY)
is
regarded
as
an
exceptional
candidate
to
meet
the
growing
demand
in
many
fields
due
its
rich
chemical
bonds,
highly
π‐conjugated
structure,
uniformly
distributed
pores,
large
surface
area,
and
high
inhomogeneity
of
charge
distribution.
The
extensive
research
efforts
bring
about
a
rapid
expansion
GDY
with
variety
functionalities,
which
significantly
enhance
performance
including
photocatalysis,
energy,
biomedicine,
etc.
In
this
review,
synthetic
strategies
(in
situ
ex
approaches)
that
are
designed
rationally
functionalize
GDY,
optimizing
their
nanostructures
by
surface/interface
engineering
dopants
or
functional
groups
(heteroatoms/small
molecules/macromolecules),
building
up
hierarchical
GDY‐based
heterostructures
highlighted.
Theoretical
calculations
on
structural
evolution
electronic
characteristics
after
functionalization
briefly
discussed.
With
elaborate
rational
structure
engineering,
applied
emerging
applications
(e.g.,
hydrogen
reaction,
CO
2
reduction
nitrogen
energy
storage
conversion,
nanophotonics,
sensors,
biomedical
applications,
etc.)
comprehensively
Finally,
challenges
prospects
concerning
future
development
nanoarchitectures
also
presented.
ACS Sensors,
Год журнала:
2024,
Номер
9(2), С. 577 - 588
Опубликована: Янв. 22, 2024
Revolutionary
developments
in
analytical
chemistry
have
led
to
the
rapid
development
of
self-powered
photoelectrochemical
(PEC)
sensors.
Different
from
conventional
PEC
sensors,
sensors
do
not
require
an
external
power
source
or
complex
devices
for
sensitive
detection
targets.
As
a
result,
these
enormous
application
potential
novel
portable
An
increasing
body
work
is
making
excellent
progress
toward
implementation
detection,
but
there
been
no
reviews
date.
The
present
review
first
introduces
state
art
Then,
different
types
are
summarized
and
discussed
detail,
including
their
current,
power,
potential.
Additionally,
single-
dual-photoelectrode
systems
classified
systematically
compared.
Finally,
current
major
challenges
that
need
be
addressed
also
summarized.
This
provides
valuable
insights
into
promote
further
this
field.
Advanced Materials,
Год журнала:
2024,
Номер
unknown
Опубликована: Май 23, 2024
Self-powered
wearable
devices
with
integrated
energy
supply
module
and
sensitive
sensors
have
significantly
blossomed
for
continuous
monitoring
of
human
activity
the
surrounding
environment
in
healthcare
sectors.
The
emerging
MXene-based
materials
has
brought
research
upsurge
fields
electronics,
owing
to
their
excellent
electrochemical
performance,
large
surface
area,
superior
mechanical
tunable
interfacial
properties,
where
performance
can
be
further
boosted
via
multi-interface
engineering.
Herein,
a
comprehensive
review
recent
progress
MXenes
self-powered
is
discussed
from
aspects
fundamental
properties
including
electronic,
mechanical,
optical,
thermal
characteristics
are
detail.
Different
previous
works
on
MXenes,
engineering
termination
regulation
modification
impact
storage/conversion
summarized.
Based
manipulation
strategies,
potential
applications
outlined.
Finally,
proposals
perspectives
provided
current
challenges
future
directions
devices.
ACS Nano,
Год журнала:
2024,
Номер
18(9), С. 7204 - 7222
Опубликована: Фев. 19, 2024
Commercial
collagen
membranes
face
difficulty
in
guided
bone
regeneration
(GBR)
due
to
the
absence
of
hierarchical
structural
design,
effective
interface
management,
and
diverse
bioactivity.
Herein,
a
Janus
membrane
called
SrJM
is
developed
that
consists
porous
enhance
osteogenic
function
dense
maintain
barrier
function.
Specifically,
biomimetic
intrafibrillar
mineralization
with
strontium
apatite
realized
by
liquid
precursors
amorphous
phosphate.
Polycaprolactone
methacryloyl
further
integrated
on
one
side
as
face,
which
endows
mechanical
support
prolonged
lifespan.
In
vitro
experiments
demonstrate
acts
strong
against
fibroblasts,
while
significantly
promotes
cell
adhesion
differentiation
through
activation
calcium-sensitive
receptor/integrin/Wnt
signaling
pathways.
