Structure and reactivity in reactions of dimethyltin(IV) di(azide) and di(isocyanate) with dimethylplatinum(II) complexes
Inorganica Chimica Acta,
Год журнала:
2025,
Номер
581, С. 122613 - 122613
Опубликована: Фев. 27, 2025
Язык: Английский
Synthesis, structural characterization, Hirshfeld surface analysis and thermal properties of dibutyltin(IV)-based complexes containing thiocyanate and pyridyl ligands
Journal of Molecular Structure,
Год журнала:
2024,
Номер
1317, С. 139155 - 139155
Опубликована: Дек. 1, 2024
Язык: Английский
Comprehensive Investigation of Organotin(IV) Complexes Derived From a Novel Schiff Base: Synthesis, Characterization, Antioxidant, ADME Profiling, and In Vitro Biological Evaluation
Applied Organometallic Chemistry,
Год журнала:
2024,
Номер
39(1)
Опубликована: Сен. 23, 2024
ABSTRACT
Six
organotin(IV)
complexes
(
1–6
)
were
synthesized,
following
the
general
formulas
as
R
2
Sn(L)Cl
and
3
Sn(L),
have
been
reported.
In
these
complexes,
L
represents
a
Schiff
base
prepared
by
reaction
of
phenylhydrazine
with
5‐bromo‐2‐hydroxybenzaldehyde,
=
Me,
n
‐Bu,
Ph.
Various
analytical
techniques
employed
to
characterize
determine
structure
newly
synthesized
compounds.
The
techniques,
including
elemental
analysis,
molar
conductivity
measurements,
UV–visible,
FT‐IR,
NMR
spectroscopy,
mass
spectrometry.
Spectroscopic
analysis
suggested
that
ligand
(4‐bromo‐2‐[(2‐phenylhydrazinylidene)meth‐yl]phenol)
(HL)
coordinates
tin
(Sn)
metal
through
its
phenolic
oxygen
(O)
azomethine
nitrogen
(N)
atoms.
Molar
measurements
indicated
all
compounds
are
nonelectrolytes.
percent
CHN
data
also
corroborates
spectroscopic
results.
UV–Vis
spectra
revealed
mode
transitions
electrons
due
π–π*
transitions,
n–π*
involving
charge
transfer
from
metal,
which
occurred
in
recently
developed
organotin
(IV)
complexes.
emergence
additional
bands
FT‐IR
),
attributed
ν(Sn–O)
ν(Sn–N),
absent
precursor,
offers
further
proof
for
synthesis
spectral
studies
give
information
about
nature
number
protons
having
same
or
different
chemical
environment
being
reported
this
study.
potential
be
used
bioactive
future
was
assessed
performing
biological
activities
(antimicrobial
antioxidant)
DPPH
free
radical
method
antioxidant
Based
on
assessments,
it
can
concluded
ligand's
efficiency
improves
upon
complexation,
primarily
type
quantity
alkyl
groups
attached
[Sn]
atom.
ADME
conducted
forecast
effectiveness
Among
these,
1
4
prioritized
docking
Aspergillus
flavus
,
Bacillus
subtilis
Escherichia
coli
.
found
biologically
more
effective
towards
microbes.
Antioxidant
activity
test
follows
trend:
Methyltin(IV)
exhibit
lowest
activity,
whereas
butyltin(IV)
phenyl(IV)
higher
levels
phenyltin(IV)
showing
most
significant
activity.
Язык: Английский
Experimental and Computational Studies of Chlorido(indole-3-acetohydroxamato) Dimethyltin (IV) Complex: Single Crystal Structure, Biological Evaluation and Molecular Docking Study
Journal of Inorganic and Organometallic Polymers and Materials,
Год журнала:
2024,
Номер
unknown
Опубликована: Ноя. 26, 2024
Язык: Английский