Batteries & Supercaps,
Год журнала:
2023,
Номер
6(9)
Опубликована: Июль 26, 2023
Abstract
As
emerging
energy
storage
devices,
sodium‐ion
batteries
(SIBs)
are
perceived
as
promising
alternatives
to
lithium‐ion
(LIBs)
due
their
low
cost
and
high
safety.
The
cathodic
side
plays
a
crucial
role
in
determining
the
density
well
service
life
of
SIBs,
polyanionic
cathode
materials
featured
by
excellent
cycle
stability,
flexible
operating
voltage
suitable
overall
electrochemical
properties.
However,
intrinsic
inferior
electronic
conductivity
limits
rate
performance.
Recently,
possibility
employing
advanced
electrospinning
techniques
fabricate
has
been
explored.
facile
can
greatly
facilitate
ionic
conduction
cathodes
constructing
three‐dimensional
(3D)
conductive
networks
with
one‐dimensional
(1D)
nanofibers,
thus
improves
In
this
review,
we
summarize
research
progress
electro‐spun
applications
present
future
prospects
challenges
polyanions
faced
ever‐increasing
demand
storage.
Advanced Materials,
Год журнала:
2024,
Номер
36(25)
Опубликована: Март 8, 2024
Abstract
Room‐temperature
sodium‐sulfur
(RT‐Na/S)
batteries
are
promising
alternatives
for
next‐generation
energy
storage
systems
with
high
density
and
power
density.
However,
some
notorious
issues
hampering
the
practical
application
of
RT‐Na/S
batteries.
Besides,
working
mechanism
under
conditions
such
as
sulfur
loading,
lean
electrolyte,
low
capacity
ratio
between
negative
positive
electrode
(N/P
ratio),
is
essential
importance
applications,
yet
significance
these
parameters
has
long
been
disregarded.
Herein,
it
comprehensively
reviewed
recent
advances
on
Na
metal
anode,
S
cathode,
separator
engineering
The
discrepancies
laboratory
research
elaborately
discussed,
endeavors
toward
applications
highlighted,
suggestions
values
crucial
rationally
proposed.
Furthermore,
an
empirical
equation
to
estimate
actual
pouch
cells
proposed
first
time,
making
possible
evaluate
gravimetric
conditions.
This
review
aims
reemphasize
vital
bridge
gaps
applications.
Angewandte Chemie International Edition,
Год журнала:
2024,
Номер
63(21)
Опубликована: Март 12, 2024
Abstract
Sodium‐ion
batteries
(SIBs)
present
a
promising
avenue
for
next‐generation
grid‐scale
energy
storage.
However,
realizing
all‐climate
SIBs
operating
across
wide
temperature
range
remains
challenge
due
to
the
poor
electrolyte
conductivity
and
instable
electrode
interphases
at
extreme
temperatures.
Here,
we
propose
comprehensively
balanced
by
pairing
carbonates
with
low‐freezing‐point
low‐polarity
ethyl
propionate
solvent
which
enhances
ion
diffusion
Na
+
‐desolvation
kinetics
sub‐zero
Furthermore,
leverages
combinatorial
borate‐
nitrile‐based
additive
strategy
facilitate
uniform
inorganic‐rich
interphases,
ensuring
excellent
rate
performance
cycle
stability
over
from
−45
°C
60
°C.
Notably,
Na||sodium
vanadyl
phosphate
cell
delivers
remarkable
capacity
of
105
mAh
g
−1
high
2
C
−25
In
addition,
cells
exhibit
cycling
range,
maintaining
retention
84.7
%
3,000
cycles
95.1
500
cycles.
The
full
also
exhibits
impressive
range.
This
study
highlights
critical
role
interphase
engineering
enabling
that
function
optimally
under
diverse
climatic
environments.
Advanced Functional Materials,
Год журнала:
2024,
Номер
34(18)
Опубликована: Янв. 7, 2024
Abstract
Sodium
plating–stripping
with
high
reversibility
is
still
an
intractable
challenge
for
sodium
metal‐based
batteries
due
to
the
fragile
natural
solid‐electrolyte
interphase
(SEI)
film
and
severe
Na
dendrites
growth.
