Metal–metal oxide hybrid catalysts for electrocatalytic CO2 reduction reaction DOI Open Access
Zuohuan Chen, Yifan Ye, Kun Jiang

и другие.

Chemical Physics Reviews, Год журнала: 2024, Номер 5(4)

Опубликована: Ноя. 20, 2024

Electrocatalytic CO2 reduction is emerging as a promising technology to address anthropogenic carbon emissions, with the searching of effective catalysts being primary barrier toward industrial implementation. This review starts from long-standing debates over role subsurface oxygen and positively charged metal sites (Mδ+) within oxide-derived catalysts. Thereafter, we focus on strategy constructing metal–metal oxide hybrid catalysts, which enriched M1–O–M2 heterojunctions that capable maintaining positive valence state active improving performance. Specifically, advances in for CO2-to-C1 conversions are overviewed selective CO, formate, or CH4 production, respectively. summarize interfacial engineering approaches Cu/MOx aimed at C2+ including boundary density, morphology effect MOx support, choice MOx, their interaction manipulation Cu sites. concludes an outlook challenges future directions developing precisely controlled in-depth understanding structure–performance relationship. Continued interdisciplinary collaborations materials science, surface chemistry, analytical methodology, theoretical modeling will be pivotal overcoming existing pushing frontiers research.

Язык: Английский

Improved performances toward electrochemical carbon dioxide and oxygen reductions by iron-doped stannum nanoparticles DOI

Jiangtao Zhu,

Quan Zhang, Caiyun Wang

и другие.

Nanoscale, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

We have designed a catalyst that can efficiently convert CO 2 into through Zn–CO batteries and the electrochemical RR, addressing both energy conversion environmental concerns simultaneously.

Язык: Английский

Процитировано

2
High entropy catalysts in electrolytic water splitting: A review from properties to applications DOI
Zhijie Zhang, Yu Ning, Yilin Dong

и другие.

Chemical Engineering Journal, Год журнала: 2024, Номер 498, С. 155736 - 155736

Опубликована: Сен. 12, 2024

Язык: Английский

Процитировано

9
Dual Effect of Oxygen Vacancy‐Enriched TiO2 Interlayer in Si Photocathode for Enhanced Photoelectrochemical CO2 Reduction to HCOOH DOI Open Access
Jun Xing, Junxia Shen,

Zhihe Wei

и другие.

Small, Год журнала: 2025, Номер unknown

Опубликована: Март 6, 2025

Integrating nanostructured catalysts with semiconductors is a prevalent strategy for the design of photoelectrochemical (PEC) photocathodes toward CO2 reduction reaction (CO2RR). However, it still challenge to achieve high efficiency and selectivity due incompatible catalyst/semiconductor heterogeneous interface. Here, proposed that engineering oxygen vacancy in TiO2 interlayer plays multifunctional role boosting PEC activity CO2RR on Bi catalyst modified Si photocathode (denoted as Si/dT/Bi). It discovered accelerates carrier transport. These vacancies also promote growth Bi-based sponge-like nanostructures during photoelectro-deposition process. Numerous experimental results combined situ attenuated total reflection surface-enhanced infrared absorption spectroscopy reveal these nano-catalysts Si/dT/Bi provide density active sites adsorption kinetics HCOOH production by accelerating formation key intermediate *OCHO. This provides unique route future advancements technologies.

Язык: Английский

Процитировано

1
Induced C−C Coupling by Amorphous‐Crystalline Hybrid Structure for Selective CO2 Photoreduction into C2 Fuels DOI Open Access

Dongpo He,

Guangbing Huang,

Jun Hu

и другие.

Advanced Energy Materials, Год журнала: 2024, Номер unknown

Опубликована: Авг. 21, 2024

Abstract Selective photoreduction of carbon dioxide (CO 2 ) into high‐value C products remains a formidable challenge due to the elusive C−C coupling step. Herein, novel concept is first introduced that an amorphous‐crystalline hybrid structure can galvanize previously inert metal atoms, thereby establishing highly active dual sites. This ingenious configuration promotes coupling, paving way for CO products. Taking Bi MoO 6 nanosheets anchored by amorphous FeOOH species as example, X‐ray photoelectron spectroscopy (XPS) spectra and absorption near edge density functional theoretical (DFT) calculations confirm electron transfer from nanosheets. Thus, introduction activates nonoperative sites construction Bi−Mo sites, verified in situ XPS DFT calculations. Gibbs free energy revealed formation barrier hugely lowed 3.41 0.45 eV thanks presence species. Therefore, FeOOHBi are game changer, delivering sole liquid product, acetic acid, with impressive selectivity ≈86.9%. In contrast, lag behind, only capable producing monoxide photoreduction.

