ACS Catalysis,
Год журнала:
2024,
Номер
14(16), С. 12093 - 12101
Опубликована: Июль 30, 2024
The
process
of
C
self-doping
modifies
the
molecular
structure
and
electron
distribution
carbon
nitride,
hindering
integration
foreign
elements.
In
this
study,
self-doped
nitride-ethylenediamine
(HCN-EDA)
was
produced
via
a
hydrothermal
technique
involving
dicyanodiamine
ethylenediamine
(EDA).
This
variant
nitride
exhibits
broadened
visible-light
absorption
range,
thereby
improving
utilization
sunlight.
HCN-EDA
is
characterized
by
significantly
lower
photoluminescence
intensity,
increased
carrier
lifetime,
detectable
paramagnetic
resonance
signal
compared
to
pristine
nitride.
Furthermore,
theoretical
calculations
synchronous
illumination
X-ray
photoelectron
spectroscopy
confirmed
that
with
rearranged
distribution,
leading
enhanced
light
responsiveness
more
active
transfer
behavior.
hydrogen-evolution
rate
reached
52.16
mmol/(g
×
h),
which
63
times
greater
than
under
white
from
light-emitting
diode.
Additionally,
demonstrated
impressive
visible
reactivity,
apparent
quantum
yields
31.6%
at
420
nm
4.3%
520
nm.