Herein,
a
surface
reconstruction
strategy
proposed
rooted
heterogeneous
interlayer
derived
from
in
situ
reactions
between
tin
selenide
metal
(
abbr
.
Na/SnSe)
produced
regulate
+
deposition
behavior
impede
dendrite
The
sodiophilic
15
Sn
4
component
demonstrates
robust
combination
suppression
capability,
inhibiting
fracture
delamination
problems
during
volume
variation.
Meanwhile,
superionic
2
Se
ingredient
contributes
optimized
conduction
efficiency
low
nucleation
overpotential,
enabling
uniform
distribution
of
electrical
fields
ultimately
eliminating
dendrites.
Consequently,
reconfigured
multifunctional
Na/SnSe
realizes
long‐term
lifespan
over
2400
h
at
0.5
mA
cm
−2
/1
mAh
symmetric
cell
extremely
voltage
hysteresis.
Moreover,
assembled
Na/SnSe||NaNi
1/3
Fe
Mn
O
pouch
achieves
exceptional
cycling
stability
capacity
retention
(90.4
g
−1
after
1800
cycles
current
density
A
),
exploiting
avenue
designing
durable
SEI
layer
high‐quality
batteries.
Advanced Functional Materials,
Год журнала:
2024,
Номер
34(36)
Опубликована: Март 28, 2024
Abstract
The
utilization
of
Al
current
collector
for
the
sodium
deposition
is
considered
ideal
achieving
a
low‐cost,
high‐energy‐density
metal
battery.
However,
poor
affinity
between
and
leads
to
uneven
plating/stripping,
which
poses
significant
challenge
in
pursuit
stable
anode.
Herein,
heterostructure
(V/VO
x
)‐modified
proposed,
effectively
enables
highly
reversible
Na
plating/stripping
process,
inhibits
dendrites
growth.
Experimental
results
theoretical
calculations
demonstrate
that
V/VO
@Al
not
only
exhibits
strong
sodiophilicity,
but
also
ensures
uniform
density
distribution.
Thanks
these
merits,
assembled
cells
excellent
performances
with
low
nucleation
overpotential
(11
mV
at
1
mA
cm
−2
),
long
cycle
life
(2750
h)
minimal
voltage
polarization
(13
).
More
impressively,
full
cell
displays
remarkable
stability,
sustaining
1400
cycles
10
C.
This
work
provides
valuable
insights
development
more
batteries.
The
interfacial
wettability
between
electrodes
and
electrolytes
could
ensure
sufficient
physical
contact
fast
mass
transfer
at
the
gas-solid-liquid,
solid-liquid,
solid-solid
interfaces,
which
improve
reaction
kinetics
cycle
stability
of
rechargeable
metal-based
batteries
(RMBs).
Herein,
engineering
multiphase
interfaces
is
summarized
from
electrolyte
electrode
aspects
to
promote
interface
rate
durability
RMBs,
illustrates
revolution
that
taking
place
in
this
field
thus
provides
inspiration
for
future
developments
RMBs.
Specifically,
review
presents
principle
macro-
microscale
summarizes
emerging
applications
concerning
effect
on
Moreover,
deep
insight
into
development
provided
outlook.
Therefore,
not
only
insights
but
also
offers
strategic
guidance
modification
optimization
toward
stable
electrode-electrolyte
Advanced Materials,
Год журнала:
2023,
Номер
36(1)
Опубликована: Сен. 20, 2023
Inorganic
all-solid-state
sodium
batteries
(IASSSBs)
are
emerged
as
promising
candidates
to
replace
commercial
lithium-ion
in
large-scale
energy
storage
systems
due
their
potential
advantages,
such
abundant
raw
materials,
robust
safety,
low
price,
high-energy
density,
favorable
reliability
and
stability.
solid
electrolytes
(ISSEs)
an
indispensable
component
of
IASSSBs,
gaining
significant
attention.
Herein,
this
review
begins
by
discussing
the
fundamentals
ISSEs,
including
ionic
conductivity,
mechanical
property,
chemical
electrochemical
stabilities.
