Engineering in Life Sciences,
Год журнала:
2018,
Номер
18(7), С. 434 - 439
Опубликована: Апрель 16, 2018
Abstract
This
Mini
Review
gives
an
overview
of
and
respective
references
for
the
current
situation
regarding
global
phosphorus
reserves
legal
P
recovery
using
Germany
as
model.
Apart
from
well‐known
pilot
up
to
industrial/full
scale
techniques,
emerging
chemical
bio‐based
techniques
are
named
without
claiming
be
all‐encompassing.
Special
attention
is
paid
biological
systems
that
reveal
ways
use
renewable
resources
raw
materials.
A
few
chemically
based
like
AirPrex®,
(Ostara)PEARL™,
AshDec®,
RecoPhos®
have
already
been
used
recover
at
a
rate
quality
which
allows
its
sale
fertilizer.
Many
processes
stage
investigation
on
or
laboratory
scale,
e.g.
P‐RoC,
LeachPhos,
Mephrec®.
All
biologically
technologies
P‐Bac
still
early
research
show
promising
results.
Of
all
recovered
materials
struvite,
calcium
phosphate
bound
phosphorous
seem
best
plant
availability.
Although
there
no
ultimate
“one
fits
all”
technology,
potential
P‐recovery
operators
can
choose
wide
range
will
fit
local
material
availability,
economic
ecological
situation.
Journal of Environmental Quality,
Год журнала:
2019,
Номер
48(5), С. 1300 - 1313
Опубликована: Авг. 8, 2019
The
development
of
highly
concentrated
phosphorus
(P)
fertilizers,
such
as
triple
superphosphate,
by
the
Tennessee
Valley
Authority
helped
mark
beginning
a
revolution
in
way
we
manage
food
crop
nutrition.
Since
then,
scientists,
with
help
farmers,
have
made
great
advancements
understanding
P
fate
and
transport
across
many
environments
but
largely
failed
to
produce
new
generation
products
and/or
application
techniques
that
are
widely
accepted
vastly
improve
plant
acquisition
efficiency.
Under
certain
conditions,
important
been
made.
For
example,
applying
liquid
formulations
phosphates
lieu
dry
granules
some
calcareous
soils
has
dramatically
reduced
precipitation
sparingly
soluble
calcium
phosphate
minerals,
other
attempts,
co‐application
humic
substances,
sorption
layered
double
hydroxides,
or
use
nanoparticles,
not
generated
kind
results
necessary
continue
economically
increasing
yields
without
further
environmental
cost.
New
sources
fertility
will
need
be
affordable
produce,
transport,
furnish
soil
solution
manner
well
synchronized
demand.
This
paper
provides
review
recent
literature
on
cutting‐edge
fertilizer
technology.
goal
is
this
synthesis
used
starting
point
from
which
larger
discussion
responsible
nutrient
management
increased
efficiency
research
can
built.
Core
Ideas
Reaction
constituents
limits
availability
yield.
A
variety
approaches
being
explored.
Ideally,
should
More
innovation
along
mechanistic
field‐scale
trials
required.
Soil Science Society of America Journal,
Год журнала:
2020,
Номер
84(3), С. 653 - 671
Опубликована: Март 6, 2020
Abstract
The
low
water
solubility
of
struvite
is
thought
to
limit
its
agronomic
utility
as
a
phosphorus
(P)
fertilizer
compared
with
highly
soluble
P
fertilizers.
Furthermore,
struvite's
potential
complicated
by
hypothesized
soil
pH‐dependent
solubility,
crop‐specific
interactions,
and
limited
availability
struvite‐derived
N,
which
may
explain
conflicting
reports
crop
responses
conventional
A
systematic
literature
review
meta‐analysis
was
conducted
evaluate
the
effects
pH,
test
(STP),
rate,
particle
size,
N
on
aboveground
biomass,
concentration,
uptake,
uptake.
Struvite‐fertilized
plants
yielded
higher
uptake
ammonium
phosphates,
superphosphates
in
soils
pH
<
6
decreased
increasing
pH.
Crop
were
inversely
related
experiment
duration
mass
ratios
(d
kg
−1
)
used
greenhouse
studies,
opposite
benefit
more
roots
per
unit
dissolution.
proportion
total
applied
derived
from
increased
struvite‐P
application
rate
likely
due
reliance
slowly
available
struvite‐N.
potentially
overestimated
high
STP
and/or
rates
underestimated
limitation
large
proportions
struvite.
Evaluations
collectively
indicate
efficacy
affected
contribution
application.
Journal of Environmental Quality,
Год журнала:
2019,
Номер
48(5), С. 1247 - 1264
Опубликована: Авг. 15, 2019
Soil
phosphorus
(P)
cycling
in
agroecosystems
is
highly
complex,
with
many
chemical,
physical,
and
biological
processes
affecting
the
availability
of
P
to
plants.
Traditionally,
fertilizer
recommendations
have
been
made
using
an
insurance‐based
approach,
which
has
resulted
accumulation
intensively
managed
agricultural
soils
worldwide
contributed
widespread
water
quality
issue
eutrophication.
To
mitigate
further
environmental
degradation
because
future
supplies
are
threatened
due
finite
phosphate
rock
resources
associated
geopolitical
issues,
there
immediate
need
increase
use
efficiency
(PUE)
agroecosystems.
Through
cultivar
selection
improved
cropping
system
design,
contemporary
research
suggests
that
sufficient
crop
yields
could
be
maintained
at
reduced
soil
test
(STP)
concentrations.