Meanwhile,
effectively
enhances
osteogenesis
angiogenesis
recruiting
stem
cells
modulating
osteoimmune
response,
thus
creating
an
ideal
microenvironment
for
regeneration.
vivo
studies
verify
defect
region
completely
repaired
newly
formed
vascularized
bone.
Overall,
outstanding
performance
supports
its
ongoing
development
multifunctional
GBR
membrane,
this
study
provides
versatile
strategy
fabricating
collagen-based
biomaterials
hard
tissue
Advanced Functional Materials,
Год журнала:
2024,
Номер
34(44)
Опубликована: Май 21, 2024
Abstract
Amorphous
materials
with
a
high
number
of
unsaturated
coordinated
dangling
bonds
exhibits
macroscopic
homogeneity
and
isotropy,
making
it
easily
modifiable
to
improve
the
catalytic
properties.
At
present,
several
feasible
modification
strategies
for
amorphous
have
been
proposed
applied
multiple
fields.
This
review
aims
provide
comprehensive
overview
recent
research
advancements
in
catalysis.
First,
general
modifying
are
summarized.
Subsequently,
potential
applications
modified
electrocatalysis
photocatalysis
highlighted.
Additionally,
positive
effects
various
tools
on
properties
elucidated.
Finally,
summary
challenges
offer
critical
perspective
further
development
presented.
The
primary
goal
this
is
systematic
understanding
how
enhance
performance
stimulate
catalysts
future.
ACS Catalysis,
Год журнала:
2025,
Номер
15(3), С. 2124 - 2138
Опубликована: Янв. 22, 2025
Replacing
the
oxygen
evolution
reaction
(OER)
in
photoelectrocatalytic
(PEC)
water
splitting
with
glycerol
oxidation
(GOR)
not
only
enhances
hydrogen
production
but
also
generates
high-value
byproducts.
In
this
study,
we
developed
a
ternary
photoanode,
Co-LDH/Bi2O3/TiO2,
by
loading
particulate
Bi2O3
and
linear
Co-LDH
onto
TiO2
nanorod
for
conversion
production.
The
characterization
results
confirm
formation
of
coupled
interfaces
between
TiO2,
which
improves
visible
light
utilization
promotes
type
II
heterojunctions,
resulting
significant
suppression
electron–hole
recombination
an
improvement
PEC
performance.
Fourier
transform
infrared
(FT-IR)
spectroscopy
revealed
that
Co-LDH/Bi2O3/TiO2
photoanode
exhibited
stronger
adsorption
intermediate
hydroxyl
group
more
effective
desorption
DHA
compared
to
binary
photoanodes
(Co-LDH/TiO2
Bi2O3/TiO2),
high-selectivity
DHA.
Mechanistic
studies
density
function
theory
calculations
have
shown
Co-LDH/TiO2
oxidizes
mainly
through
hole
oxidation,
Bi2O3/TiO2
radical
(•OH)
oxidation.
Therefore,
constructed
(Co-LDH/Bi2O3/TiO2)
dual
heterojunction
converts
pathways
•OH
This
work
demonstrates
promising
strategy
developing
high-performance
systems
production,
leveraging
synergistic
effects
multisemiconductor
heterojunctions
multiple
pathways,
offering
potential
practical
applications.
Advanced Functional Materials,
Год журнала:
2023,
Номер
33(46)
Опубликована: Июль 8, 2023
Abstract
Semiconductor‐based
photoelectrochemical
(PEC)
fuel
cells
offer
a
feasible
solution
for
sustainable
and
environmentally
friendly
energy
production
by
converting
solar
chemical
into
electrical
energy.
However,
the
low
PEC
activities
of
have
hindered
their
practical
application
due
to
rapid
electron‐hole
recombination
slow
interfacial
reaction
kinetics.
To
address
this
issue,
unique
cell
composed
dual
photoelectrodes
utilizing
low‐cost
biomass,
ascorbic
acid,
as
an
organic
is
reported.
Significantly,
integration
bifunctional
iron
single‐atom
catalysts
(Fe
SACs)
photoactive
materials
has
effectively
constructed
bridge
charge
carrier
transfer,
boosting
kinetics
photoelectric
conversion
efficiency.
Notably,
optimal
dual‐photoelectrode
decorated
with
Fe
SACs
exhibits
superior
performance,
delivering
maximum
power
density
82.82
µW
cm
−2
.
Taking
advantage
peroxidase‐like
activity
SACs,
resultant
self‐powered
are
explored
sensitively
detecting
actual
uric
acid
samples.
This
study
provides
promising
avenue
boost
efficiency
sensitive
biosensing.