Revolutionizing Micro‐Scale Energy Storage by 0D Carbon Nanostructures: Synthesis, Integration, Performance Optimization Mechanisms and Sustainable Applications DOI Creative Commons

Fazal Ul Nisa,

Muhammad Tahir, S. Khalid

и другие.

Advanced Functional Materials, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 19, 2024

Abstract The micro‐scale energy storage devices (MESDs) have experienced significant revolutions driven by developments in micro‐supercapacitors (MSCs) and micro‐batteries (MBs). This review summarizes the advancements of MSC MB architecture, highlighting electrode–electrolyte designs emergence alkali metal ions aqueous batteries. performance synthesis carbon quantum dots (CQDs), graphene (GQDs), their synergistic effects for applications are investigated. focus is on integrating CQDs/GQDs into MESDs enhanced performance. development compositing CQD/GQD with other materials, reveals capacitive pseudocapacitive performance, extending MESDs’ possibilities. Moreover, this systematically covers various fabrication techniques from photolithography to printing techniques. merits practicality each technique fabricating MSCs MBs assessed. Electrochemical evaluation, capacitance enhancement, charge–discharge kinetics, stability assessments presented demonstrate efficiency practical applications. Despite progress, challenges remain, particularly scalability understanding long‐term stability. Nevertheless, prospects promising, avenues synthesis, fabrication, electrochemical which lead a paradigm shift MESDs. offers broad perspective, combining innovations across diverse domains directing frontline microelectronics.

Язык: Английский

Sweat Gland‐Like Fabric for Personal Thermal‐Wet Comfort Management DOI
Qian Zhang, Manyu Wang, Tao Chen

и другие.

Advanced Functional Materials, Год журнала: 2024, Номер unknown

Опубликована: Июль 19, 2024

Abstract The sweat evaporation strategy has shown great potential for passive cooling of the human body. However, accumulation at skin resulting from hindrance by traditional fabrics increases heat load and causes clothing to stick skin. Sweat textiles that perform sweat‐wicking function glands are thus highly desirable. Here, a gland‐like (Sg‐like) fabric is proposed personal thermal‐wet comfort management. Sg‐like channels formed in through spraying ultrasonic welding processes can pull liquid water spread it out over outer layer rapid evaporation. design principle also well‐validated based on colored fabrics. In artificial sweating demonstrations, temperature covered with comparable bare lower than commercial textiles. body tests, reduction ≈2 °C observed coated compare skin‐coated cotton. It expected this work offers promising guidelines developing sweat‐evaporation textile meet requirements

Язык: Английский

Процитировано

10
High Density 3D Carbon Tube Nanoarray Electrode Boosting the Capacitance of Filter Capacitor DOI Creative Commons

Gan Chen,

Fangming Han, Huachun Ma

и другие.

Nano-Micro Letters, Год журнала: 2024, Номер 16(1)

Опубликована: Июль 3, 2024

Electric double-layer capacitors (EDLCs) with fast frequency response are regarded as small-scale alternatives to the commercial bulky aluminum electrolytic capacitors. Creating carbon-based nanoarray electrodes precise alignment and smooth ion channels is crucial for enhancing EDLCs' performance. However, controlling density of macropore-dominated poses challenges in boosting capacitance line-filtering EDLCs. Herein, a simple technique finely adjust vertical-pore diameter inter-spacing three-dimensional nanoporous anodic oxide (3D-AAO) template achieved, 3D compactly arranged carbon tube (3D-CACT) nanoarrays created symmetrical EDLCs using 3D-AAO template-assisted chemical vapor deposition carbon. The 3D-CACT demonstrate high surface area 253.0 m

Язык: Английский

Процитировано

8
Effect of MXene Nanosheet Sticking on Supercapacitor Device Performance DOI Creative Commons
Mariya Aleksandrova, Nikolay Kurtev, И. М. Пандиев

и другие.

Applied Sciences, Год журнала: 2024, Номер 14(6), С. 2452 - 2452

Опубликована: Март 14, 2024

Supercapacitors have garnered significant interest in recent years due to their high power density, rapid charge/discharge rates, and long cycle life. MXenes, a family of two-dimensional (2D) transition metal carbides/nitrides, emerged as promising electrode materials for supercapacitors. However, one major challenge associated with incorporating MXenes supercapacitor structures is the occurrence sticking, wherein individual MXene flakes agglomerate, leading reduced performance. This review paper discusses various causes sticking approaches preventing it, offering insights into design development high-performance MXene-based The morphology size flakes, flake surface chemistry, thickness, area/volume ratio, processing techniques (including solvent selection, additives incorporation, deposition technology), environmental factors were shown be basic resulting sheets. Among strategies mitigate this challenge, functionalization passivation, integration polymer matrices or carbon nanomaterials, optimization considered. Possible paths future directions study, such novel compositions, understanding interfaces electrode–electrolyte interactions, advanced architectures, energy storage systems, assumed.

Язык: Английский

Процитировано

5
Amorphization‐Driven RhRu Bimetallene Enhances Water Dissociation Kinetics DOI
Jiandong Wu, Manman Liu, Jinchang Fan

и другие.

Advanced Functional Materials, Год журнала: 2024, Номер unknown

Опубликована: Июль 21, 2024

Abstract Phase engineering holds great promise in enhancing the functionalities of nanomaterials by enabling precise control over their phase and morphology. However, achieving this level synthesis remains a significant challenge. In study, highly amorphous RhRu (a‐RhRu) bimetallene using one‐pot wet‐chemical approach is presented. The introduction structure allows for optimization electron configurations overall a‐RhRu. This catalyst demonstrates exceptional activity alkaline hydrogen evolution reaction, with low overpotential 32 mV at 10 mA cm −2 high turnover frequency (TOF) 3.06 H 2 s −1 an 50 mV, surpassing performance most reported Rh‐based electrocatalysts. findings underscore potential strategies electrocatalysis.

