Renewable and Sustainable Energy Reviews, Год журнала: 2023, Номер 192, С. 114243 - 114243
Опубликована: Дек. 27, 2023
Язык: Английский
International Journal of Molecular Sciences, Год журнала: 2022, Номер 23(6), С. 3381 - 3381
Опубликована: Март 21, 2022
Greater awareness of environmental sustainability has driven many industries to transition from using synthetic organic solvents greener in their manufacturing. Deep eutectic (DESs) have emerged as a highly promising category green with well-demonstrated and wide-ranging applications, including use solvent extraction small-molecule bioactive compounds for food pharmaceutical applications. The DES an biological macromolecules, on the other hand, not been extensively studied. Thereby, feasibility employing biomacromolecule well elucidated. To bridge this gap, review provides overview emphasis its unique physicochemical properties that make it attractive (e.g., non-toxicity, biodegradability, ease preparation, renewable, tailorable properties). Recent advances three classes biomacromolecules-i.e., proteins, carbohydrates, lipids-were discussed future research needs were identified. importance DES's properties-particularly viscosity, polarity, molar ratio components, water addition-on extraction's performance discussed. Not unlike findings small molecules, biomacromolecules was concluded be generally superior solvents.
Язык: Английский
Процитировано
154
Bioresource Technology, Год журнала: 2022, Номер 360, С. 127631 - 127631
Опубликована: Июль 16, 2022
Язык: Английский
Процитировано
142
ACS Energy Letters, Год журнала: 2021, Номер 7(1), С. 247 - 260
Опубликована: Дек. 15, 2021
Metal-ion batteries (MIBs) are promising for large-scale energy storage because they can alleviate the inherent intermittency of renewable energy. As an indispensable part MIBs, electrolytes influence electrochemical performance. Recently, new concept eutectic has aroused extensive research attention in field MIBs due to their simple synthesis and eco-friendly features. Nevertheless, development is still its infancy deserves further attention. This review focuses on systematic understanding relationship between corresponding performances MIBs. First, fundamentals described. Then, recent progress use introduced, including correlations structure properties, chemistry at electrode interface, ion/charge transport mechanism. Finally, challenges prospects related discussed. Focus Review will provide better directions devise advanced high-performance
Язык: Английский
Процитировано
133
RSC Sustainability, Год журнала: 2023, Номер 1(2), С. 179 - 212
Опубликована: Янв. 1, 2023
Production quantity ratio of petroleum derived chemical products. This also presents the concept replacing all petroleum-based products with natural biomass-based
Язык: Английский
Процитировано
132
Resources Conservation and Recycling, Год журнала: 2022, Номер 188, С. 106690 - 106690
Опубликована: Окт. 7, 2022
Язык: Английский
Процитировано
129
Bioresource Technology, Год журнала: 2022, Номер 369, С. 128396 - 128396
Опубликована: Ноя. 26, 2022
Pretreatment processes - recognized as critical steps for efficient biomass refining have received much attention over the last two decades. In this context, deep eutectic solvents (DES) emerged a novel alternative to conventional representing step forward in achieving more sustainable with both environmental and economic benefits. This paper presents an updated review of state-of-the-art DES-based applications biorefinery schemes. Besides describing fundamentals DES composition, synthesis, recycling, study comprehensive existing techno-economic life cycle assessment studies. Challenges, barriers, perspectives scale-up are also discussed.
Язык: Английский
Процитировано
103
Advanced Materials, Год журнала: 2023, Номер 35(36)
Опубликована: Июнь 20, 2023
Flexible zinc-ion batteries (ZIBs) with high capacity and long cycle stability are essential for wearable electronic devices. Hydrogel electrolytes have been developed to provide ion-transfer channels while maintaining the integrity of ZIBs under mechanical strain. However, hydrogel matrices typically swollen aqueous salt solutions increase ionic conductivity, which can hinder intimate contact electrodes reduce properties. To address this, a single-Zn-ion-conducting electrolyte (SIHE) is by integrating polyacrylamide network pseudo-polyrotaxane structure. The SIHE exhibits Zn2+ transference number 0.923 conductivity 22.4 mS cm-1 at room temperature. Symmetric demonstrate stable Zn plating/stripping performance over 160 h, homogenous smooth deposition layer. Full cells La-V2 O5 cathodes exhibit 439 mA h g-1 0.1 A excellent retention 90.2% after 3500 cycles 5 . Moreover, flexible display electrochemical harsh conditions, such as bending, cutting, puncturing, soaking. This work provides simple design strategy single-ion-conducting electrolytes, could pave way long-life batteries.
Язык: Английский
Процитировано
99
Green Chemistry, Год журнала: 2022, Номер 24(17), С. 6685 - 6695
Опубликована: Янв. 1, 2022
Deep-eutectic solvents (DESs) are often considered to be safe, eco-friendly and non-toxic solvents. Due these green credentials, they increasingly being studied for application in metal recycling processes. One example is their use as lixiviants the recovery of cobalt from lithium oxide (LiCoO
Язык: Английский
Процитировано
87
Food Research International, Год журнала: 2022, Номер 161, С. 111842 - 111842
Опубликована: Авг. 28, 2022
Язык: Английский
Процитировано
85
Chemical Reviews, Год журнала: 2024, Номер 124(5), С. 2617 - 2650
Опубликована: Фев. 22, 2024
The societal importance of plastics contrasts with the carelessness which they are disposed. Their superlative properties lead to economic and environmental efficiency, but linearity puts climate, human health, global ecosystems at risk. Recycling is fundamental transitioning this linear model into a more sustainable, circular economy. Among recycling technologies, chemical depolymerization offers route virgin quality recycled plastics, especially when valorizing complex waste streams poorly served by mechanical methods. However, exists in interlinked system end-of-life fates, complementarity each approach key environmental, economic, sustainability. This review explores recent progress made five commercial polymers: poly(ethylene terephthalate), polycarbonates, polyamides, aliphatic polyesters, polyurethanes. Attention paid not only catalytic technologies used enhance efficiencies also interrelationship other systemic constraints imposed Novel polymers, designed for depolymerization, concisely reviewed terms their underlying chemistry potential integration current plastic systems.
Язык: Английский
Процитировано
80