Applied Physics A, Год журнала: 2024, Номер 130(9)
Опубликована: Авг. 22, 2024
Язык: Английский
Applied Physics A, Год журнала: 2024, Номер 130(9)
Опубликована: Авг. 22, 2024
Язык: Английский
Inorganic Chemistry Communications, Год журнала: 2025, Номер unknown, С. 114686 - 114686
Опубликована: Май 1, 2025
Язык: Английский
Процитировано
0International Journal of Biological Macromolecules, Год журнала: 2025, Номер unknown, С. 144657 - 144657
Опубликована: Май 1, 2025
Язык: Английский
Процитировано
0Applied Sciences, Год журнала: 2025, Номер 15(11), С. 6236 - 6236
Опубликована: Июнь 1, 2025
This study examines a catalyst based on graphitic carbon nitride (g-C3N4) for synthesizing glycerol carbonate through the coupling reaction of and CO2. In this research, we focus simultaneously improving CO2 emission reduction valorization by co-doping g-C3N4 with phosphorus (P), sulfur (S), magnesium (Mg), lithium (Li) better catalytic performance. The catalysts were prepared one-step thermal condensation process characterized using XRD, SEM, TGA, FTIR, nitrogen adsorption–desorption techniques. further enhanced surface chemical properties, Lewis acidity, basicity, stability, evidenced lower crystallinity, wider pore, performance as assessed carbonylation reaction, optimized Box–Behnken design. MgPSCN exhibited highest conversion (68.72%) yield (44.90%) at 250 °C, 50 mg 10 bar pressure. model accuracy was validated ANOVA (R2 > 0.99; p values < 0.0001). results indicated that doping significantly performance, most likely due to improved electron charge transfer structural distortions within framework. Such highlights potential co-doped sustainable utilization scalable pathway toward green synthesis—an approach comes in line worldwide decarbonization goals.
Язык: Английский
Процитировано
0Applied Physics A, Год журнала: 2024, Номер 130(11)
Опубликована: Окт. 30, 2024
Язык: Английский
Процитировано
1Applied Physics A, Год журнала: 2024, Номер 130(9)
Опубликована: Авг. 22, 2024
Язык: Английский
Процитировано
0