Polymers,
Год журнала:
2024,
Номер
16(22), С. 3103 - 3103
Опубликована: Ноя. 5, 2024
In
this
study,
recycled
acrylonitrile-butadiene-styrene
terpolymer
(ABSr)
was
reused
to
produce
polyamide
6
(PA6)-based
blends.
This
achieved
through
reactive
compatibilization
using
styrene-acrylonitrile-maleic
anhydride
(SAN-g-MA)
copolymer
with
a
high
degree
of
functionalization
(6–10%
MA).
The
PA6/ABSr
and
PA6/ABSr/SAN-g-MA
blends
were
prepared
melt
processing
injection
molding
then
analyzed
for
their
rheological,
mechanical,
thermomechanical,
thermal,
structural
properties,
as
well
morphology.
torque
rheometry
revealed
maximum
reactivity
the
(70/30
wt%)
blend
low
SAN-g-MA
(5
phr—parts
per
hundred
resin)
content,
while
above
threshold,
began
decline,
indicating
compatibilizer
saturation
in
interface.
These
findings
further
substantiated
by
increase
complex
viscosity
lower
flow
index
(MFI)
phr)
blend.
5
phr
significantly
enhanced
its
impact
strength,
elongation
at
break,
tensile
heat
deflection
temperature
(HDT)
217%,
631%,
12.6%,
9.5%,
respectively,
compared
PA6/ABSr.
are
promising
plastic
recycling
field,
paving
way
production
new
tailor-made
materials
reduced
price.
Materials Today Sustainability,
Год журнала:
2024,
Номер
26, С. 100757 - 100757
Опубликована: Март 24, 2024
Filaments
from
blends
of
post-industrial,
low-quality
recycled
poly(ethylene
terephthalate)
(RPET)
and
ethylene-butyl-acrylate-glycidyl-methacrylate
(EBA-GMA)
were
extruded
with
different
EBA-GMA
contents,
then
specimens
3D-printed
by
fused
filament
fabrication
technology.
It
has
been
demonstrated
that,
when
0–90°
layer
order
is
applied,
at
15
wt%
content
the
unnotched
impact
strength
increases
two
a
half
times
notched
nine
compared
to
samples
printed
elastomer-free
RPET.
DSC
DMA
measurements
proved
that
reactively
bonds
PET
molecules,
which
indicated
increment
rigid
amorphous
phase
glass
transition
temperature
reduction
crystallinity.
The
co-polymer
molecules
formed
in-situ
during
compounding
create
Toughening
Enhancer
Interphase
(TEI),
also
remains
after
3D
printing
effectively
enhances
strength.
strain
break
tensile
filaments
are
substantially
higher
than
due
increasing
shrinkage
resulting
increased
porosity
content.
However,
Young-modulus
values
quite
similar.
flexural
reaches
40–60%
injection
moulded
samples.
proposed
method
enables
production
parts
arbitrary
geometry
balanced
mechanical
properties
RPET,
may
substitute
acrylonitrile
butadiene
styrene.
Journal of Composites Science,
Год журнала:
2024,
Номер
8(6), С. 215 - 215
Опубликована: Июнь 7, 2024
The
development
of
efficient
waste
valorization
strategies
has
emerged
as
an
important
field
in
the
overall
efforts
for
alignment
with
environmental
goals
that
have
been
set
by
European
Union
(EU)
Green
Deal
regarding
sustainable
circular
economy
models.
Additive
manufacturing
a
method
secondary
life
product
main
advantages
it
being
form
net-zero
production
and
having
ability
to
successfully
transport
complex
design
actual
products
finding
applications
industry
rapid
prototyping
or
tailored
products.
insertion
eco-friendly
materials
these
processes
can
lead
significant
reduction
material
footprints
lower
energy
demands
process,
helping
achieve
Sustainable
Development
Goal
12
(SDG12)
EU
responsible
consumption.
aim
this
comprehensive
review
is
state
existing
progress
incorporation
polymeric
composite
additive
(AM)
identify
possible
gaps
further
research.
In
context,
presentation
reacquired
coming
from
urban
industrial
are
used
produce
composites
made.
Then,
assessment
printability
mechanical
response
constructed
made,
taking
into
consideration
some
key
thermal,
rheological
properties
(e.g.,
viscosity,
melting
degradation
temperature,
tensile
impact
strength).
Finally,
cycle
analysis
results
presented
footprint
during
waste-to-feedstock
processes.
