MOF and related composites as selective functional separators and interlayers for Li-S batteries

Energy Materials, Год журнала: 2025, Номер 5(8)

Опубликована: Март 18, 2025

Lithium-sulfur (Li-S) batteries are one of the most promising technologies compared to lithium-ion-based ones, mainly due their outstanding high energy density (2,567 Wh/kg). Nonetheless, Li-S still face important drawbacks, namely shuttle effect caused by polysulfide dissolution into electrolyte and escape from cathode, leading active material loss ultimately anode passivation. Mitigating this is crucial boost at a large scale rational design separator or interlayer considered as an effective solution. Metal-Organic Frameworks related composites have been recently proposed candidates selectively capture polysulfides, tunable structures compositions ordered micro- meso-porosity which can sieve polysulfides through physical barriers chemical sorption catalyze conversion kinetics. Moreover, once introduced composite membranes functional separators interlayers, promotes easy inclusion in devices. This short review summarizes recent progress field, emphasizing different types interlayers integrating Frameworks, proposes new research directions optimize these systems.

Язык: Английский

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Zirconium-based metal–organic frameworks for electrochemical energy storage

Coordination Chemistry Reviews, Год журнала: 2025, Номер 538, С. 216704 - 216704

Опубликована: Апрель 19, 2025

Язык: Английский

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Benzothiadiazole-Functionalized Two-Dimensional Zr-MOF Nanosheets as Efficient Separator Coatings for Li–S Batteries

ACS Applied Nano Materials, Год журнала: 2025, Номер unknown

Опубликована: Май 16, 2025

Язык: Английский

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A review on solid-state electrolytes for Li-S batteries: Encompassing background to recent advancements

Materials Research Bulletin, Год журнала: 2024, Номер 184, С. 113249 - 113249

Опубликована: Дек. 10, 2024

Язык: Английский

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