Metal Cluster-based Crystalline Materials for the Electrocatalytic Reduction of Carbon Dioxide DOI
Fanfei Meng, Man Dong, Jingting He

и другие.

ACS Materials Letters, Год журнала: 2024, Номер 7(1), С. 229 - 249

Опубликована: Дек. 16, 2024

Given the increasingly severe global climate change and energy crisis, conversion of carbon dioxide (CO2) into very valuable chemicals has been proposed as an attractive solution. The electrocatalytic CO2 reduction reaction (eCO2RR) represents a remarkably efficient pathway for reducing under mild conditions. Metal cluster-based crystalline materials (MCMs) have garnered significant interest in area CO2RR because their elevated concentration active sites, tunable backbone structures, excellent stability. These enable precise control metal valence states charge transfer pathways, offering variety pathways CO2RR. Herein, we examine utilization MCMs eCO2RR recent years. We cover fundamental principles reduction, synthesis approaches these materials, connection between structural characteristics catalytic performance. Additionally, paper delves challenges opportunities presented by enhancing efficiency selectivity. aim to provide researchers with new perspective on field eCO2RR, thereby improving understanding relationship structure Ultimately, this work seeks advance technology contributing significantly sustainable production mitigation greenhouse gas emissions.

Язык: Английский

Atomic Design of Copper Active Sites in Pristine Metal–Organic Coordination Compounds for Electrocatalytic Carbon Dioxide Reduction DOI Creative Commons
Juan Wang, Qingbo Wa,

Qi Diao

и другие.

Small Methods, Год журнала: 2024, Номер 8(11)

Опубликована: Май 20, 2024

Abstract Electrocatalytic carbon dioxide reduction reaction (CO 2 RR) has emerged as a promising and sustainable approach to cut emissions by converting greenhouse gas CO value‐added chemicals fuels. Metal–organic coordination compounds, especially the copper (Cu)‐based which feature well‐defined crystalline structures designable metal active sites, have attracted much research attention in electrocatalytic RR. Herein, recent advances of electrochemical RR on pristine Cu‐based compounds with different types Cu sites are reviewed. First, general pathways briefly introduced. Then highly efficient conversion various kinds (e.g., single‐Cu site, dimeric‐Cu multi‐Cu heterometallic site) is systematically discussed, along corresponding catalytic mechanisms. Finally, some existing challenges potential opportunities for this direction provided guide rational design metal–organic their practical application

Язык: Английский

Процитировано

4
Tailored High-Entropy Alloy Nanomaterials for Electrocatalytic Applications DOI
Chaohui Wang, Yunhao Wang, Yuecheng Xiong

и другие.

EnergyChem, Год журнала: 2025, Номер unknown, С. 100155 - 100155

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

0
Synthesis of Two-Dimensional Metal Nanomaterials for Electrocatalytic Multielectron Transfer Reactions DOI
Yuecheng Xiong, Han Wu,

Yijia Cheng

и другие.

Chemistry of Materials, Год журнала: 2025, Номер unknown

Опубликована: Июнь 5, 2025

Язык: Английский

Процитировано

0
Metal–Organic Frameworks-Based Catalysts for Methane Production DOI
Lusheng Xu,

Qianzhe Zhang,

Zehai Xu

и другие.

Industrial & Engineering Chemistry Research, Год журнала: 2024, Номер 63(46), С. 19972 - 19993

Опубликована: Ноя. 11, 2024

Methane is important as an electrofuel (e-fuel), which can be efficiently converted into cleaner energy sources, thereby reducing carbon emissions and supporting the transition to sustainable energy. Because of their specific properties, metal–organic framework (MOF)-based catalysts have drawn significant attention methane production, such high surface area, multiple active sites, tunability, versatility, porosity. With growing progresses on MOFs catalytic behavior for this review focuses how enhance performance MOF-based through multicomponent design stability improvements. It addresses challenges faced in production using highlights critical requirements practical applications. The summarizes strategies designing with features by precursors construct multimetallic MOFs, single-atom MOF catalysts, functional composites. Moreover, recent advances including coordination structures compositions improved stability, are discussed. also provides overview application covering areas photocatalysis, electroreduction, biomethane production. Finally, it outlines suggests future directions

Язык: Английский

Процитировано

0
Metal Cluster-based Crystalline Materials for the Electrocatalytic Reduction of Carbon Dioxide DOI
Fanfei Meng, Man Dong, Jingting He

и другие.

ACS Materials Letters, Год журнала: 2024, Номер 7(1), С. 229 - 249

Опубликована: Дек. 16, 2024

Given the increasingly severe global climate change and energy crisis, conversion of carbon dioxide (CO2) into very valuable chemicals has been proposed as an attractive solution. The electrocatalytic CO2 reduction reaction (eCO2RR) represents a remarkably efficient pathway for reducing under mild conditions. Metal cluster-based crystalline materials (MCMs) have garnered significant interest in area CO2RR because their elevated concentration active sites, tunable backbone structures, excellent stability. These enable precise control metal valence states charge transfer pathways, offering variety pathways CO2RR. Herein, we examine utilization MCMs eCO2RR recent years. We cover fundamental principles reduction, synthesis approaches these materials, connection between structural characteristics catalytic performance. Additionally, paper delves challenges opportunities presented by enhancing efficiency selectivity. aim to provide researchers with new perspective on field eCO2RR, thereby improving understanding relationship structure Ultimately, this work seeks advance technology contributing significantly sustainable production mitigation greenhouse gas emissions.

Язык: Английский

Процитировано

0