ACS Applied Materials & Interfaces,
Год журнала:
2024,
Номер
unknown
Опубликована: Окт. 3, 2024
Toward
commercialization
of
carbon-based
perovskite
solar
cells
(C-PSCs),
it
is
crucial
to
innovatively
design
inorganic
hole
transport
layer
materials
that
excel
in
extracting
and
transporting
charge
carriers
promote
their
photoelectric
conversion
efficiency
(PCE).
In
this
work,
a
novel
high-connectivity
CuBi
Inorganic Chemistry,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 7, 2025
Bismuth
oxide
nanosheets
were
synthesized
through
the
exfoliation
of
layered
compounds
without
any
organic
agents.
The
compound
Bi2.2Sr1.8CaFe2O9,
comprising
Bi–O
layers
and
Sr–Ca–Fe–O
layers,
was
as
starting
material.
selectively
dissolved
by
shaking
in
0.3
M
HNO3
solution,
yielding
aggregates
consisting
solely
bismuth
layers.
Subsequent
ultrasonic
treatment
these
pure
water
led
to
formation
nanosheets.
nanosheet
exhibited
a
higher
photocatalytic
activity
for
H2
production
compared
α-Bi2O3.
Characterization
using
FE-SEM,
AFM,
HAADF-STEM
revealed
that
exhibit
complex
structure.
They
consist
crystalline
framework
ε-bismuth
oxide,
interspersed
with
island-like
regions
amorphous
or
oxide.
Additionally,
self-standing
membranes
nanosheets,
aligned
[001]
direction,
successfully
synthesized.
This
method,
which
involves
partial
dissolution
structure
acid
followed
processing
water,
is
anticipated
be
applicable
other
well.
Advanced Sustainable Systems,
Год журнала:
2023,
Номер
8(2)
Опубликована: Сен. 24, 2023
Abstract
Electrochemical
reduction
of
CO
2
toward
value‐added
liquid
fuel
is
a
promising
route
to
achieve
the
carbon
neutrality.
Especially
for
electroreduction
formic
acid
production,
despite
favorable
activity
and
selectivity
can
be
achieved,
unstable
Faradaic
efficiency
(FE)
in
wide
potential
range
poor
energy
remain
bottlenecks.
Herein,
this
study
reports
metallic
Bi
catalyst
(B‐ArH
‐2)
derived
from
defective
O
3
,
which
achieves
nearly
100%
FE
HCOOH
production
over
broad
(−0.7
−1.1
V)
with
an
outstanding
cathodic
71%.
Additionally,
B‐ArH
‐2
displays
high
partial
current
density
(
j
27.5
mA
cm
−2
)
rate
(475
µmol
h
−1
long‐term
stability
(20
h).