Chinese Journal of Structural Chemistry, Год журнала: 2024, Номер 43(8), С. 100350 - 100350
Опубликована: Май 22, 2024
Язык: Английский
Chinese Journal of Structural Chemistry, Год журнала: 2024, Номер 43(8), С. 100350 - 100350
Опубликована: Май 22, 2024
Язык: Английский
Angewandte Chemie International Edition, Год журнала: 2024, Номер 63(36)
Опубликована: Июнь 7, 2024
The creation of frustrated Lewis pairs on catalyst surface is an effective strategy for tuning CO
Язык: Английский
Процитировано
34Advanced Powder Materials, Год журнала: 2024, Номер unknown, С. 100243 - 100243
Опубликована: Сен. 1, 2024
Язык: Английский
Процитировано
26EnergyChem, Год журнала: 2024, Номер 6(5), С. 100130 - 100130
Опубликована: Июль 16, 2024
Язык: Английский
Процитировано
20Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 160238 - 160238
Опубликована: Фев. 1, 2025
Язык: Английский
Процитировано
5Molecular Catalysis, Год журнала: 2025, Номер 578, С. 114978 - 114978
Опубликована: Март 6, 2025
Язык: Английский
Процитировано
4Applied Catalysis B Environment and Energy, Год журнала: 2025, Номер 371, С. 125275 - 125275
Опубликована: Март 18, 2025
Язык: Английский
Процитировано
4Advanced Functional Materials, Год журнала: 2025, Номер unknown
Опубликована: Янв. 10, 2025
Abstract Reducing carbon dioxide (CO 2 )to high‐value products using green renewable energy is a promising approach for addressing and greenhouse effect issues. Consequently, electrocatalytic CO reduction reaction (CO RR) technology has become current research hotspot. Since the discovery of high activity selectivity copper in RR, atomically dispersed Cu catalysts have garnered widespread attention due to their efficient atom utilization, unique electronic structure, outstanding catalytic performance. However, great challenge remains providing rational catalyst design principles achieve regulation product distribution. A clear understanding materials an in‐depth interpretation mechanism as well elucidation strategy progress toward different are keys building solving above problem. Therefore, this review starts with introduction advanced characterization techniques reveal structure mechanisms. Then, various optimization strategies applications producing targeted summarized discussed. Finally, perspectives on RR field future development offered.
Язык: Английский
Процитировано
3New Journal of Chemistry, Год журнала: 2024, Номер 48(19), С. 8933 - 8962
Опубликована: Янв. 1, 2024
Nanostructured materials are widely researched for energy applications like solar cells, catalysts, batteries, and graphene-based due to their high surface area, favorable transport properties, tunable physical attributes, confinement effects at the nanoscale.
Язык: Английский
Процитировано
18Small, Год журнала: 2024, Номер unknown
Опубликована: Апрель 30, 2024
Abstract Photocatalytic CO 2 reduction technology, capable of converting low‐density solar energy into high‐density chemical energy, stands as a promising approach to alleviate the crisis and achieve carbon neutrality. Semiconductor metal oxides, characterized by their abundant reserves, good stability, easily tunable structures, have found extensive applications in field photocatalysis. However, wide bandgap inherent oxides contributes poor efficiency photocatalytic reduction. Defect engineering presents an effective strategy address these challenges. This paper reviews research progress defect enhance performance summarizing classifications, preparation methods, characterization techniques. The focus is on engineering, represented vacancies doping, for improving oxide photocatalysts. includes advancements expanding photoresponse range, enhancing photogenerated charge separation, promoting molecule activation. Finally, provides summary current issues challenges faced along with prospective outlook future development technology.
Язык: Английский
Процитировано
18Advanced Functional Materials, Год журнала: 2024, Номер unknown
Опубликована: Окт. 29, 2024
Abstract Ethylene (C 2 H 4 ) electrosynthesis from the electrocatalytic CO reduction process holds enormous potential applications in industrial production. However, sluggish kinetics of C─C coupling often result low yield and poor selectivity for C Herein, performance Cu catalysts varying sizes is investigated, prepared via a cryo‐mediated liquid phase exfoliation technique, electrochemical to . The activity gradually increase as size decreases tens nanometers few nanometers. Impressively, 5 nm quantum dots (Cu‐5) achieve maximum Faradaic efficiency (FE) 81.5% half‐cell cathodic energy (CEE) 42.2% with large partial current density 1.1 A cm −2 at −0.93 V versus reversible hydrogen electrode. Structural characterization situ spectroscopic analysis reveal that Cu‐5 dots, dominated by (100) facet, provide an abundance active sites enhance adsorption activation, promoting formation *CO intermediates. accumulation intermediates on facilitates CO‐CHO reaction, thus enhancing production rate.
Язык: Английский
Процитировано
15