Covalent Organic Frameworks (COFs) for CO2 Utilizations

Carbon Capture Science & Technology, Год журнала: 2025, Номер unknown, С. 100365 - 100365

Опубликована: Янв. 1, 2025

Язык: Английский

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Recent advances in photocatalytic CO2 cycloaddition reaction

Nano Research, Год журнала: 2024, Номер unknown

Опубликована: Сен. 11, 2024

Язык: Английский

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Pyrimidine-containing covalent organic frameworks for efficient photosynthesis of hydrogen peroxide via one-step two electron oxygen reduction process

Nano Research, Год журнала: 2024, Номер 17(11), С. 9498 - 9506

Опубликована: Авг. 17, 2024

Язык: Английский

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Photothermal CO2 conversion to cyclic carbonate over titanium-substituted polyoxometalate within covalent organic frameworks

Journal of Catalysis, Год журнала: 2024, Номер 442, С. 115908 - 115908

Опубликована: Дек. 19, 2024

Язык: Английский

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An Overview of Light-Assisted CO₂ Cycloaddition for Cyclic Carbonate: Paths of Photo-Induced Thermal-Catalysis, Photocatalysis and Photo-Thermal Synergistic Catalysis

Science for energy and environment., Год журнала: 2025, Номер unknown, С. 1 - 1

Опубликована: Янв. 6, 2025

Review An Overview of Light-Assisted CO2 Cycloaddition for Cyclic Carbonate: Paths Photo-Induced Thermal-Catalysis, Photocatalysis and Photo-Thermal Synergistic Catalysis Bin Zhu 1, Qichao Cao Xin Ding 1,*, Xiaolong Yang 1,2,* 1 School Chemistry Chemical Engineering, Qingdao University, 308 NingXia Road, 266071, China 2 State Key Laboratory Bio-Fibers Eco-Textiles, Collaborative Innovation Center Shandong Marine Bio-Based Fibers Ecological Textiles, * Correspondence: [email protected] (X.D.); [email protected] (X.Y.) Received: 4 November 2024; Revised: 6 January Accepted: 22 2025; Published: February 2026 Abstract: The increase concentration significantly results in severe greenhouse effect. Reducing emission chemically utilizing are effective means to solve this problem. cycloaddition reaction with epoxide is atomically economical environmentally friendly. However, current catalytic systems still have a long way go high efficiency under mild conditions. Solar energy has demonstrated excellent characteristics direct photothermal utilization, photocatalytic reactions, photoelectrochemical reactions recently. Therefore, herein review summarizes the research work on solar mediated past decade. Firstly, heat generated by effects confined local space can be more effectively absorbed molecules efficient greatly reducing consumption traditional thermal reactions. carbon-based materials, polyoxometalates (POM), metal organic frameworks (MOFs), covalent (COFs), ionic liquids (ILs) as catalysts reviewed analyzed; Secondly, semiconductor exhibit activity due activation reactants photogenerated charges holes. Single atom catalysts, composites, atomic clusters, MOFs, COFs, Porous polymers (POPs), others used such Finally, light synergistic catalysis system external heating synergy introduced analyzed. Last but not least, some issues development analyzed discussed, future prospects proposed basis.

Язык: Английский

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MOF-derived zinc and nickel bimetals grown on carbon fibers as efficient catalysts for synergistic photo-thermal catalytic CO2 cycloaddition

Molecular Catalysis, Год журнала: 2025, Номер 576, С. 114949 - 114949

Опубликована: Фев. 27, 2025

Язык: Английский

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Solvent-Free Preparation of Superhydrophobic and Photocatalytic Monoliths for Water Treatment Applications

Colloids and Surfaces A Physicochemical and Engineering Aspects, Год журнала: 2025, Номер unknown, С. 137227 - 137227

Опубликована: Май 1, 2025

Язык: Английский

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In Situ Reducible Ionic Frameworks for Dual‐Site and Photothermal Catalysis

Small, Год журнала: 2025, Номер unknown

Опубликована: Май 19, 2025

Abstract Ionic frameworks (IFs), characterized by ionic bonds and periodic framework structures, find extensive applications in several fields. However, the inherent high bond energy of often leads to formation close‐packed structures rather than open frameworks. Consequently, selection suitable building units is pivotal for successful synthesis IFs. Utilizing large size negative charge polyoxometalates (POMs), along with their combination metal cations, offers an effective approach constructing In this study, 2D IFs are fabricated using {Na 4 O 18 } cluster formed sodium ions Anderson‐type polyanions. Polyoxovanadates integrated into voids, resulting a uniform distribution two clusters. The catalytic performance evaluated through reactions, revealing that clusters act as dual‐site catalysts, thereby enhancing reaction efficiency. presence strong reductants, polyoxovanadates undergo partial reduction, inducing single‐crystal‐to‐single‐crystal transformation. reduced display pronounced photothermal conversion capabilities serve efficient photothermal‐catalytic agents cycloaddition epoxides carbon dioxide. This research not only enhances structural diversity achieves but also pioneeringly demonstrates situ reduction application near‐infrared catalysis.

Язык: Английский

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Exploring the role of ferric source in the structural regulation of ZIF-8 derived nitrogen-doped porous carbon for enhanced photothermal CO2 cycloaddition

Chemical Communications, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

Three ZIF-8 derived nitrogen-doped porous carbons were fabricated using an incorporation-pyrolysis process to study the impact of ferric source on photothermal catalytic activity for CO 2 cycloaddition.

Язык: Английский

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Construction of Au Plasmonic Nanoparticles Incorporated into Hierarchical UiO-66 via an In-Situ Pyrolysis for Enhanced Photo-thermal CO2 Cycloaddition

Applied Catalysis B Environment and Energy, Год журнала: 2025, Номер unknown, С. 125534 - 125534

Опубликована: Май 1, 2025

Язык: Английский

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