Lignin-based support for metal catalysts: Synthetic strategies, performance boost, and application advances

Coordination Chemistry Reviews, Год журнала: 2025, Номер 528, С. 216426 - 216426

Опубликована: Янв. 10, 2025

Язык: Английский

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Spinel nanomaterials and their composites as extractors and sensors for heavy metals and other pollutants

TrAC Trends in Analytical Chemistry, Год журнала: 2025, Номер unknown, С. 118159 - 118159

Опубликована: Янв. 1, 2025

Язык: Английский

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TACKLING ELECTROCATALYTIC OXIDATION OF GLYCEROL TO DIHYDROXYACETONE: A COMPREHENSIVE REVIEW

Current Opinion in Electrochemistry, Год журнала: 2025, Номер unknown, С. 101665 - 101665

Опубликована: Фев. 1, 2025

Язык: Английский

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Electrooxidation of Glycerol to Formic Acid: from Catalyst Design Strategies to Key Coupled Systems

ChemSusChem, Год журнала: 2025, Номер unknown

Опубликована: Март 12, 2025

Abstract As a major by‐product of biodiesel production, glycerol offers significant economic potential when effectively utilized. The electrooxidation to formic acid in couped systems has attracted considerable attentions due its environmental friendliness, cost‐effectiveness, low energy consumption and production high‐value‐added chemicals. This concept presents the key strategies for catalyst design rational construction representative coupled towards efficient acid. Firstly, we overview from four aspects, including heteroatom doping, vacancy engineering, interface component construct highly active sites tune electronic properties electrocatalysts. Subsequently, discuss oxidation acid, highlight importance high‐value added Finally, conclude by outlining current challenges proposing future perspectives, arouse further research interest facilitate development.

Язык: Английский

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Sulfur-modified promoting the electrochemical CO2 reduction into formate performance of BiOI

Ionics, Год журнала: 2025, Номер unknown

Опубликована: Апрель 15, 2025

Язык: Английский

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Phosphidation‐Free Synthesis of Ni_xCo_yP on Nanostructured N,S,P‐Doped Carbon Networks as Self‐Supported Multifunctional Electrocatalysts

Small Structures, Год журнала: 2024, Номер 5(11)

Опубликована: Окт. 14, 2024

The synthesis of supported multielement transition metal phosphides (TMPs) to exploit the synergistic interplay between electronic and geometric effects resulting from presence different metals in material arrangement heterogeneous atoms is pivotal for reducing content while offering multiple active sites. However, integration Ni, Co, P, example, into a nanostructured carbon network develop self‐supporting Ni x Co y P bimetallic limited by several factors, including discrepancy crystal structure respective monometallic phosphides. Moreover, conventional TMPs often separates nanoparticles, support phosphidation steps, which do not allow tailoring physical catalytic properties via particle support, interactions. Herein, an innovative solid‐state, ex situ phosphidation‐free approach tailored synthesize library N,S,P‐modified networks generated together with particles presented. Extensive multivariate characterization validates unique materials enhanced electrocatalytic performance hydrogen evolution reaction selective electroconversion biomass‐derived 5‐hydroxymethylfurfural (5‐HMF) value‐added 2,5‐furandicarboxylic acid (FDCA) 90–100% Faradaic efficiency. Overall, expands possibilities microstructure improved physical/catalytic properties.

Язык: Английский

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Role of hydroxyl groups in Zn‐containing nanosized MFI zeolite for the photocatalytic oxidation of methane

ChemSusChem, Год журнала: 2024, Номер unknown

Опубликована: Сен. 12, 2024

The effective conversion of methane to a mixture more valuable hydrocarbons and hydrogen under mild conditions is significant scientific practical challenge. Here, we synthesized Zn-containing nanosized MFI zeolite for direct oxidation in the presence H

Язык: Английский

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