Biofuels Bioproducts and Biorefining, Год журнала: 2024, Номер unknown
Опубликована: Дек. 19, 2024
Abstract The behavior of biomass pyrolysis can be predicted by analyzing its characteristics. This study aimed to model the release volatiles across various temperatures, properties, and heating rates. Palm kernel shells were pyrolyzed at 433–773 K with a rate 5 K·min −1 using volatile‐state kinetic modeling. process began calculating type number ( N CT ), which was used determine volatile enhancement V E yield Y VY product i mass fraction y ). parameters, including activation energy for formation ai derived through fitting process. results indicate 70.77% within devolatilization zone, corresponding degradation cellulose hemicellulose. increased higher lower , ranged from 155–185 kJ·mol⁻¹ biocrude oil (BCO) 149–186 gas. parameters demonstrated errors below 0.2% in comparison experimental data, confirming model's accuracy reliability.
Язык: Английский