In
addition,
more
efficient
field
scale
can
achieved
through
agroecosystem
management
increases
organic
matter
mineralization
optimizes
arbuscular
mycorrhizal
fungi
(AMF)
symbioses.
This
review
paper
provides
a
perspective
on
how
agriculture
potential
utilize
plant
microbial
traits
improve
PUE
accordingly,
maintain
lower
STP
It
also
links
tighten
cycle
regional
scale,
including
discussion
recovery
recycling
technologies,
particular
focus
struvite
as
recycled
fertilizer.
Guidance
directions
for
provided.
Core
Ideas
There
urgent
Crop
than
recommended
Both
quantity
influence
availability.
Further
ability
supply
crops
needed.
Struvite
fill
important
niche
recycling.
Environmental Engineering Science,
Год журнала:
2019,
Номер
36(5), С. 511 - 529
Опубликована: Март 7, 2019
Phosphorus
(P)
is
a
non-renewable
resource,
production
of
nitrogen
(N)
fertilizer
energy
intensive,
and
discharge
these
nutrients
in
treated
wastewater
causes
environmental
eutrophication.
Hence,
recovery
from
municipal
has
attracted
attention.
In
this
article,
current
technologies
for
such
are
reviewed,
with
synthesis
terms
characteristics,
goals,
effluent
limits,
constraints
on
chemical
usage,
treatment
plant
scale,
operational
complexity
applicability,
analysis
demands.
processes
applicable
centralized
plants
include
enhanced
biological
phosphorus
removal
(EBPR)
combined
electrochemical
struvite
precipitation
alone,
whereas
ion
exchange
(IE)
may
be
adapted
to
onsite
packaged
plants.
Many
can
used
N
concentration;
however,
been
reported
only
by
acid
absorption
following
separation
gas
stripping
or
permeable
membrane.
Only
produce
requiring
minimal
post-processing
beyond
filtration.
Electrochemical
calcium
phosphate
further
capable
addition.
Direct
microbiological
as
protein
an
emerging
technology,
algal
being
developed
livestock
fuel
production.
Although
reactive
filtration
achieve
very
low
P
concentrations,
the
individually
removing
secondary
below
10
μg/L,
example,
surficial
waters,
were
adsorption
IE.
Several
authors
point
EBPR
currently
preferred
approach,
development
appears
warranted.
ACS Sustainable Chemistry & Engineering,
Год журнала:
2017,
Номер
5(10), С. 9043 - 9052
Опубликована: Сен. 4, 2017
Monoammonium
phosphate
(MAP),
triple
superphosphate
(TSP),
and
phosphoric
acid
(H3PO4),
with
without
the
addition
of
magnesium
oxide
(MgO),
were
mixed
poultry
litter
(PL)
to
produce
biochar-based
fertilizers
(BBFs).
This
is
a
novel
approach
aiming
add
value
PL
residue
increase
P
use
efficiency
in
acidic
tropical
soils.
Samples
BBFs
assessed
by
P-release
kinetics
water,
X-ray
diffraction
(XRD),
Fourier
transform
infrared
spectroscopy
(FTIR),
bioassay
maize
greenhouse
using
clayey
Oxisol.
Addition
MgO
reduced
released
from
impregnated
all
sources.
XRD
analysis
showed
formation
low-solubility
Ca2P2O7
Mg2P207
compounds,
which
supported
P—O—P
or
P═O
stretching
observed
FTIR
spectra.
The
MgO-treated
increased
shoot
dry
matter
production
compared
control,
but
inferior
when
TSP
short
term.
slow
release
alkaline
reaction
show
great
potential
for
these
materials
be
used
as
enhanced
The Science of The Total Environment,
Год журнала:
2020,
Номер
756, С. 143726 - 143726
Опубликована: Ноя. 24, 2020
Production
of
struvite
(MgNH4PO4·6H2O)
from
waste
streams
is
increasingly
implemented
to
recover
phosphorus
(P),
which
listed
as
a
critical
raw
material
in
the
European
Union
(EU).
To
facilitate
EU-wide
trade
P-containing
secondary
materials
such
struvite,
EU
issued
revised
fertilizer
regulation
2019.
A
comprehensive
overview
supply
and
its
quality
presently
missing.
This
study
aimed:
i)
determine
current
production
volumes,
ii)
evaluate
all
legislated
physicochemical
characteristics
pathogen
content
against
newly
set
regulatory
limits,
iii)
compare
not-regulated
characteristics.
It
estimated
that
2020,
between
990
1250
ton
P
are
recovered
EU.
Struvite
24
plants,
accounting
for
30%
80
installations
worldwide
was
sampled.
Three
samples
failed
legal
limits;
one
had
<7%
three
exceeded
organic
carbon
3%
dry
weight
(DW).
Mineralogical
analysis
revealed
six
80–90%
DW,
13
>90%
DW.
All
showed
heavy
metal
below
limits.
Microbiological
analyses
indicated
may
exceed
certain
Differences
morphology
particle
size
distribution
were
observed
sourced
digestate
(rod
shaped;
transparent;
82
mass%
<
1
mm),
dewatering
liquor
(spherical;
opaque;
65
1–2
mm)
effluent
upflow
anaerobic
sludge
blanket
reactor
processing
potato
wastewater
51
mm
34
>
2
mm).
uniform
soil-plant
P-availability
pattern
3.5–6.5
mg
P/L
soil/d
over
28
days
sampling
period
observed.
No
differences
plant
biomass
yield
In
conclusion,
results
highlight
suitability
most
enter
market.