Язык: Английский

Процитировано

4
Photolithographic Microfabrication of Microbatteries for On-Chip Energy Storage DOI Creative Commons
Yuan Ma, Sen Wang,

Zhong-Shuai Wu

и другие.

Nano-Micro Letters, Год журнала: 2025, Номер 17(1)

Опубликована: Янв. 8, 2025

Abstract Microbatteries (MBs) are crucial to power miniaturized devices for the Internet of Things. In evolutionary journey MBs, fabrication technology emerges as cornerstone, guiding intricacies their configuration designs, ensuring precision, and facilitating scalability mass production. Photolithography stands out an ideal technology, leveraging its unparalleled resolution, exceptional design flexibility, entrenched position within mature semiconductor industry. However, comprehensive reviews on application in MB development remain scarce. This review aims bridge that gap by thoroughly assessing recent status promising prospects photolithographic microfabrication MBs. Firstly, we delve into fundamental principles step-by-step procedures photolithography, offering a nuanced understanding operational mechanisms criteria photoresist selection. Subsequently, highlighted specific roles photolithography including utilization template creating micropatterns, protective layer during etching process, mold soft lithography, constituent active component, sacrificial construction micro-Swiss-roll structure. Finally, concludes with summary key challenges future perspectives MBs fabricated providing insights sparking research inspiration this field.

Язык: Английский

Процитировано

0
Bamboo‐Inspired Hierarchically Hollow Aerogel MXene Fibers with Ultrafast Ionic Channels and Multiple Electromagnetic Wave Attenuation Routes Toward High‐Performance Supercapacitors and Microwave Absorption DOI Open Access
Wenhui Zhang,

Shouyu Ren,

Yongzhe Zhang

и другие.

Small, Год журнала: 2025, Номер unknown

Опубликована: Янв. 13, 2025

Abstract 2D materials feature large specific surface areas and abundant active sites, showing great potential in energy storage conversion. However, the dense, stacked structure severely restricts its practical application. Inspired by of bamboo nature, hollow interior porous exterior wall, MXene aerogel fiber (HA‐Ti 3 C 2 T X fiber) is proposed. Owing to continuous microstructure optimized cavity, this possesses accessible area ions structural defects, leading a fast charge transfer kinetics high faradic activity. Consequently, HA‐Ti exhibits exceptional gravimetric capacitance 355 F g −1 . Besides, solid‐state asymmetric fiber‐shaped supercapacitors (FSCs) display 276 density 9.58 Wh kg Additionally, delivers outstanding electromagnetic wave (EMW) absorption performance with minimum reflection loss −52.39 dB effective bandwidth up 4.6 GHz, which attributed multiple paths, strong dielectric from structure. This novel design provides new reference for construction advanced fibers EMW materials.

Язык: Английский

Процитировано

0
The morphology-dependent on the electrochemical performance of molybdenum trioxide in supercapacitors DOI
Hui Zhao, Ziwei Chen, Yuanhao Li

и другие.

Vacuum, Год журнала: 2025, Номер unknown, С. 114179 - 114179

Опубликована: Фев. 1, 2025

Язык: Английский

Процитировано

0
One-Step Synthesis of Large-Micropores Dominated Hierarchical Porous Carbons by Aminobenzoic Acid for High Performance Supercapacitor Electrodes DOI
Xiaocui Wang, Zhenhu Li, Yang Tian

и другие.

Опубликована: Янв. 1, 2025

Язык: Английский

Процитировано

0
Organic Radical-Boosted Ionic Conductivity in Redox Polymer Electrolyte for Advanced Fiber-Shaped Energy Storage Devices DOI Creative Commons

Jeong-Gil Kim,

Jaehyoung Ko, Hyung‐Kyu Lim

и другие.

Nano-Micro Letters, Год журнала: 2025, Номер 17(1)

Опубликована: Март 13, 2025

Abstract Fiber-shaped energy storage devices (FSESDs) with exceptional flexibility for wearable power sources should be applied solid electrolytes over liquid due to short circuits and leakage issue during deformation. Among the options, polymer are particularly preferred their robustness flexibility, although low ionic conductivity remains a significant challenge. Here, we present redox electrolyte (HT_RPE) 4-hydroxy-2,2,6,6-tetramethylpiperidine-1-oxyl (HT) as multi-functional additive. HT acts plasticizer that transforms glassy state into rubbery improved chain mobility provides distinctive ion conduction pathway by self-exchange reaction between radical oxidized species. These synergetic effects lead high (73.5 mS cm −1 ) based on lower activation of 0.13 eV than other additives. Moreover, HT_RPE pseudocapacitive characteristic enables an outstanding electrochemical performance symmetric FSESDs using carbon-based fiber electrodes (energy density 25.4 W h kg at 25,000 without typical active materials, along excellent stability (capacitance retention 91.2% after 8,000 bending cycles). This work highlights versatile utilizes unique functionality both capability, providing promising next-generation flexible devices.

Язык: Английский

Процитировано

0
High-performance flexible zinc–air batteries enabled by carboxymethyl cellulose/graphene oxide composite hydrogel electrolytes DOI
Xianqiang Qu, Na Xu,

Lina Zhao

и другие.

New Journal of Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

CMC/PAM/GO hydrogel enables flexible Zn–air batteries via GO-enhanced H-bonding/crosslinking. With 350% strain and 71.6% water retention, it suppresses dendrites/dehydration. 68.7 mW cm −2 (KI) 30 h stability (KCl) for wearables.

Язык: Английский

Процитировано

0