Structure–property–performance relationship of vanadium- and manganese-based metal–organic frameworks and their derivatives for energy storage and conversion applications

Journal of Materials Chemistry A, Год журнала: 2024, Номер 12(19), С. 11149 - 11175

Опубликована: Янв. 1, 2024

The current review discusses on vanadium- and manganese-based metal–organic frameworks their derivatives for energy storage conversion applications along with the potential future advancements in these fields.

Язык: Английский

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Vanadium- and manganese-based metal-organic frameworks for potential environmental and catalysis applications

Coordination Chemistry Reviews, Год журнала: 2024, Номер 522, С. 216231 - 216231

Опубликована: Сен. 25, 2024

Язык: Английский

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Design and engineering of MOF/LDH hybrid nanocomposites and LDHs derived from MOF templates for electrochemical energy conversion/storage and environmental remediation: Mechanism and future perspectives

Coordination Chemistry Reviews, Год журнала: 2024, Номер 523, С. 216256 - 216256

Опубликована: Окт. 22, 2024

Язык: Английский

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Recent advanced strategies for bimetallenes toward electrocatalytic energy conversion reactions

Chemical Communications, Год журнала: 2024, Номер 60(23), С. 3129 - 3137

Опубликована: Янв. 1, 2024

Designing low-dimensional nanomaterials is vital to address the energy and environmental crisis by means of electrocatalytic conversion reactions. Bimetallenes, as an emerging class 2D materials, present promise for By leveraging atomically thin layers, bimetallenes unsaturated surface coordination, high specific area conductivity, which are all indispensable features heterogeneous electrochemical However, intrinsic activity stability needs be improved further bimetallene electrocatalysts, due higher demands practical applications. Recently, many strategies have been developed optimize chemical or electronic structure accommodate transfer reactants, adsorption desorption intermediates, dissociation products. Considering that most such work focuses on adjusting structure, this review offers in-depth insight into recent representative optimizing mainly including alloying, strain effects, ligand defects heteroatom doping. Moreover, summarizing performance optimized using various strategies, we provide a understand structure-property relationships. In addition, future prospects challenges discussed development electrocatalysts.

Язык: Английский

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Water-Stable Pillared Three-Dimensional Zn–V Bimetal–Organic Framework for Promoted Electrocatalytic Urea Oxidation

Inorganic Chemistry, Год журнала: 2024, Номер 63(12), С. 5642 - 5651

Опубликована: Март 12, 2024

Urea oxidation reaction (UOR) is one of the potential routes in which urea-rich wastewater used as a source energy for hydrogen production. Metal–organic frameworks (MOFs) have promising applications electrocatalytic processes, although there are still challenges identifying MOFs' molecular regulation and obtaining practical catalytic systems. The current study sought to synthesize [Zn6(IDC)4(OH)2(Hprz)2]n (Zn-MOF) with three symmetrically independent Zn(II) cations connected via linear N-donor piperazine (Hprz), rigid planar imidazole-4,5-dicarboxylate (IDC3–), −OH ligands, revealing 3,4T1 topology. optimized noble-metal-free Zn0.33V0.66-MOF/NF electrocatalysts show higher robustness performance compared those parent Zn monometallic MOF/NF electrode other bimetallic MOFs different Zn–V molar ratios. low 1.42 V (vs RHE) at 50 mA cm–2 1.0 M KOH 0.33 urea required by developed Zn0.33V0.66-MOF makes its application UOR more feasible. availability exposed active sites, ion diffusion path, conductivity result from distinctive configuration synthesized electrocatalyst, highly stable capable synergistic effects, consequently enhancing desired reaction. research contributes introducing practical, cost-effective, sustainable solution decompose produce hydrogen.

