High-Entropy Structural Modification Strategy for O3-type Layered Sodium-Ion Cathode Materials with Enhanced Electrochemical Performance DOI
Xinjian Wan, Yanyun Zhang, Fangfang Dong

и другие.

ACS Applied Energy Materials, Год журнала: 2025, Номер unknown

Опубликована: Май 7, 2025

Язык: Английский

Improving upon rechargeable battery technologies: On the role of high-entropy effects DOI
Zihao Zhou, Yuan Ma, Torsten Brezesinski

и другие.

Energy & Environmental Science, Год журнала: 2024, Номер unknown

Опубликована: Янв. 1, 2024

An overview of high-entropy strategies for batteries is provided, emphasizing their unique structural/compositional attributes and positive effects on stability performance, alongside a discussion key challenges future research directions.

Язык: Английский

Процитировано

10

Revealing Microstructure and Mechanism of Layered Oxide Cathodes for Sodium-ion Batteries by Advanced TEM Techniques DOI Creative Commons
Sheng Xu,

Lihua Zhao,

Shukui Li

и другие.

Chemical Communications, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

This review provides insight into the TEM applications for studying layered oxides SIBs, and broadens their potential future advancements.

Язык: Английский

Процитировано

1

High-entropy engineering enables O3-type layered oxide with high structural stability and reaction kinetic for sodium storage DOI
Xiong Wang, Qiaoling Kang, Jiaze Sun

и другие.

Journal of Colloid and Interface Science, Год журнала: 2025, Номер unknown, С. 137438 - 137438

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

1

Entropic design strategy to enhance cycling stability of layered iron-based fluorophosphates in sodium-ion batteries DOI
Huijie Ren, Jian Qin,

Xiaohan Yang

и другие.

Journal of Energy Storage, Год журнала: 2025, Номер 121, С. 116578 - 116578

Опубликована: Апрель 11, 2025

Язык: Английский

Процитировано

0

Transformative Effect of Li Salt for Proactively Mitigating Interfacial Side Reactions in Sodium-Ion Batteries DOI Creative Commons

Jooeun Byun,

Joon Ha Chang, Chihyun Hwang

и другие.

Nano-Micro Letters, Год журнала: 2025, Номер 17(1)

Опубликована: Апрель 21, 2025

Abstract The robust respective formations of a solid electrolyte interphase (SEI) and pillar at the surfaces hard carbon O3-type positive electrodes are consequences integrating LiPF 6 salt into sodium-ion battery that considerably strengthens both interfaces negative electrodes. improvement cycle performances due to formation highly passivating SEI on electrode is induced by alternated solvation structure following addition Li salt, which inhibits electron leakage from further decomposition. with incorporated less soluble than Na-based SEI, passivation ability initially formed can thus be well preserved. Conversely, gas evolution caused oxygen release reduced marginal surface intercalation ions O3-positive electrode. Additionally, LiF layer forms O3 diminishes additional deterioration after formation. Compared fluoroethylene carbonate additive typically applied, simultaneously strengthened interface yields major improvements in capacity retention.

Язык: Английский

Процитировано

0

Inhibiting Oxygen Activity and Phase Transition in Cu‐F Doped Ni‐Mn Layered Oxide Cathodes for Sodium‐Ion Batteries DOI
Xilong Zhang,

Fei Xie,

Jinbao Han

и другие.

Small, Год журнала: 2025, Номер unknown

Опубликована: Апрель 25, 2025

Abstract Sodium‐ion batteries (SIBs) have emerged as a promising alternative for large‐scale energy storage due to the abundance of sodium resources. Among cathode materials, layered oxides shown exceptional potential, yet their practical application is hindered by structural instability during electrochemical cycling. In this study, challenge addressed introducing novel strategy Cu and F dual doping into octahedral ligand field oxygen‐activated P2‐type Na 0.67 Ni 0.33 Mn O 2 oxides. Through comprehensive suite advanced characterization techniques, unprecedented insights modulation oxygen redox activity are uncovered. Ex situ X‐ray photoelectron spectroscopy Raman reveal enhanced reversibility stability in chemical bonding, while diffraction analysis indicates suppression detrimental phase transitions, ensuring stable unobstructed + diffusion pathway. Density functional theory calculations further elucidate that Cu‐F co‐doping reduces overlap between t g orbitals 2p orbitals, thereby inhibiting activity. Remarkably, co‐doped material exhibits significantly improved capacity retention rate performance. This work not only advances fundamental understanding engineering but also provides transformative approach designing high‐performance materials SIBs, paving way widespread adoption systems.

Язык: Английский

Процитировано

0

High-Entropy Structural Modification Strategy for O3-type Layered Sodium-Ion Cathode Materials with Enhanced Electrochemical Performance DOI
Xinjian Wan, Yanyun Zhang, Fangfang Dong

и другие.

ACS Applied Energy Materials, Год журнала: 2025, Номер unknown

Опубликована: Май 7, 2025

Язык: Английский

Процитировано

0