Electrochemistry Communications, Год журнала: 2025, Номер unknown, С. 107944 - 107944
Опубликована: Май 1, 2025
Язык: Английский
The Chemical Record, Год журнала: 2022, Номер 22(5)
Опубликована: Фев. 1, 2022
Abstract Syntheses of chemicals using renewable electricity and when generating high atom economies are considered green sustainable processes. In the present state affairs, electrochemical manufacturing fine pharmaceuticals is not as common place it could be therefore, merits more attention. There also a need to turn attention toward synthesis valuable from recyclable greenhouse gases that can accelerate process circular economy. CO 2 emissions major contributor human‐induced global warming. conversion into application its utilisation will contribute economy while maintaining environmental sustainability. Herein, we an overview electro‐carboxylation, including mechanistic aspects, which forms carboxylic acids molecular carbon dioxide. We discuss fluorination, methoxylation amide formation reactions.
Язык: Английский
Процитировано
16
Sustainable Chemistry, Год журнала: 2022, Номер 3(4), С. 430 - 454
Опубликована: Окт. 13, 2022
The electrochemical generation of highly reactive and hazardous bromine under controlled conditions as well the reduction surplus oxidizers reagent waste has placed synthesis in a highlighted position. In particular, dibromination bromofunctionalization alkenes alkynes have received significant attention, forming synthetically important derivatives can be generated from bench-stable safe bromide sources “green” conditions. Readily available non-corrosive salts been utilized with dual role both supporting electrolyte. However, this trend seems to change preparation organobromine species. review, was addressed terms their sustainability.
Язык: Английский
Процитировано
15
European Polymer Journal, Год журнала: 2023, Номер 184, С. 111852 - 111852
Опубликована: Янв. 27, 2023
Guar gum (GG) from seeds of cluster bean (Cyamopsis tetragonolobus) contains mainly non-ionic galactomannan polysaccharide. Due to fascinating properties, great natural abundancy, low cost, biocompatibility and biodegradability, GG polysaccharide has been studied employed in various research fields industries. To explore extend full potentials GG, further chemical functionalization the material is essential. This review highlights recent progress modification its derivatives based on nucleophilic reactions, partial oxidation, graft polymerization cross-linking with diverse reagents reaction pathways. Moreover, insights into structure–property relationships as well potential applications materials are also provided discussed.
Язык: Английский
Процитировано
9
JACS Au, Год журнала: 2024, Номер 4(6), С. 2188 - 2196
Опубликована: Апрель 18, 2024
Iminophosphoranes are commonly used reagents in organic synthesis and are, therefore, of great interest. An efficient sustainable iodide-mediated electrochemical N-sulfonyl iminophosphoranes from readily available phosphines sulfonamides is reported. This method features low amounts supporting electrolytes, inexpensive electrode materials, a simple galvanostatic setup, high conversion rates. The broad applicability could be demonstrated by synthesizing 20 examples yields up to 90%, having diverse functional groups including chiral moieties biologically relevant species. Furthermore, electrolysis was performed on g scale run repetitive mode recycling the electrolyte, which illustrates suitability for large-scale production. A reaction mechanism involving mediation iodide-based electrolyte proposed, completely agreeing with all results.
Язык: Английский
Процитировано
3
Electrochemistry Communications, Год журнала: 2025, Номер unknown, С. 107944 - 107944
Опубликована: Май 1, 2025
Язык: Английский
Процитировано
0