A
lack
scientific
research
was
observed,
manifestation
novel
evaluation
techniques
such
dynamic
testing.
Assessing
vital
evaluating
whether
types
adequate
upscaling
use
real
applications.
Macromolecular Rapid Communications,
Год журнала:
2024,
Номер
45(17)
Опубликована: Май 31, 2024
Abstract
This
review
aims
to
present
the
different
approaches
lessen
environmental
impact
of
extrusion‐based
additive
manufacturing
(MEX)
process
thermoplastic‐based
resins
and
protect
ecosystem.
The
benefits
drawbacks
each
alternative,
including
use
biomaterials
or
recycled
materials
as
feedstock,
energy
efficiency,
polluting
emissions
reduction,
have
been
examined.
First,
technological
option
using
a
pellet‐fed
printer
was
compared
filament‐fed
printer.
Then,
common
biopolymers
utilized
in
MEX
applications
are
discussed,
along
with
methods
for
improving
mechanical
properties
associated
printed
products.
introduction
natural
fillers
thermoplastic
biocomposite
filaments
proposed
improve
specific
performance
items,
highlighting
numerous
challenges
related
their
extrusion.
Various
polymers
derived
from
recycling
presented
feeding
raw
printers
reduce
waste
accumulation,
showing
inferior
qualities
resulting
goods
when
products
made
virgin
materials.
Finally,
consumption
released
into
atmosphere
during
printing
potential
both
aspects
be
controlled
through
material
selection
operating
conditions.
Proceedings of the Institution of Mechanical Engineers Part E Journal of Process Mechanical Engineering,
Год журнала:
2024,
Номер
unknown
Опубликована: Апрель 1, 2024
This
article
proposes
an
investigation
on
sustainable
polylactic
acid/wood
dust
(PLA/WD)
composite
material
for
three-dimensional
(3D)-printing
applications.
eco-friendly
aids
a
remarkable
reduction
in
thermoplastic
waste,
while
minimising
resource
depletion,
as
result
it
promotes
circular
economies,
and
mitigates
environmental
pollution.
In
order
to
extend
the
service
life
of
manufactured
components,
becomes
necessary
investigate
key
fused
filament
fabrication
(FFF)
processing
parameters
that
affect
mechanical
performance
PLA/WD
parts.
Taguchi-based
L
27
orthogonal
array
design
was
implemented
experimentation,
mathematical
models
were
developed
by
using
grey
relational
analysis
predict
responses
proposed
material.
Moreover,
FFF
input
with
three
levels
values
considered
experimentation
are
nozzle
temperature
(190°C–200°C),
layer
height
(0.12–0.28
mm),
print
speed
(30–50
mm/min),
infill
density
(80–100%)
raster
angle
(0°–90°).
The
results
revealed
highest
grade
obtained
0.8333
experiment
run
19
sample
having
ultimate
tensile
strength
shore
D
hardness
20.71
±
1.24
MPa
74
2
SHD,
respectively.
angle,
found
be
influential
properties
sample.
Furthermore,
200°C,
0.2
mm,
30
mm/min,
100%
90°
optimum
parameters.
Rapid Prototyping Journal,
Год журнала:
2024,
Номер
30(4), С. 760 - 769
Опубликована: Март 23, 2024
Purpose
This
study
aims
to
present
an
experimental
approach
develop
a
high-strength
3D-printed
recycled
polymer
composite
reinforced
with
continuous
metal
fiber.
Design/methodology/approach
The
fiber
was
3D
printed
using
and
virgin
acrylonitrile
butadiene
styrene-blended
filament
(RABS-B)
in
the
ratio
of
60:40
postused
brass
wire
(CBW).
printing
done
in-nozzle
impregnation
technique
FFF
printer
installed
self-modified
nozzle.
tensile
single-edge
notch
bend
(SENB)
test
samples
are
fabricated
evaluate
fracture
toughness
properties
compared
VABS
RABS-B
samples.
Findings
SENB
tests
revealed
that
RABS-B/CBW
0.7
mm
layer
spacing
exhibited
notable
improvement
Young’s
modulus,
ultimate
strength,
elongation
at
maximum
load
by
51.47%,
18.67%
107.3%
22.75%
VABS,
respectively.
Social
implications
novel
integrating
CBW
thermoplastic
represents
significant
leap
forward
material
science,
delivering
superior
strength
unlocking
potential
for
advanced,
sustainable
composites
demanding
engineering
fields.
