Supramolecular deep eutectic solvents and their applications

Green Chemistry, Год журнала: 2022, Номер 24(13), С. 5035 - 5045

Опубликована: Янв. 1, 2022

Supramolecular Deep Eutectic Solvent (SUPRADES) – another milestone towards Green Chemistry.

Язык: Английский

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An overview of deep eutectic solvents: Alternative for organic electrolytes, aqueous systems & ionic liquids for electrochemical energy storage

Journal of Energy Chemistry, Год журнала: 2023, Номер 82, С. 592 - 626

Опубликована: Апрель 7, 2023

Язык: Английский

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Eutectic Electrolytes Chemistry for Rechargeable Zn Batteries

Small, Год журнала: 2022, Номер 18(21)

Опубликована: Март 15, 2022

Abstract Rechargeable zinc batteries (RZBs) have proved to be promising candidates as an alternative lithium‐ion due their low cost, inherent safety, and environmentally benign features. While designing cost‐effective electrolyte systems with excellent compatibility electrode materials, high energy/power density well long life‐span challenge further application grid‐scale energy storage devices. Eutectic electrolytes a novel class of been extensively reported explored taking advantage feasible preparation tunability. Recently, some perspectives summarized the development eutectic in metal‐based batteries, but infancy requires attention discussion. This review systematically presents fundamentals definitions electrolytes. Besides, specific classification recent progress performance on RZB fields are introduced well. Significantly, impacts various composing disserted for critical chemistries including attractive features at electrolyte/electrode interfaces ions/charges transport kinetics. The remaining challenges proposed ultimately induced, which deliver opportunities offer practical guidance design advanced superior scenarios.

Язык: Английский

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Synthesis strategies of covalent organic frameworks: An overview from nonconventional heating methods and reaction media

Green Energy & Environment, Год журнала: 2022, Номер 8(6), С. 1596 - 1618

Опубликована: Май 14, 2022

Covalent organic frameworks (COFs), as an emerging class of porous crystalline materials constructed by covalent links between the building monomers, have gained tremendous attention. Over past 15 years, COFs made rapid progress and substantial development in chemistry fields. However, synthesis has been dominated solvothermal methods for a long time it usually involves high temperature, pressure toxic solvents, which created many challenges environmental considerations. Recently, exploration new approaches facile fabrication aroused extensive interest. Hence, this review, we comprehensively describe synthetic strategies from aspects nonconventional heating reaction media. In addition, advantages, limitations properties preparation are compared. Finally, outline main prospects future propose some possible solutions.

Язык: Английский

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Selective Extraction of Critical Metals from Spent Lithium-Ion Batteries

Environmental Science & Technology, Год журнала: 2023, Номер 57(9), С. 3940 - 3950

Опубликована: Фев. 17, 2023

Selective and highly efficient extraction technologies for the recovery of critical metals including lithium, nickel, cobalt, manganese from spent lithium-ion battery (LIB) cathode materials are essential in driving circularity. The tailored deep eutectic solvent (DES) choline chloride–formic acid (ChCl–FA) demonstrated a high selectivity efficiency extracting mixed (LiFePO4:Li(NiCoMn)1/3O2 mass ratio 1:1) under mild conditions (80 °C, 120 min) with solid–liquid 1:200. leaching performance could be further enhanced by mechanochemical processing because particle size reduction, grain refinement, internal energy storage. Furthermore, reactions effectively inhibited undesirable nontarget elements (iron phosphorus), thus promoting metals. This was achieved through preoxidation Fe stability iron phosphate framework, which significantly increased separation factor to 56.9 1475. proposed combination ChCl–FA reaction can achieve selective multisource LIBs conditions.

Язык: Английский

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Deep eutectic solvents: Recent advances in fabrication approaches and pharmaceutical applications

International Journal of Pharmaceutics, Год журнала: 2022, Номер 622, С. 121811 - 121811

Опубликована: Май 10, 2022

Язык: Английский

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VOCs absorption from gas streams using deep eutectic solvents – A review

Journal of Hazardous Materials, Год журнала: 2023, Номер 448, С. 130957 - 130957

Опубликована: Фев. 9, 2023

Язык: Английский

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Eutectic electrolytes with leveling effects achieving high depth-of-discharge of rechargeable zinc batteries

Energy storage materials, Год журнала: 2023, Номер 58, С. 9 - 19

Опубликована: Март 12, 2023

Язык: Английский

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Therapeutic deep eutectic solvents: A comprehensive review of their thermodynamics, microstructure and drug delivery applications

European Journal of Pharmaceutics and Biopharmaceutics, Год журнала: 2023, Номер 186, С. 85 - 104

Опубликована: Март 11, 2023

Язык: Английский

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Comparison of physicochemical and thermal properties of choline chloride and betaine-based deep eutectic solvents: The influence of hydrogen bond acceptor and hydrogen bond donor nature and their molar ratios

Journal of Molecular Liquids, Год журнала: 2023, Номер 377, С. 121563 - 121563

Опубликована: Март 4, 2023

Within the green chemistry area, deep eutectic solvents (DESs) are playing an increasingly prominent role thanks to their intriguing physicochemical properties. However, a comparative study encompassing wide range of properties as function different parameters such nature hydrogen bond acceptor (HBA) and donor (HBD) molar ratio is still missing. In this work, six DESs based on most used HBAs (choline chloride (ChCl) betaine (Bet)) HBDs (ethylene glycol (EG), glycerol (Gly) levulinic acid (LevA)) combined in three (1:2, 1:3, 1:4) have been prepared subjected series analysis aimed at measuring density, viscosity, refractive index, thermal stability behaviour. The striking findings see EG-based displaying lowest density viscosity values, while Gly-based exhibited highest. High obtained using Bet instead ChCl HBA. Increasing amount HBD caused lower all cases, increased for decreased EG LevA-based DESs. index also when portion was increased. higher temperature wavelength dependence otherwise described pretty well by Sellmeier model. refractivity implied data via Clausius-Mossotti equation consistent with that predicted empirical but well-established model Wildman Crippen. short investigated strictly related used. were less stable than ones materials. Moreover, characteristic mass loss events identified. They can be attributed evaporation/degradation HBD, intimately interacting HBD-HBA HBA, respectively. Finally, DSC analyses showed given they liquids room temperature, maintain liquid state broad temperatures (Tg < −50 °C or no observed).

Язык: Английский

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