Recent advances in 2D organic−inorganic heterostructures for electronics and optoelectronics DOI
Jahangir Khan,

Rana Tariq Mehmood Ahmad,

Junyang Tan

и другие.

SmartMat, Год журнала: 2022, Номер 4(2)

Опубликована: Ноя. 7, 2022

Abstract Two‐dimensional (2D) materials show outstanding properties such as dangling bond‐free surfaces, strong in‐plane while weak out‐of‐plane bonding, layer‐dependent electronic structures, and tunable optoelectronic properties, making them promising for numerous applications. Integrating 2D inorganics with organic to make van der Waals heterostructures at the thickness limit has created new platforms fabricating on‐demand multifunctional devices. To further broaden limited choices of inorganic‐based heterostructures, a wide range available have opened opportunities designing large numbers inorganic materials. This review aims attract attention researchers toward this emerging organic−inorganic field. We first highlight recent progress in their synthesis then discuss potential applications, field‐effect transistors, photodetectors, solar cells, neuromorphic computing In end, we present summary challenges

Язык: Английский

A comprehensive review on the electrochemical parameters and recent material development of electrochemical water splitting electrocatalysts DOI Creative Commons
Asha Raveendran,

Mijun Chandran,

Ragupathy Dhanusuraman

и другие.

RSC Advances, Год журнала: 2023, Номер 13(6), С. 3843 - 3876

Опубликована: Янв. 1, 2023

Electrochemical splitting of water is an appealing solution for energy storage and conversion to overcome the reliance on depleting fossil fuel reserves prevent severe deterioration global climate. Though there are several cells, hydrogen (H

Язык: Английский

Процитировано

350
Conductive Metal–Organic Frameworks with Tunable Dielectric Properties for Boosting Electromagnetic Wave Absorption DOI
Xue Zhang,

Xuelei Tian,

Yutian Qin

и другие.

ACS Nano, Год журнала: 2023, Номер 17(13), С. 12510 - 12518

Опубликована: Июнь 23, 2023

Metal-organic frameworks (MOFs) manifest enormous potential in promoting electromagnetic wave (EMW) absorption thanks to the tailored components, topological structure, and high porosity. Herein, rodlike conductive MOFs (cMOFs) composed of adjustable metal ions Zn, Cu, Co, or Ni ligands hexahydroxytriphenylene (HHTP) are prepared attain tunable dielectric properties for a EMW absorption. Specifically, influences cMOFs' composition, charge transport characteristic, crystalline anisotropy microstructure on performance ascertained, advancing understanding attenuation mechanisms MOFs. The boosted polarization losses derived from conjugation effects terminal groups, as well shape anisotropy, lead prominent cMOFs. Cu-HHTP confers minimum reflection loss (RLmin) -63.55 dB at thickness 2.9 mm maximum effective bandwidth 5.2 GHz. Moreover, Zn-HHTP showcases superiority S-band (2-4 GHz) with an RLmin -62.8 1.9 mm. This work not only hoists mechanistic structure-function relationships cMOFs but also offers guidelines preparing functional MOF materials.

Язык: Английский

Процитировано

215
Integration of Alloy Segregation and Surface CoO Hybridization in Carbon‐Encapsulated CoNiPt Alloy Catalyst for Superior Alkaline Hydrogen Evolution DOI
Yangdan Pan, Junkuo Gao,

Enjun Lv

и другие.

Advanced Functional Materials, Год журнала: 2023, Номер 33(41)

Опубликована: Июль 28, 2023

Abstract Constructing an efficient alkaline hydrogen evolution reaction (HER) catalyst with low platinum (Pt) consumption is crucial for the cost reduction of energy devices, such as electrolyzers. Herein, nanoflower‐like carbon‐encapsulated CoNiPt alloy catalysts composition segregation are designed by pyrolyzing morphology‐controlled and Pt‐proportion‐tuned metal–organic frameworks (MOFs). The optimized containing 15% NFs (15%: Pt mass percentage, NFs: nanoflowers) exhibits outstanding HER performance a overpotential 25 mV at current density 10 mA cm −2 , far outperforming those commercial Pt/C (47 mV) most advanced catalysts. Such superior activity originates from integration Co‐O hybridization. hierarchical structure guarantees full exposure sites. Density functional theory calculations suggest that components not only promote water dissociation but also facilitate adsorption process, synergistically accelerating kinetics HER. In addition, volcanically distributed surface oxygen content, mainly in form Co 3d O 2p hybridization, which another reason enhanced activity. This work provides feasible insights into design cost‐effective coordinating kinetic sites adjusting appropriate content.

Язык: Английский

Процитировано

153
Zirconium-based metal-organic frameworks for fluorescent sensing DOI

Chen Jia,

Tao He, Guo‐Ming Wang

и другие.

Coordination Chemistry Reviews, Год журнала: 2022, Номер 476, С. 214930 - 214930

Опубликована: Ноя. 15, 2022

Язык: Английский

Процитировано

138
Iron-based metal–organic frameworks and their derived materials for photocatalytic and photoelectrocatalytic reactions DOI
Yangdan Pan, Reza Abazari,

Beenish Tahir

и другие.

Coordination Chemistry Reviews, Год журнала: 2023, Номер 499, С. 215538 - 215538

Опубликована: Ноя. 1, 2023

Язык: Английский

Процитировано

129
Waste-Derived Catalysts for Water Electrolysis: Circular Economy-Driven Sustainable Green Hydrogen Energy DOI Creative Commons
Zhijie Chen, Sining Yun, Lan Wu

и другие.