Язык: Английский

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Bimetallic NiCo Metal–Organic Frameworks with High Stability and Performance Toward Electrocatalytic Oxidation of Urea in Seawater

Inorganic Chemistry, Год журнала: 2024, Номер 63(34), С. 15813 - 15820

Опубликована: Авг. 14, 2024

The urea oxidation reaction (UOR) is an alternative anodic for hydrogen generation via water splitting. significance of UOR lies in both H2 production and the decontamination urea-containing wastewater. Commercial electrocatalysts this field are generally based on noble metals show several limitations. Bimetal–organic frameworks (BMOFs) can be excellent candidates replacement noble-metal-based catalysts beacuse their promising features, such as a tunable structure, high surface area, abundant sites electrocatalysis. In study, series nickel–cobalt BMOFs (Nix-Coy-BMOFs: x y refer to molar fraction Ni Co) were synthesized applied UOR. particular, Ni0.15Co0.85-MOF material with structure similar that its parent Co-MOF, revealed exceptional electrocatalytic performance, evidenced by low values overpotential (1.33 V vs RHE at 10 mA cm–2), TOF (0.47 s–1), Tafel slope (125 mV dec–1). At 40 cm–2 current density, also showed stability during 72 h tests. This performance NiCo-BMOF assigned synergistic effect between Co Ni, active sites, porosity, all which result increased rate due acceleration charge mass transfers. Thus, present work introduces efficient noble-metal-free energy from urea-based

Язык: Английский

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Postsynthetic Modification of Amine-Functionalized MIL-101(Cr) Metal–Organic Frameworks with an EDTA–Zn(II) Complex as an Effective Heterogeneous Catalyst for Hantzsch Synthesis of Polyhydroquinolines

ACS Omega, Год журнала: 2024, Номер 9(26), С. 28114 - 28128

Опубликована: Июнь 21, 2024

The present work aims at preparing the EDTA–Zn(II) complex─supported on amine-functionalized MIL-101(Cr) MOF─as a new and effective heterogenized catalyst. optimization of hydrothermal process shows that 120 °C is best condition to grow MIL-101(Cr)–NH2 MOF crystals. Moreover, regarding use postsynthetic modification (PSM) method, hexadentate EDTA was grafted this support via simple aminolysis before further coordinating it with Zn ions create corresponding Zn(II) catalytic complex. activity compound then investigated in context one-pot synthesis polyhydroquinolines. This approach has number advantages including following: solvent not hazardous, applying porous catalyst inexpensive, secure, recyclable; rapid reaction times, high levels efficiency, simplicity separation. Accordingly, question can be given label "green chemistry".

Язык: Английский

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Copper-Based Bio-MOF/GO with Lewis Basic Sites for CO₂ Fixation into Cyclic Carbonates and C–C Bond-Forming Reactions

Inorganic Chemistry, Год журнала: 2024, Номер 63(27), С. 12667 - 12680

Опубликована: Июнь 25, 2024

Several measures, including crude oil recovery improvement and carbon dioxide (CO2) conversion into valuable chemicals, have been considered to decrease the greenhouse effect ensure a sustainable low-carbon future. The Knoevenagel condensation CO2 fixation introduced as two principal solutions these challenges. In present study for first time, bio-metal–organic frameworks (MOF)(Cu)/graphene oxide (GO) nanocomposites used catalytic agents reactions. view of attendance amine groups, biological MOFs with NH2 functional groups Lewis base sites protruding on channels' internal surface were used. bio-MOF(Cu)/20%GO performs efficaciously in fixation, leading more than 99.9% TON = 525 via solvent-free reaction under 1 bar atmosphere. It has shown that are highly due basic sites, i.e., NH2, pyrimidine, C═O groups. Besides, active exert synergistic effects render bio-MOF(Cu)/10%GO nanostructures efficient catalysts, significantly accelerating reactions aldehydes malononitrile substrates, thanks high TOF (1327 h–1) acceptable reusability. Bio-MOFs can be stabilized using GO oxygen-containing contribute substitutes, an expeditious speed facilitating substrate absorption.

Язык: Английский

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Application of metal-organic framework materials in supercapacitors

Journal of Energy Storage, Год журнала: 2025, Номер 113, С. 115535 - 115535

Опубликована: Фев. 8, 2025

Язык: Английский

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Recent advances in hydrogen production using metal organic frameworks and their composites

International Journal of Hydrogen Energy, Год журнала: 2024, Номер 78, С. 303 - 324

Опубликована: Июнь 26, 2024

Язык: Английский

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