137Cs RECOVERY FROM DIFFERENT COMPOSITION SOLUTIONS BY FERROCYANIDE SORBENTS BASED ON POLYACRYLONITRILE FIBER DOI Open Access
Iuliia G. Shibetskaia, Viktoriia A. Razina, N. A. Bezhin

и другие.

Transaction Kola Science Centre, Год журнала: 2024, Номер 15(1), С. 448 - 453

Опубликована: Ноя. 28, 2024

Sorbents based on polyacrylonitrile (PAN) fiber and transition metal ferrocyanides were obtained. The influence of the studied solution composition (pH, concentration Na+, K+, NH4+ ions) cesium distribution coefficients during its recovery by obtained sorbents was assessed. A study trace amount sorption 137Cs carried out in comparison with commercially available highly efficient (FNS-10 Termoksid-35), it shown that resulting are not inferior to industrial ferrocyanide sorbents.

Язык: Английский

A facile synthesis of polyacrylic acid–ammonium phosphomolybdate microspheres for the highly selective removal of cesium DOI

Chengyun Fu,

Wei Xin,

Lian Jie

и другие.

Journal of Radioanalytical and Nuclear Chemistry, Год журнала: 2024, Номер 333(4), С. 2207 - 2220

Опубликована: Март 20, 2024

Язык: Английский

Процитировано

7

Sorbents Based on Polyacrylonitrile Fiber for Complex Recovery of Artificial 137Cs and Natural Radionuclides from Natural Media DOI Open Access
Iuliia G. Shibetskaia, Viktoriia A. Razina, N. A. Bezhin

и другие.

Water, Год журнала: 2025, Номер 17(2), С. 147 - 147

Опубликована: Янв. 8, 2025

Sorbents based on polyacrylonitrile fiber, containing ferrocyanides of transition metals and manganese oxides (CoMn-PAN FeMn-PAN) or iron(III) hydroxide (CoFe-PAN) in their structure were obtained, as confirmed by the results X-ray diffraction energy-dispersive analyses. The selectivity obtained sorbents was investigated, along with ability to sorb Cs, Ba (as an analog Ra), P, Be from various natural media, including river water seawater varying salinity 18.2 33.8 ‰. data show that are universal for recovery artificial 137Cs radionuclides environments, complex salt composition (seawater). Researching during marine expeditions efficiency materials metal sorption 137Cs, 7Be, 210Pb, 210Po, 226Ra, 228Ra, 234Th. Additionally, sorbent effective 32P, 33P, Based results, methods comprehensively determining using these developed.

Язык: Английский

Процитировано

0

New Sorbents Based on Polyacrylonitrile Fiber and Transition Metal Ferrocyanides for 137Cs Recovery from Various Composition Solutions DOI Creative Commons
Iuliia G. Shibetskaia,

Victoria A. Razina,

N. A. Bezhin

и другие.

Applied Sciences, Год журнала: 2024, Номер 14(2), С. 627 - 627

Опубликована: Янв. 11, 2024

For the first time, new sorbents based on polyacrylonitrile (PAN) fiber and transition metal ferrocyanides were obtained. The main difference between obtained existing ones is stage of preliminary preparation initial support by converting it into forms PAN-Fe(OH)3 or PAN-MnO2, due to which additional ion exchange groups (carboxyl, carbonyl, etc.) are formed, increases amount ferrocyanide fixed support. best components conditions for synthesis determined (concentration (0.1–0.2 mol/L), as well pH (1 PAN-Fe(OH)3, 1–5—PAN-MnO2) potassium solution, concentration salts (0.02 temperature conditions). influence studied solution composition (pH, Na+, K+, NH4+ ions) cesium distribution coefficients during its recovery was assessed. possibility from solutions with 1–9 containing macro quantities cations demonstrated. derived characterized modern structural methods such infrared spectroscopy, thermogravimetric analysis, scanning electron microscopy EDS analysis. A study trace sorption 137Cs carried out in comparison commercially available highly efficient (FNS-10 Termoksid-35), shown that resulting not inferior industrial can be used selective technological natural waters.

Язык: Английский

Процитировано

3

Silica-Reinforced AMP–Calcium Alginate Beads for Efficient and Selective Removal of Cesium from a Strong Acidic Medium DOI Creative Commons
Qiang Jin,

Xinya Diao,

Fan Ye

и другие.

ACS Omega, Год журнала: 2024, Номер 9(29), С. 32011 - 32020

Опубликована: Июль 12, 2024

Due to the significant selectivity for Cs

Язык: Английский

Процитировано

2

Novel and Sustainable Materials for the Separation of Lithium, Rubidium, and Cesium Ions from Aqueous Solutions in Adsorption Processes—A Review DOI Open Access
Małgorzata A. Kaczorowska

Materials, Год журнала: 2024, Номер 17(24), С. 6158 - 6158

Опубликована: Дек. 17, 2024

The growing demand for alkali metals (AMs), such as lithium, cesium, and rubidium, related to their wide application across various industries (e.g., electronics, medicine, aerospace, etc.) the limited resources of naturally occurring ores, has led an increased interest in methods recovery from secondary sources brines, wastewater, waste leachates). One dynamically developing research directions field separation AMs ions aqueous solutions is search novel, efficient, “green” materials that could be used adsorption processes, also on a larger industrial scale. This review concerns latest achievements (mainly 2023 2024) development innovative ion sieves, aluminum-based adsorbents, mineral composites, resins) Li+, Cs+, Rb+ solutions, with particular emphasis most important advantages limitations, well potential impact environment.

Язык: Английский

Процитировано

1

137Cs RECOVERY FROM DIFFERENT COMPOSITION SOLUTIONS BY FERROCYANIDE SORBENTS BASED ON POLYACRYLONITRILE FIBER DOI Open Access
Iuliia G. Shibetskaia, Viktoriia A. Razina, N. A. Bezhin

и другие.

Transaction Kola Science Centre, Год журнала: 2024, Номер 15(1), С. 448 - 453

Опубликована: Ноя. 28, 2024

Sorbents based on polyacrylonitrile (PAN) fiber and transition metal ferrocyanides were obtained. The influence of the studied solution composition (pH, concentration Na+, K+, NH4+ ions) cesium distribution coefficients during its recovery by obtained sorbents was assessed. A study trace amount sorption 137Cs carried out in comparison with commercially available highly efficient (FNS-10 Termoksid-35), it shown that resulting are not inferior to industrial ferrocyanide sorbents.

Язык: Английский

Процитировано

0