Nano-Micro Letters, Год журнала: 2022, Номер 15(1)

Опубликована: Дек. 1, 2022

The sustainable production of green hydrogen via water electrolysis necessitates cost-effective electrocatalysts. By following the circular economy principle, utilization waste-derived catalysts significantly promotes development energy. Currently, diverse have exhibited excellent catalytic performance toward evolution reaction (HER), oxygen (OER), and overall (OWE). Herein, we systematically examine recent achievements in electrocatalysts for electrolysis. general principles design efficient are discussed, followed by illustration current strategies transforming wastes into Then, applications (i.e., carbon-based catalysts, transitional metal-based heterostructure catalysts) HER, OER, OWE reviewed successively. An emphasis is put on correlating catalysts' structure-performance relationship. Also, challenges research directions this booming field finally highlighted. This review would provide useful insights design, synthesis, electrocatalysts, thus accelerate economy-driven energy scheme.

Язык: Английский

Процитировано

122
Applications of Metal–Organic Frameworks and Their Derivatives in Electrochemical CO2 Reduction DOI Creative Commons
Chengbo Li,

Yuan Ji,

Youpeng Wang

и другие.

Nano-Micro Letters, Год журнала: 2023, Номер 15(1)

Опубликована: Апрель 30, 2023

Abstract Electrochemically reducing CO 2 to more reduced chemical species is a promising way that not only enables the conversion of intermittent energy resources stable fuels, but also helps build closed-loop anthropogenic carbon cycle. Among various electrocatalysts for electrochemical reduction, multifunctional metal–organic frameworks (MOFs) have been employed as highly efficient and selective heterogeneous due their ultrahigh porosity topologically diverse structures. Up now, great progress has achieved in design synthesis active MOF-related catalysts reduction reaction (CO RR), corresponding mechanisms thoroughly studied. In this review, we summarize recent applying MOFs derivatives RR, with focus on strategies electrolyzers. We first discussed different RR products introduced commonly applied electrolyzer configurations current system. Then, an overview several categories (CO, HCOOH, CH 4 , 3 OH, multi-carbon chemicals) generated from or via was discussed. Finally, offer some insights perspectives future development reduction. aim provide new into field further guide research large-scale applications.

Язык: Английский

Процитировано

83
Constructing Nitrogen‐Doped Carbon Hierarchy Structure Derived from Metal‐Organic Framework as High‐Performance ORR Cathode Material for Zn‐Air Battery DOI Open Access
Yangdan Pan, Junkuo Gao,

Yuwen Li

и другие.

Small, Год журнала: 2023, Номер 20(3)

Опубликована: Сен. 10, 2023

Abstract The development of efficient and low‐cost catalysts for cathodic oxygen reduction reaction (ORR) in Zn‐air battery (ZAB) is a key factor reducing costs achieving industrialization. Here, novel segregated CoNiPt alloy embedded N‐doped porous carbon with nanoflowers (NFs)‐like hierarchy structure synthesized through pyrolyzing Hofmann‐type metal‐organic frameworks (MOFs). unique hierarchical NFs exposes more active sites facilitates the transportation intermediates, thus accelerating kinetics. Impressively, resulting 15% CoNiPt@C catalyst exhibits outstanding alkaline ORR activity half‐wave potential 0.93 V, its mass 7.5 times higher than that commercial Pt/C catalyst, surpassing state‐of‐the‐art noble metal‐based catalysts. Furthermore, assembled CoNiPt@C+RuO2 ZAB demonstrates maximum power density 172 mW cm −2 , which superior to Pt/C+RuO2 ZAB. Experimental results reveal intrinsic attributed synergistic interaction between defects pyrrolic/graphitic N species, optimizes adsorption energy intermediate species process greatly enhances catalytic activity. This work provides practical feasible strategy synthesizing cost‐effective by optimizing electronic MOF‐derived

Язык: Английский

Процитировано

69
Low-temperature synthesis of nano-porous high entropy spinel oxides with high grain boundary density for oxygen evolution reaction DOI
Lei He, Hongjun Kang,

Guangyao Hou

и другие.

Chemical Engineering Journal, Год журнала: 2023, Номер 460, С. 141675 - 141675

Опубликована: Фев. 2, 2023

Язык: Английский

Процитировано

67
Recent Progress in Emerging Novel MXenes Based Materials and their Fascinating Sensing Applications DOI
Karim Khan, Ayesha Khan Tareen, Muhammad Waqas Iqbal

и другие.

Small, Год журнала: 2023, Номер 19(19)

Опубликована: Фев. 8, 2023

Early transition metals based 2D carbides, nitrides and carbonitrides nanomaterials are known as MXenes, a novel extensive new class of materials family. Since the first accidently synthesis discovery Ti3 C2 in 2011, more than 50 additional compositions have been experimentally reported, including at least eight distinct methods also 100 stoichiometries theoretically studied. Due to its distinctive surface chemistry, graphene like shape, metallic conductivity, high hydrophilicity, outstanding mechanical thermal properties, redox capacity affordable with mass-produced nature, this diverse MXenes tremendous scientific technological significance. In review, we'll come across MXene possible methods, their advantages, limitations future suggestions, chemistry related selected properties potential sensing applications, which will help us explain why family is growing very fast compared other families. Secondly, problems that further improve commercialization sensors examined, many advances commercializing proposed. At end, go through current challenges, suggestions.

Язык: Английский

Процитировано

57