Catalytic Conversion of Carbon Dioxide to Propylene Carbonate: Catalyst Design and Industrialization Progress
Jun Wu,
Yaxuan Du,
Xiejun Wang
и другие.
ACS Catalysis,
Год журнала:
2025,
Номер
unknown, С. 1305 - 1340
Опубликована: Янв. 7, 2025
Converting
CO2
into
valuable
chemicals
is
an
effective
way
to
alleviate
the
high
level
of
global
CO2.
The
cycloaddition
reaction
and
propylene
oxide
(PO)
has
atomic
economy
advantage
environmental
friendliness
compared
with
traditional
phosgene
method
carbonate
(PC).
Due
chemical
inertness
CO2,
catalysts
are
needed
make
proceed
smoothly.
Through
rational
design,
a
multifunctional
catalyst
that
combines
activation
sites
attack
PO
adsorption
can
be
formed.
At
same
time,
use
harmful
substances
reduced
by
making
catalytic
process
more
environmentally
friendly.
In
this
work,
we
discuss
research
progress
synthesis
PC
from
PO.
Starting
mechanism,
system
summarized
perspective
design.
homogeneous
catalysts,
focus
on
effect
composition
performance.
heterogeneous
heterogenization
(preparation
methods),
including
supported,
confined,
polymerized
catalysts.
addition,
promising
photocatalysis
biomass
catalysis
especially
introduced.
Finally,
in
order
experimental
results
move
toward
industrial
production,
several
problems
existing
industrialization
discussed,
production
equipment,
influence
source,
product/catalyst
separation.
Язык: Английский
Hydroxyl-Functionalized Poly(triphenylimidazolinium bromide) as an Efficient Catalyst for the Cycloaddition of CO2 to Epoxides
Catalysis Letters,
Год журнала:
2025,
Номер
155(5)
Опубликована: Апрель 9, 2025
Язык: Английский
Solvent Free Ambient Pressure CO2 Cycloaddition Catalyzed by Cobalt‐Impregnated 2D‐Nanofibrous COFs
ChemSusChem,
Год журнала:
2024,
Номер
unknown
Опубликована: Ноя. 14, 2024
Abstract
Covalent
organic
frameworks
(COFs)
constitute
an
evolving
class
of
permanently
porous
and
ordered
materials,
they
have
recently
attracted
increased
interest
due
to
their
intriguing
morphological
features
numerous
applications
in
gas
storage,
adsorption,
catalysis.
However,
low
aqueous
stabilities
tedious
syntheses
generally
hamper
use
heterogeneous
Nonetheless,
a
capable
water‐stable
catalytic
system
for
coupling
CO
2
/epoxides
generate
industrially
important
cyclic
carbonates
is
still
great
interest.
Herein,
exceedingly
water‐
thermally
stable
2D‐cobalt‐impregnated
hydrazone‐linked
fibrous
COFs
are
reported
as
catalyst
/epoxide
reactions
at
ambient
pressure.
The
functionalized
cobalt
(Co)‐doped
demonstrated
excellent
activities
with
the
high
TONs
(80925)
TOFs
(6466
h
−1
),
outperforming
catalysts
We
found
that
Co
2+
ions
within
COF
matrix
catalyze
cycloaddition
through
density
functional
theory
calculations.
also
confirmed
structural
stability
consistent
activity
Co‐doped
up
ten
repeating
cycles.
Язык: Английский
Green Conversion of Epoxides to Cyclic Carbonates by Copper Nanocrystals Fabricated on Jute Tartaric Acid Composite Surface
Crystal Research and Technology,
Год журнала:
2024,
Номер
59(11)
Опубликована: Окт. 8, 2024
Abstract
The
synthesis
of
copper
nanocrystals
on
tartaric
acid
jute
composite
surface
is
reported.
formation
detected
by
FT
IR,
Powder
X‐ray
diffraction,
SEM,
and
TEM
analysis.
average
size
the
found
to
be
500
nm.
reaction
with
CO
2
resulted
in
a
decrease
nanoparticles.
Cycloaddition
epoxides
cyclic
carbonate
efficiently
carried
out
(CUNPJT)
without
using
any
cocatalyst
solvent.
To
best
author's
knowledge,
this
first
example
catalyzing
cycloaddition
epoxide.
Язык: Английский