Anatase‐Rutile TiO2@V4C3Tx MXene for Omnidirectional Electrocatalytic Water Splitting DOI Creative Commons

Neermunda Shabana,

Punnoli Muhsin,

Ya‐Yun Yang

и другие.

Advanced Materials Interfaces, Год журнала: 2024, Номер unknown

Опубликована: Авг. 27, 2024

Abstract The quest for composite materials with unique features that each component, inherently, does not have is always an aspirational but challenging task. Among Transition metal oxides (TMOs), TiO 2 emerged as a prototype due to its earth abundance, environmental friendliness, and cost‐effectiveness, which has shown high activity photocatalytic hydrogen evolution. Unfortunately, inert electrocatalytic evolution reaction (HER) because it poor electrical conductivity unfavorable adsorption/desorption behavior. Herein the revitalization of overall water splitting, i.e., both HER oxygen (OER) reported by anchoring rutile‐anatase (a/r) nanoparticles on ‐OH/‐F terminated V 4 C 3 T x MXene, giving a/r @V heterostructure. synergetic effect showcases remarkable pH‐independent overpotential 35, 39, 82 mV in 0.5 m H SO , 1 KOH, phosphate‐buffered saline (PBS) respectively. catalyst also exhibits OER lowest 217, 267, 292 PBS respectively, outperforms pure . These findings, first time, support success anatase‐rutile MXene omnidirectional performance, low pH independence, pave avenue finding cost‐effective catalysts splitting.

Язык: Английский

Unlocking the potential of hydrogen evolution: Advancements in 3D nanostructured electrocatalysts supported on nickel foam DOI

Chengzhi Xiao,

Tongzhou Hong,

Jin Jia

и другие.

Applied Catalysis B Environment and Energy, Год журнала: 2024, Номер 355, С. 124197 - 124197

Опубликована: Май 12, 2024

Язык: Английский

Процитировано

18
High entropy catalysts in electrolytic water splitting: A review from properties to applications DOI
Zhijie Zhang, Yu Ning, Yilin Dong

и другие.

Chemical Engineering Journal, Год журнала: 2024, Номер 498, С. 155736 - 155736

Опубликована: Сен. 12, 2024

Язык: Английский

Процитировано

9
Room‐Temperature Synthesis of Amorphous Fe‐Doped Nickel Phosphate for High‐Efficiency Alkaline Seawater Oxidation DOI Open Access
D. Xu, Chenxi Zhang, Yun Liu

и другие.

Small, Год журнала: 2025, Номер unknown

Опубликована: Фев. 2, 2025

The construction of an efficient and durable oxygen evolution reaction (OER) electrocatalyst through a simple synthesis strategy is crucial for the hydrogen produced from seawater splitting. However, achieving this goal remains great challenge. Herein, amorphous Fe-doped nickel phosphate (Fe-NixPO4) as high-performance OER electrocatalysts alkaline freshwater/seawater splitting presented using straightforward co-precipitation method at room-temperature. Experimental results reveal structural reconstruction Fe-NixPO4 into NiOOH decorated with PO4 3-. collaborative interplay between Ni2+ Fe3+, along decoration 3-, can effectively modulate electronic environment electrocatalyst. Consequently, optimized exhibits exceptional activity, requiring overpotentials 359 422 mV to generate 1000 mA cm-2 in freshwater seawater, respectively. Moreover, also displays outstanding stability 100 h seawater. This research presents viable approach fabricating efficiency electrolysis.

Язык: Английский

Процитировано

0
Black phosphorus: A promising nonmetallic doping source for enhancing visible light photoelectrocatalytic water splitting performance of TiO2 nanotube array-based photoanodes DOI
Yue Liu, Xiaowei Niu, Ying Su

и другие.

Applied Surface Science, Год журнала: 2025, Номер unknown, С. 162938 - 162938

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

0
Electronic Structure Engineering of NiCoP Sites via N, Ru Dual Doping for Bifunctional Water Electrolysis DOI

Meng Zhou,

Wenzhi Jia, Tian Tian

и другие.

Inorganic Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 21, 2024

Exploiting highly effective electrocatalysts is a challenge for boosting the overall efficiency of water splitting. Herein, we present nitrogen and ruthenium dual-doping strategy to tailor electronic structures NiCoP(N, Ru–NiCoP), creating high-performance bifunctional electrodes hydrogen evolution reaction (HER) oxygen (OER). The approach favorable interactions within NiCoP CoP, yielding near-zero Gibbs free energy H adsorption. Consequently, optimized N, Ru–NiCoP exhibit exceptional activities, with overpotentials 53 405 mV at 100 mA cm–2 HER OER, respectively. Notably, their performance surpasses that commercial Pt/C RuO2 catalysts large current densities, demonstrating potential industrial splitting applications. Moreover, water-splitting device achieves density 10 driving voltage only 1.54 V. This work provides an heteroatom doping develop low-cost active electrocatalysts.

Язык: Английский

Процитировано

1
Ru and Ruδ+ Synergistic Catalysis Efficiently Promotes 2,2,6,6-Tetramethyl-4-Piperidone Hydrogenation for 2,2,6,6-Tetramethyl-4-Piperidinol Preparation DOI
Ping Zhao, Bingcheng Li, Lili Zeng

и другие.

Опубликована: Янв. 1, 2024

Download This Paper Open PDF in Browser Add to My Library Share: Permalink Using these links will ensure access this page indefinitely Copy URL DOI

Язык: Английский

Процитировано

0
Ru and Ruδ+ synergistic catalysis efficiently promotes 2,2,6,6-Tetramethyl-4-Piperidone hydrogenation for 2,2,6,6-Tetramethyl-4-Piperidinol preparation DOI
Ping Zhao, Bingcheng Li, Lili Zeng

и другие.

Molecular Catalysis, Год журнала: 2024, Номер 563, С. 114239 - 114239

Опубликована: Май 24, 2024

Язык: Английский

Процитировано

0
Anatase‐Rutile TiO2@V4C3Tx MXene for Omnidirectional Electrocatalytic Water Splitting DOI Creative Commons

Neermunda Shabana,

Punnoli Muhsin,

Ya‐Yun Yang

и другие.

Advanced Materials Interfaces, Год журнала: 2024, Номер unknown

Опубликована: Авг. 27, 2024

Abstract The quest for composite materials with unique features that each component, inherently, does not have is always an aspirational but challenging task. Among Transition metal oxides (TMOs), TiO 2 emerged as a prototype due to its earth abundance, environmental friendliness, and cost‐effectiveness, which has shown high activity photocatalytic hydrogen evolution. Unfortunately, inert electrocatalytic evolution reaction (HER) because it poor electrical conductivity unfavorable adsorption/desorption behavior. Herein the revitalization of overall water splitting, i.e., both HER oxygen (OER) reported by anchoring rutile‐anatase (a/r) nanoparticles on ‐OH/‐F terminated V 4 C 3 T x MXene, giving a/r @V heterostructure. synergetic effect showcases remarkable pH‐independent overpotential 35, 39, 82 mV in 0.5 m H SO , 1 KOH, phosphate‐buffered saline (PBS) respectively. catalyst also exhibits OER lowest 217, 267, 292 PBS respectively, outperforms pure . These findings, first time, support success anatase‐rutile MXene omnidirectional performance, low pH independence, pave avenue finding cost‐effective catalysts splitting.

Язык: Английский

Процитировано

0