It
then
presents
crystal
structures
advanced
ISSEs
(e.g.,
β/β''-alumina,
NASICON,
sulfides,
complex
hydride
halide
electrolytes)
related
issues,
along
with
corresponding
modification
strategies.
The
also
outlines
effective
approaches
for
forming
intimate
interfaces
between
working
electrodes.
Finally,
current
challenges
critical
perspectives
developments
possible
directions
improve
interfacial
contacts
future
practical
applications
highlighted.
This
comprehensive
aims
advance
understanding
development
next-generation
rechargeable
IASSSBs.
Energy & Environmental Science,
Год журнала:
2024,
Номер
17(16), С. 6113 - 6126
Опубликована: Янв. 1, 2024
The
high
voltage
electrolyte
strategy:
a
highly
oxidation
resistant
solvent
occupies
the
solvation
site
to
both
expand
electrochemical
window
and
form
stable
interface,
thus
inhibiting
irreversible
phase
transition
of
cathode
materials.
Advanced Functional Materials,
Год журнала:
2024,
Номер
unknown
Опубликована: Авг. 5, 2024
Abstract
Sodium
metal
is
regarded
as
an
optimal
anode
material
for
high‐energy‐density
sodium‐ion
batteries
(SIBs).
However,
during
the
processes
of
sodium
deposition
and
stripping,
failure
solid
electrolyte
interphase
(SEI)
film
leads
to
continuous
accumulation
inactive
sodium,
thereby
compromising
cycling
reversibility
battery.
Here,
a
novel
fluoride
heterointerface
layer
generated
constructed
through
in
situ
manipulation
reaction
between
TiF
4
Na.
The
reconstructed
NaF/TiF
3
interface
layer,
which
tightly
anchors
metal,
effectively
suppresses
formation
dendrites
charge‐discharge
process.
highly
sodium‐philic
component
exhibits
strong
binding
with
Na
ions,
while
NaF
reduces
+
diffusion
energy
barrier,
significantly
enhancing
kinetics.
Due
successful
artificial
construction
this
Na/TiF
composite
electrode
demonstrates
exceptional
ultra‐long
stability
2370
h
symmetric
cells
(0.5
mAh
cm
−2
).
Density
functional
theory
(DFT)
calculations
further
validate
functionality
each
protective
layer.
When
paired
NaNi
1/3
Fe
Mn
O
2
cathode
pouch
cell,
it
up
2000
cycles
at
current
densities
C
C,
maximum
density
output
483.1
Wh
kg
−1
(power
density:
320.8
W
Abstract
The
practical
application
of
sodium
metal
batteries
faces
significant
challenges,
such
as
unpredictable
Na
dendrite
growth
and
the
instability
solid‐electrolyte
interphase.
Herein,
a
novel
separator
composed
glass
fiber
(GF)
impregnated
with
zeolitic
imidazolate
framework
(ZIF‐8)
layer,
referred
to
GF@ZIF‐8
is
introduced.
This
optimized
exhibits
enhanced
anti‐puncture
strength,
high
transference
number,
fast
Na‐ion
conductivity.
ZIF‐8
layer
effectually
regulates
spatial
concentration
distribution
ions
their
flux
vectors,
leading
homogeneous
deposition
Na.
Consequently,
Na||Na
symmetric
cells
utilizing
demonstrate
outstanding
cyclability,
achieving
850
h
at
0.5
mA
cm
−2
420
1
,
outperforming
bare
GF
(<180
h).
Furthermore,
assembled
3
V
2
(PO
4
)
||GF@ZIF‐8||Na
full
exhibit
remarkably
improves
rate
performance
(81
g
−1
30
C),
cyclability
(93.5%
capacity
retention
over
900
cycles
10
low‐temperature
applicability
(78
under
0.2
C
−40
°C).
simulations
reveal
that,
except
for
regulating
flux,
introduction
porous
on
also
enhances
local
electric
field
near
anode,
thereby
boosting
transfer
+
which
contributes
improved
storage
performance.
