Boosting the ionic conductivity of amorphous oxychloride solid electrolytes via different degrees of amorphization DOI Open Access

Junquan Ou,

Ishani Senevirathna,

Vignyatha Reddy Tatagari

и другие.

Energy Materials, Год журнала: 2025, Номер 5(8)

Опубликована: Апрель 22, 2025

Solid electrolytes provide improved safety, greater electrochemical and thermal stability, better compatibility with high-energy materials than liquid electrolytes. Compared to crystalline solid electrolytes, amorphous offer reduced grain boundary resistance, enhanced processability, isotropic ionic conductivity superior mechanical properties. Herein, the impacts of varying ball milling intensities on degree amorphization 1.6Li2O-TaCl5 oxychloride thus its are investigated. It is shown that can reach as high 8.30 × 10-3 S/cm at room temperature by increasing amorphization. Furthermore, sample exhibiting highest also releases largest stored enthalpy upon heating, indicating structural defects in play a crucial role enhancing their Li-ion conductivities. This discovery opens door for boosting conductivities other future

Язык: Английский

Polymer Electrolytes for Sustainable Energy: A Minireview on Zero-Carbon Storage and Conversion DOI
Mahmood Alhajj,

Ling Shing Liau,

Abdo Mohammed Al‐Fakih

и другие.

ACS Applied Polymer Materials, Год журнала: 2025, Номер unknown

Опубликована: Март 12, 2025

Язык: Английский

Процитировано

0

Boosting the ionic conductivity of amorphous oxychloride solid electrolytes via different degrees of amorphization DOI Open Access

Junquan Ou,

Ishani Senevirathna,

Vignyatha Reddy Tatagari

и другие.

Energy Materials, Год журнала: 2025, Номер 5(8)

Опубликована: Апрель 22, 2025

Solid electrolytes provide improved safety, greater electrochemical and thermal stability, better compatibility with high-energy materials than liquid electrolytes. Compared to crystalline solid electrolytes, amorphous offer reduced grain boundary resistance, enhanced processability, isotropic ionic conductivity superior mechanical properties. Herein, the impacts of varying ball milling intensities on degree amorphization 1.6Li2O-TaCl5 oxychloride thus its are investigated. It is shown that can reach as high 8.30 × 10-3 S/cm at room temperature by increasing amorphization. Furthermore, sample exhibiting highest also releases largest stored enthalpy upon heating, indicating structural defects in play a crucial role enhancing their Li-ion conductivities. This discovery opens door for boosting conductivities other future

Язык: Английский

Процитировано

0