Harshly Oxidized Activated Charcoal Enhances Protein Persulfidation with Implications for Neurodegeneration as Exemplified by Friedreich’s Ataxia DOI Creative Commons
Anh Tran Tram Vo, Uzair Khan, Anton V. Liopo

и другие.

Nanomaterials, Год журнала: 2024, Номер 14(24), С. 2007 - 2007

Опубликована: Дек. 13, 2024

Harsh acid oxidation of activated charcoal transforms an insoluble carbon-rich source into water-soluble, disc structures graphene decorated with multiple oxygen-containing functionalities. We term these pleiotropic nano-enzymes as “pleozymes”. A broad redox potential spans many crucial reactions including the hydrogen sulfide (H2S) to polysulfides and thiosulfate, dismutation superoxide radical (O2−*), NADH NAD+. The H2S is predicted enhance protein persulfidation—the attachment sulfur cysteine residues. Persulfidated proteins act intermediates, persulfidation protects from irreversible ubiquitination, providing important means signaling. Protein believed decline in several neurological disorders aging. Importantly, consistent role signaling, master antioxidant transcription factor Nrf2 regulated by Keap1’s persulfidation. Here, we demonstrate that pleozymes increased overall cells apparently healthy individuals mitochondrial mutation responsible for Friedreich’s ataxia. further find specifically enhanced Keap1 persulfidation, subsequent accumulation Nrf2’s targets.

Язык: Английский

Neuroprotective signaling by hydrogen sulfide and its dysregulation in Alzheimer's disease DOI Creative Commons
Bindu D. Paul, Andrew A. Pieper

Current Opinion in Chemical Biology, Год журнала: 2024, Номер 82, С. 102511 - 102511

Опубликована: Авг. 13, 2024

The ancient messenger molecule hydrogen sulfide (H

Язык: Английский

Процитировано

9

Role of cystathionine-β-synthase and hydrogen sulfide in down syndrome DOI Creative Commons
Csaba Szabó

Neurotherapeutics, Год журнала: 2025, Номер unknown, С. e00584 - e00584

Опубликована: Апрель 1, 2025

Язык: Английский

Процитировано

0

Intracellular hydrogen sulfide induces stress granule formation and translational repression through eIF2α phosphorylation DOI
Sanae Kanno, Seishiro Hirano,

Jun Monma‐Otaki

и другие.

Archives of Toxicology, Год журнала: 2025, Номер unknown

Опубликована: Апрель 9, 2025

Язык: Английский

Процитировано

0

Increased hydrogen sulfide turnover serves a cytoprotective role during the development of replicative senescence DOI
Anna Kieronska‐Rudek, Kelly Ascenção, Stefan Chłopicki

и другие.

Biochemical Pharmacology, Год журнала: 2024, Номер unknown, С. 116595 - 116595

Опубликована: Окт. 1, 2024

Язык: Английский

Процитировано

3

Recent advances in the role of hydrogen sulfide in age-related diseases DOI

C. Zhang,

Yan Wang, Yuqing Jin

и другие.

Experimental Cell Research, Год журнала: 2024, Номер 441(2), С. 114172 - 114172

Опубликована: Июль 23, 2024

Язык: Английский

Процитировано

2

Emerging roles of hydrogen sulfide-metabolizing enzymes in cancer DOI Creative Commons
Alyaa Dawoud,

Rana A. Youness,

Kareem Elsayed

и другие.

Redox Report, Год журнала: 2024, Номер 29(1)

Опубликована: Дек. 6, 2024

Gasotransmitters play crucial roles in regulating many physiological processes, including cell signaling, cellular proliferation, angiogenesis, mitochondrial function, antioxidant production, nervous system functions and immune responses. Hydrogen sulfide (H2S) is the most recently identified gasotransmitter, which characterized by its biphasic behavior. At low concentrations, H2S promotes bioenergetics, whereas at high it can exert cytotoxic effects. Cystathionine β-synthetase (CBS), cystathionine-γ-lyase (CSE), 3-mercaptopyruvate sulfurtransferase (3-MST), cysteinyl-tRNA synthetase 2 (CARS2) are pivotal players biosynthesis mammalian cells tissues. The focus of this review regulation various pathways involved metabolism forms cancer. Key enzymes process include oxidation unit (SOU), includes sulfide:quinone oxidoreductase (SQOR), human ethylmalonic encephalopathy protein 1 (hETHE1), rhodanese, sulfite oxidase (SUOX/SO), cytochrome c (CcO) enzymes. Furthermore, potential role methylation processes mediated thiol S-methyltransferase (TMT) thioether (TEMT) outlined cancer biology, with opportunities for targeting them clinical translation. In order to understand oncogenesis tumor progression, one must appreciate intricate interplay between H2S-synthesizing H2S-catabolizing

Язык: Английский

Процитировано

2

Autophagy is a promising process for linking inflammation and redox homeostasis in Down syndrome DOI Creative Commons

Xuehai Ma,

Weimin Li,

Jun Ma

и другие.

Frontiers in Pharmacology, Год журнала: 2024, Номер 15

Опубликована: Окт. 2, 2024

Trisomy 21, characterized by the presence of an additional chromosome leads to a set clinical features commonly referred as Down syndrome (DS). The pathological phenotypes observed in DS are caused combination factors, such mitochondrial dysfunction, neuroinflammation, oxidative stress, disrupted metabolic patterns, and changes protein homeostasis signal transduction, these factors collectively induce neurological alterations. In DS, triplication 21 micronuclei arising from missegregation chromosomes closely associated with inflammation development redox imbalance. Autophagy, essential biological process that affects cellular homeostasis, is powerful tool facilitate degradation redundant or dysfunctional cytoplasmic components, thereby enabling recycling their constituents. Targeting autophagy has been suggested promising method balance intracellular stress improve dysfunction. this review, we summarize role regulating discuss crosslinks. A comprehensive elucidation roles offers novel insights for therapeutic strategies aimed at aneuploidy-associated diseases.

Язык: Английский

Процитировано

0

Harshly Oxidized Activated Charcoal Enhances Protein Persulfidation with Implications for Neurodegeneration as Exemplified by Friedreich’s Ataxia DOI Creative Commons
Anh Tran Tram Vo, Uzair Khan, Anton V. Liopo

и другие.

Nanomaterials, Год журнала: 2024, Номер 14(24), С. 2007 - 2007

Опубликована: Дек. 13, 2024

Harsh acid oxidation of activated charcoal transforms an insoluble carbon-rich source into water-soluble, disc structures graphene decorated with multiple oxygen-containing functionalities. We term these pleiotropic nano-enzymes as “pleozymes”. A broad redox potential spans many crucial reactions including the hydrogen sulfide (H2S) to polysulfides and thiosulfate, dismutation superoxide radical (O2−*), NADH NAD+. The H2S is predicted enhance protein persulfidation—the attachment sulfur cysteine residues. Persulfidated proteins act intermediates, persulfidation protects from irreversible ubiquitination, providing important means signaling. Protein believed decline in several neurological disorders aging. Importantly, consistent role signaling, master antioxidant transcription factor Nrf2 regulated by Keap1’s persulfidation. Here, we demonstrate that pleozymes increased overall cells apparently healthy individuals mitochondrial mutation responsible for Friedreich’s ataxia. further find specifically enhanced Keap1 persulfidation, subsequent accumulation Nrf2’s targets.

Язык: Английский

Процитировано

0