The Chemical Record,
Год журнала:
2023,
Номер
24(1)
Опубликована: Ноя. 20, 2023
Abstract
In
recent
years,
a
new
class
of
highly
crystalline
advanced
permeable
materials
covalent‐organic
frameworks
(COFs)
have
garnered
great
deal
attention
thanks
to
their
remarkable
properties,
such
as
large
surface
area,
ordered
pores
and
channels,
controllable
structures.
The
lower
physical
stability
electrical
conductivity,
however,
prevent
them
from
being
widely
used
in
applications
like
photocatalytic
activities
innovative
energy
storage
conversion
devices.
For
this
reason,
many
studies
focused
on
finding
ways
improve
upon
these
interesting
while
also
minimizing
drawbacks.
This
review
article
begins
with
brief
introduction
the
history
major
milestones
COFs
development
before
moving
comprehensive
exploration
various
synthesis
methods
successes
signposts
potential
carbon
dioxide
(CO
2
)
sequestration,
supercapacitors
(SCs),
lithium‐ion
batteries
(LIBs),
hydrogen
production
(H
‐energy).
conclusion,
difficulties
future
developing
efficient
ideas
for
well
electrochemical
are
highlighted.
Angewandte Chemie International Edition,
Год журнала:
2023,
Номер
63(4)
Опубликована: Дек. 8, 2023
Abstract
Aqueous
zinc
ion
batteries
are
gaining
popularity
due
to
their
high
energy
density
and
environmental
friendliness.
However,
random
deposition
of
ions
on
the
anode
sluggish
migration
interface
would
lead
growth
dendrites
poor
cycling
performance.
To
address
these
challenges,
we
developed
a
fluorinated
solid‐state‐electrolyte
layer
composed
Ca
5
(PO
4
)
3
F/Zn
2
via
an
in
situ
exchange
strategy
guide
zinc‐ion
oriented
fast
during
cycling.
The
introduction
F
(FAP)
can
increase
nucleation
sites
along
(002)
crystal
plane,
while
formation
Zn
accelerate
ions.
Benefited
from
our
design,
assembled
Zn//V
O
⋅
H
based
FAP‐protected
(FAP‐Zn)
achieve
higher
capacity
retention
84
%
(220
mAh
g
−1
than
that
bare‐Zn
batteries,
which
have
23
(97
at
3.0
A
after
800
cycles.
This
work
provides
new
solution
for
rational
design
development
solid‐state
electrolyte
high‐performance
batteries.
The Chemical Record,
Год журнала:
2023,
Номер
24(1)
Опубликована: Ноя. 20, 2023
Abstract
In
recent
years,
a
new
class
of
highly
crystalline
advanced
permeable
materials
covalent‐organic
frameworks
(COFs)
have
garnered
great
deal
attention
thanks
to
their
remarkable
properties,
such
as
large
surface
area,
ordered
pores
and
channels,
controllable
structures.
The
lower
physical
stability
electrical
conductivity,
however,
prevent
them
from
being
widely
used
in
applications
like
photocatalytic
activities
innovative
energy
storage
conversion
devices.
For
this
reason,
many
studies
focused
on
finding
ways
improve
upon
these
interesting
while
also
minimizing
drawbacks.
This
review
article
begins
with
brief
introduction
the
history
major
milestones
COFs
development
before
moving
comprehensive
exploration
various
synthesis
methods
successes
signposts
potential
carbon
dioxide
(CO
2
)
sequestration,
supercapacitors
(SCs),
lithium‐ion
batteries
(LIBs),
hydrogen
production
(H
‐energy).
conclusion,
difficulties
future
developing
efficient
ideas
for
well
electrochemical
are
highlighted.
