Environmental Processes,
Год журнала:
2021,
Номер
9(1)
Опубликована: Дек. 29, 2021
Abstract
The
aim
of
this
paper
is
the
presentation
current
state-of-the-art
about
determination
polycyclic
aromatic
hydrocarbons
(PAHs)
and
their
oxidized
forms
originating
from
Suspended
Particulate
Matter
(SPM)
samples.
influence
SPM
on
health
twofold.
SPM,
as
composed
small
particles,
dangerous
for
respiratory
system.
Additionally,
a
carrier
many
hazardous
compounds,
particularly
PAHs.
Recently,
several
researches
focus
derivatives
PAHs,
nitro-,
oxy-
hydroxy-PAHs,
which
are
more
than
parent
Both
gas
high-performance
liquid
chromatography
with
various
detection
techniques
used
to
analyze
both
PAHs
forms.
Due
appearance
these
compounds
in
environment,
at
very
low
level,
an
analyte
concentration
step
has
be
applied
prior
analysis.
If
GC
HPLC
chiefly
analytical
tools
analyses,
spectrum
procedures
broad.
Many
proposed:
classic
liquid-solid
extractions,
including
Soxhlet
technique,
pressurized
extraction
(ASE)
or
microwave
oven
(MWE)
sonic
supported
SPE
applications.
However,
one
should
remember
that
PAH
methods
solving
main
problem,
i.e.,
evaluation
hazard
connected
presence
air.
Thus,
drawback
papers
found
review,
lack
information
concerning
limit
(LOD)
makes
applicability
limited.
Atmospheric chemistry and physics,
Год журнала:
2019,
Номер
19(13), С. 8741 - 8758
Опубликована: Июль 10, 2019
Abstract.
Ambient
particulate
matter
(PM)
can
contain
a
mix
of
different
toxic
species
derived
from
wide
variety
sources.
This
study
quantifies
the
diurnal
variation
and
nocturnal
abundance
16
polycyclic
aromatic
hydrocarbons
(PAHs),
10
oxygenated
PAHs
(OPAHs)
9
nitrated
(NPAHs)
in
ambient
PM
central
Beijing
during
winter.
Target
compounds
were
identified
quantified
using
gas
chromatography–time-of-flight
mass
spectrometry
(GC-Q-ToF-MS).
The
total
concentration
varied
between
18
297
ng
m−3
over
3
h
daytime
filter
samples
23
to
165
15
night-time
samples.
concentrations
24
37
180
(mean:
97±43
m−3).
high
loading
conditions
for
PAHs,
OPAHs
NPAHs
224,
54
2.3
m−3,
respectively.
most
abundant
fluoranthene
(33
m−3),
chrysene
(27
pyrene
benzo[a]pyrene
benzo[b]fluoranthene
(25
benzo[a]anthracene
(20
m−3)
phenanthrene
(18
9,10-anthraquinone
1,8-naphthalic
anhydride
(14
9-fluorenone
(12
three
9-nitroanthracene
(0.84
3-nitrofluoranthene
(0.78
3-nitrodibenzofuran
(0.45
∑PAHs
∑OPAHs
showed
strong
positive
correlation
with
gas-phase
NO,
CO,
SO2
HONO,
indicating
that
be
associated
both
local
regional
emissions.
Diagnostic
ratios
suggested
emissions
traffic
road
coal
combustion
predominant
sources
also
revealed
main
source
secondary
photochemical
formation
rather
than
primary
PM2.5
HONO.
9-Nitroanthracene
appeared
undergo
photodegradation
HONO
(R=0.90,
P
<
0.001).
lifetime
excess
lung
cancer
risk
those
have
available
toxicological
data
(16
1
OPAH
6
NPAHs)
was
calculated
range
10−5
10−3
(risk
per
million
people
ranges
26
2053
cases
year).
Environmental Processes,
Год журнала:
2021,
Номер
9(1)
Опубликована: Дек. 29, 2021
Abstract
The
aim
of
this
paper
is
the
presentation
current
state-of-the-art
about
determination
polycyclic
aromatic
hydrocarbons
(PAHs)
and
their
oxidized
forms
originating
from
Suspended
Particulate
Matter
(SPM)
samples.
influence
SPM
on
health
twofold.
SPM,
as
composed
small
particles,
dangerous
for
respiratory
system.
Additionally,
a
carrier
many
hazardous
compounds,
particularly
PAHs.
Recently,
several
researches
focus
derivatives
PAHs,
nitro-,
oxy-
hydroxy-PAHs,
which
are
more
than
parent
Both
gas
high-performance
liquid
chromatography
with
various
detection
techniques
used
to
analyze
both
PAHs
forms.
Due
appearance
these
compounds
in
environment,
at
very
low
level,
an
analyte
concentration
step
has
be
applied
prior
analysis.
If
GC
HPLC
chiefly
analytical
tools
analyses,
spectrum
procedures
broad.
Many
proposed:
classic
liquid-solid
extractions,
including
Soxhlet
technique,
pressurized
extraction
(ASE)
or
microwave
oven
(MWE)
sonic
supported
SPE
applications.
However,
one
should
remember
that
PAH
methods
solving
main
problem,
i.e.,
evaluation
hazard
connected
presence
air.
Thus,
drawback
papers
found
review,
lack
information
concerning
limit
(LOD)
makes
applicability
limited.