Originality/value
Limited
research
has
been
conducted
on
fiber-reinforced
composites.
Adopting
this
method
holds
create
durable
suitable
applications,
thereby
diminishing
dependence
materials.
Rapid Prototyping Journal,
Год журнала:
2024,
Номер
30(6), С. 1137 - 1148
Опубликована: Май 20, 2024
Purpose
This
study
aims
to
evaluate
the
potential
of
using
in-nozzle
impregnation
approach
reuse
recycled
PET
(RPET)
develop
continuous
banana
fiber
(CBF)
reinforced
bio-composites.
The
mechanical
properties
and
fracture
morphology
behavior
are
evaluated
establish
relationships
between
layer
spacing–microstructural
characteristics–mechanical
CBF/RPET
composite.
Design/methodology/approach
uses
RPET
filament
developed
from
post-consumer
bottles
CBF
extracted
agricultural
waste
sap.
serves
as
matrix
material,
while
acts
reinforcement.
test
specimens
were
fabricated
a
customized
fused
deposition
modeling
3D
printer.
In
this
process,
printer
heads
used,
which
have
unique
capability
extrude
deposit
print
fibers
consisting
core
coated
with
an
matrix.
tensile
flexural
samples
printed
at
varying
spacing.
Findings
Young’s
modulus
(E),
yield
strength
(sy)
ultimate
sample
0.7
mm
spacing
1.9
times,
1.25
times
1.8
greater
than
neat
RPET,
respectively.
Similarly,
results
showed
that
0.6
was
47.52
±
2.00
MPa,
far
(25.12
1.94
MPa).
Social
implications
holds
significant
social
highlighting
growing
environmental
sustainability
plastic
recycling
concerns.
use
material
3D-printed
sustainable
structures
may
reduce
resource
consumption
encourages
responsible
production
practices.
Originality/value
key
innovation
lies
in
concept
approach,
where
is
composite
structure.
reinforcement
has
made
superior,
sustainable,
environmentally
friendly
can
reliance
on
virgin
for
printing.
Journal of Reinforced Plastics and Composites,
Год журнала:
2024,
Номер
unknown
Опубликована: Июль 18, 2024
The
aim
of
the
current
research
is
to
develop
a
3D
printable
PETG
composite
filament
reinforced
with
pineapple
fiber
particulate
(PALF-P).
These
filaments
were
produced
using
an
extrusion
technique,
incorporating
varying
weight
percentages
(1.5%,
2.5%,
5%,
and
7.5%)
PALF
particles
treated
5%
NaOH
chemical
solution.
Analytical
techniques
like
Fourier
Transform
Infrared
Spectroscopy
(FTIR)
X-ray
Diffraction
(XRD)
evaluated
impact
this
treatment.
A
comprehensive
study
resulting
filaments’
mechanical
physical
attributes
revealed
improved
cohesion
between
matrix
particles,
enhancing
overall
properties.
Specifically,
incorporation
5
wt
%
showed
highest
ultimate
tensile
strength
(53.54
±
2.7
MPa),
Young’s
modulus
(1443
72.22
load-bearing
capacity
(104.97
5.25
N).
In
contrast,
2.5%
had
least
noticeable
effect
on
Moreover,
developed
sustainable
significant
promise
in
advancing
bio-composites
through
additive
manufacturing,
potentially
contributing
manufacturing
practices.
This
review
investigates
the
pivotal
challenge
of
recycling
material
waste
in
context
Additive
Manufacturing
with
an
emphasis
on
decentralized
3D
printing,
shedding
light
its
environmental
and
economic
implications.
With
additive
manufacturing
experiencing
exponential
growth,
impacts
generation
during
printing
processes
have
become
increasingly
significant.
The
paper
explores
various
recycled
materials
commonly
used
including
polymers
like
polylactic
acid
(PLA),
acrylonitrile
butadiene
styrene
(ABS),
polyethylene
terephthalate
glycol
(PETG),
evaluating
their
characteristics
usability.
General
methodologies,
encompassing
mechanical
chemical
processes,
are
examined
attention
to
challenges
such
as
polymer
sorting,
additives,
coatings,
contamination,
thermoset
reprocessing.
societal
impact
integrating
into
examined.
By
identifying
research
gaps
proposing
future
trends,
this
contributes
a
deeper
understanding
how
can
play
role
achieving
sustainability
viability
within
landscape.