Chemical Communications,
Год журнала:
2024,
Номер
unknown
Опубликована: Янв. 1, 2024
A
hierarchical
WC/NiCoW
nanotube
array
enhances
HER
performance
by
promoting
bubble
surface
release.
The
WC–NiCoW
interface
optimizes
electronic
structure,
thus
achieving
high
activity
and
stability
across
alkaline,
acidic,
neutral
electrolytes.
Inorganic Chemistry,
Год журнала:
2025,
Номер
unknown
Опубликована: Фев. 25, 2025
The
slow
kinetics
of
the
oxygen
evolution
reaction
limits
electrochemical
overall
water
splitting
(OWS).
To
address
this,
integrating
thermodynamically
favorable
organic
electro-oxidation
with
hydrogen
(HER)
can
enhance
production
performance.
Notably,
5-amino-1H-tetrazole
oxidation-assisted
OWS
not
only
achieves
energy-saving
but
also
produces
energetic
compound
5,5'-azotetrazolate
salts
in
a
mild
manner.
This
necessitates
in-depth
research
into
catalysts
straightforward
synthesis
methods
and
excellent
performance
for
production.
Supported
single-atom
(SACs)
have
high
dispersibility
reduce
use
precious
metals.
Here,
we
report
highly
efficient
HER
catalyst
consisting
Ru
single
atom
anchored
on
low-crystallinity
Zn-doped
Ni2P
nanosheets
(Ru-LC-ZNP).
low
overpotential
28.9
mV
at
-10
mA
cm-2,
demonstrating
stability
least
100
h
no
noticeable
activity
loss.
experimental
results
indicate
that
outstanding
alkaline
be
attributed
to
synergistic
optimization
between
support.
By
coupling
5-AT
electro-oxidation,
cell
voltage
electrolysis
enormously
reduced
1.26
V
10
cm-2.
work
provides
insights
mechanism
supported
SACs
as
active
catalysts.
Abstract
Facing
the
complex
application
environment
and
overall
inefficiency
in
complete
water‐splitting
process,
development
of
highly
efficient
stable
catalytic
materials
is
urgently
required.
This
study
innovatively
proposes
for
first
time
implements
a
rapid
synthesis
technique
driven
by
microwave‐induced
sulfur
sublimation,
successfully
preparing
MS
2
/RuS
(M
=
Co,
Fe,
Ni)
heterostructure
interfaces
with
high
structural
stability
uniform
active
site
distribution
within
merely
60
s.
By
incorporating
iron‐group
sulfides,
electronic
structure
pyrite‐type
RuS
effectively
modulated,
enabling
developed
@G
catalyst
to
exhibit
superior
activity
alkaline
environments.
Particularly,
cobalt‐based
sulfide
regulated
(CoS
@G)
achieves
mass
hydrogen
evolution
reaction
(HER)
that
15.4
times
20
wt.%
Pt/C,
oxygen
(OER),
it
surpasses
commercial
IrO
two
orders
magnitude.
research
not
only
provides
new
pathway
enhancing
performance
environmental
adaptability
catalysts
but
also
presents
simple
universal
method
boost
through
synergistic
modulation
strategy.