High thermoelectric performance of polycrystalline SnSe prepared by cold sintering
Ceramics International,
Год журнала:
2025,
Номер
unknown
Опубликована: Фев. 1, 2025
Язык: Английский
Perspective on Crystal Structures, Synthetic Methods, and New Directions in Thermoelectric Materials
Small Structures,
Год журнала:
2024,
Номер
unknown
Опубликована: Июнь 10, 2024
This
review
explores
the
state‐of‐the‐art
of
thermoelectric
materials,
covering
different
crystalline
structures
and
material
families
(e.g.,
chalcogenides,
Zintl
phases,
skutterudites,
clathrates,
oxides,
half‐Heusler,
organic–inorganic
composites,
metal–organic
frameworks,
silicides).
It
examines
their
corresponding
properties
while
considering
synthesis
methods
employed,
paying
significant
attention
to
those
that
particularly
follow
sustainable
routes.
Additionally,
work
addresses
current
challenges
in
field,
such
as
enhancing
stability
at
high
temperatures
reducing
manufacturing
costs.
The
understanding
gained
this
field
opens
avenues
for
designing
more
efficient
devices
convert
waste
heat
into
electrical
energy,
thereby
advancing
cleaner
technologies.
Язык: Английский
Achieving a High zTavg in n-Type Sb-Doped Mg2Si0.3Sn0.7 via High-Pressure-Modulated Microstructures
ACS Applied Materials & Interfaces,
Год журнала:
2025,
Номер
unknown
Опубликована: Март 26, 2025
Mg2Si-based
compounds
are
cost-effective
and
environmentally
friendly
thermoelectric
materials.
However,
the
current
Mg2(Si,Sn)
solid
solutions
still
suffer
from
low
figure
of
merit
zT
(or
energy
conversion
efficiency),
especially
averaged
value
(zTavg
<
1.0).
In
this
study,
we
synthesize
Mg2(Si0.3Sn0.7)1–xSbx
(x
=
0,
0.5,
0.75,
1,
1.5%)
through
combination
high-pressure,
high-temperature
(HPHT)
synthesis
spark
plasma
sintering
(SPS).
The
high-pressure
instrument
effectively
inhibits
unfavorable
oxidation
Mg.
This
HPHT
+
SPS
methodology
improves
defect
formation
efficiency
Sb-doped
Mg2Si0.3Sn0.7,
leading
to
an
increased
carrier
concentration
enhanced
electrical
conductivity.
Moreover,
as
a
benefit
pressure-induced
conduction
band
convergence
Sb-flattened
band,
density
states'
effective
mass
(md*)
significantly
increases
∼3.3me,
maintaining
high
Seebeck
coefficients
even
at
concentration.
synergetic
effects
doping
md*
increase
peak
power
factor
exceed
50
μW
cm–1
K–2.
Notably,
due
HPHT-modified
microstructures,
hierarchy
phonon
scatterings
established
suppress
lattice
thermal
conductivity
1.29
W
m–1
K–1
568
K;
Sb
point
defects,
dislocations,
grain
boundaries/pores
can
scatter
short-,
medium-,
long-wavelength
phonons,
respectively.
Ultimately,
optimized
Mg2(Si0.3Sn0.7)0.99Sb0.01
sample
in
whole
temperature
region;
is
1.37
673
K,
plateau
∼1.35
realized
between
723
K.
Thus,
notable
average
over
range
323–723
K
1.08.
Our
work
demonstrates
that
high-pressure-induced
concentration,
doping,
microstructure
modifications
facilitate
property
improvement
Mg2(Si,Sn)-based
compounds.
Язык: Английский
Synergistically optimize thermoelectric and mechanical properties of cubic SnSe-based alloys via nanocomposite engineering utilizing SiC nanoparticles as the dispersed phase
Rare Metals,
Год журнала:
2025,
Номер
unknown
Опубликована: Апрель 4, 2025
Язык: Английский
A Review of Polycrystalline SnSe Thermoelectric Materials: Progress and Prospects
Acta Metallurgica Sinica (English Letters),
Год журнала:
2025,
Номер
unknown
Опубликована: Апрель 14, 2025
Язык: Английский
Exploring the frontiers of SnSeS: A comprehensive review of properties and applications
Materials Science in Semiconductor Processing,
Год журнала:
2024,
Номер
185, С. 108862 - 108862
Опубликована: Авг. 31, 2024
Язык: Английский
Variations in the optical and thermoelectric behavior of ZnCo2O4 nanostructures as a function of synthesis temperature
Journal of Ovonic Research,
Год журнала:
2024,
Номер
20(5), С. 745 - 762
Опубликована: Ноя. 1, 2024
Zinc
cobalt
oxide
nanostructures
were
synthesized
by
electrochemical
deposition
of
zinccobalt
alloy
at
various
bath
temperatures
(15,
30,
45
and
60
˚C)
its
hydrothermal
oxidation
100
˚C.
X-ray
diffraction
pattern
Raman
spectroscopy
data
reveals
the
formation
spinal
structure
ZnCo2O4.
Photoluminescence
spectra
samples
exhibit
broad
peaks
with
a
red
shift
in
emission
energy.
Diffused
reflectance
measured
band
gap
materials;
is
3.06,
3.03,
3.02
2.99
eV,
for
electrodeposited
15,
˚C,
respectively.
Optical
conductivity
materials
decreases
increasing
layers
while
shows
opposite
trend.
Thermoelectric
set
up
measures
change
potential
difference
through
when
different
are
applied
an
increment
observed.
Seebeck
co-efficient
power
factor
also
studied
as
function
temperature.
Язык: Английский
Improving the thermoelectric performance of p-type (BixSb1−x)2Te3 thin films via tuning the BixSb1−x layer
Journal of Materials Chemistry A,
Год журнала:
2024,
Номер
12(33), С. 22276 - 22285
Опубликована: Янв. 1, 2024
Through
annealing
the
precursor
layer
Bi
x
Sb
1−
combined
with
thickness
variation,
Seebeck
coefficient
and
electrical
conductivity
are
increased
simultaneously
in
(Bi
)
2
Te
3
.
A
resultant
high
PF
of
37.78
μW
cm
−1
K
−2
is
obtained.
Язык: Английский