Язык: Английский

Процитировано

5
Rational Strategies for Preparing Highly Efficient Tin‐, Bismuth‐ or Indium Based Electrocatalysts for Electrochemical CO2 Reduction to Formic acid DOI
Ziyuan Yang,

Yuxia Jin,

Zhongbao Feng

и другие.

ChemSusChem, Год журнала: 2024, Номер unknown

Опубликована: Окт. 8, 2024

Electrochemical carbon dioxide reduction reaction (CO

Язык: Английский

Процитировано

3
Strong and uniform Sn-S bond strength in tin sulfides-based electrocatalysts enables efficient CO2-to-formate conversion DOI
Guoyu Hou,

Hong‐Hua Cui,

Yicheng Li

и другие.

Science China Materials, Год журнала: 2025, Номер unknown

Опубликована: Апрель 8, 2025

Язык: Английский

Процитировано

0
Efficient degradation of sulfamethoxazole by a three-dimensional electro-Fenton system based on B-Fe@BC particle catalysts: A new non-radical dominated mechanism DOI
Yuxin Liu, Kangping Cui, Lingjun Wang

и другие.

Separation and Purification Technology, Год журнала: 2025, Номер unknown, С. 133269 - 133269

Опубликована: Апрель 1, 2025

Язык: Английский

Процитировано

0
CoFe-(Oxy)Hydroxide@Co3O4-CeO2 Core–Shell Nanorods on Nickel Foam for Oxygen Evolution Reaction DOI

Zhuo-Lin Qing,

Hao Hu, Jianli Mi

и другие.

ACS Applied Nano Materials, Год журнала: 2024, Номер 7(17), С. 20370 - 20379

Опубликована: Сен. 2, 2024

The development of highly active and cost-effective electrocatalysts, such as transition-metal oxides (oxy)hydroxides, for the oxygen evolution reaction (OER) is great importance in water-splitting electrolyzers. Building nanohybrids an effective strategy to improve OER activity (oxy)hydroxides. In this work, we present a feather-like CoFe-(oxy)hydroxide@Co3O4-CeO2 3D hierarchical heterostructure on nickel foam (NF) by coupling amorphous CoFe-(oxy)hydroxide Co3O4-CeO2 hybrid nanorods enhanced performance. Owing synergistic effect interface engineering CoFe-(oxy)hydroxide, Co3O4, CeO2, well large electrochemically surface area with exposed sites, as-prepared electrode exhibits superior required overpotential 0.228 V achieve 10 mA cm–2 1.0 M KOH, which among best values Co3O4-based CoFe-based electrocatalysts.

Язык: Английский

Процитировано

0
Stable P3HT-PC61BM inverted organic solar cells based on cerium oxide as electron transport layer DOI

S. T. H. Abidi,

Amir Hossein Habibi,

Hayley Melville

и другие.

New Journal of Chemistry, Год журнала: 2024, Номер 48(47), С. 19779 - 19790

Опубликована: Янв. 1, 2024

Cerium oxide as an electron transport layer leads to stable P3HT-PC 61 BM inverted organic solar cells.

Язык: Английский

Процитировано

0
Metal–metal oxide hybrid catalysts for electrocatalytic CO2 reduction reaction DOI Open Access
Zuohuan Chen, Yifan Ye, Kun Jiang

и другие.

Chemical Physics Reviews, Год журнала: 2024, Номер 5(4)

Опубликована: Ноя. 20, 2024

Electrocatalytic CO2 reduction is emerging as a promising technology to address anthropogenic carbon emissions, with the searching of effective catalysts being primary barrier toward industrial implementation. This review starts from long-standing debates over role subsurface oxygen and positively charged metal sites (Mδ+) within oxide-derived catalysts. Thereafter, we focus on strategy constructing metal–metal oxide hybrid catalysts, which enriched M1–O–M2 heterojunctions that capable maintaining positive valence state active improving performance. Specifically, advances in for CO2-to-C1 conversions are overviewed selective CO, formate, or CH4 production, respectively. summarize interfacial engineering approaches Cu/MOx aimed at C2+ including boundary density, morphology effect MOx support, choice MOx, their interaction manipulation Cu sites. concludes an outlook challenges future directions developing precisely controlled in-depth understanding structure–performance relationship. Continued interdisciplinary collaborations materials science, surface chemistry, analytical methodology, theoretical modeling will be pivotal overcoming existing pushing frontiers research.

Язык: Английский

Процитировано

0