Journal of Materials Chemistry C,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 1, 2025
The
superelastic
partially
rGO
aerogel
with
multi-stage
pores
exhibits
a
remarkable
RL
min
of
−67.89
dB
and
an
expanded
EAB
7.72
GHz,
combining
outstanding
mechanical
properties,
hydrophobicity,
thermal
insulation
piezoresistive
sensing.
Advanced Functional Materials,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 28, 2025
Abstract
Excessive
electromagnetic
pollution
caused
by
waves
can
interfere
with
the
normal
use
of
electronic
devices
or
cause
unnecessary
damage
to
human
health.
Although
conductive
polymer
composites
(CPCs)
are
used
replace
traditional
metals
as
an
effective
strategy
for
managing
undesirable
waves,
CPCs
have
a
non‐negligible
trade‐off
in
enhancement
interference
(EMI)
shielding
effectiveness
and
absorption
coefficient
because
their
reflection‐dominated
EMI
mechanism.
Therefore,
alleviate
secondary
pollution,
absorption‐dominated
asymmetric
structures
urgently
needed.
Recently,
structural
designs
advanced
significantly,
but
seldom
been
summarized
discussed
detail.
Consequently,
this
review
first
systematically
summarizes
current
progress
after
brief
clarification
about
necessity
configuration
structure
design.
Afterward,
various
fiber,
layered,
porous,
composite
described.
Besides,
versatility
is
briefly
introduced.
Finally,
challenges
prospects
proposed
guide
future
advancement
field.
Nano-Micro Letters,
Год журнала:
2025,
Номер
17(1)
Опубликована: Апрель 14, 2025
Abstract
Enhancing
the
firefighting
protective
clothing
with
exceptional
thermal
barrier
and
temperature
sensing
functions
to
ensure
high
fire
safety
for
firefighters
has
long
been
anticipated,
but
it
remains
a
major
challenge.
Herein,
inspired
by
human
muscle,
an
anisotropic
aerogel
(ACMCA)
precise
self-actuated
monitoring
performance
is
developed
combining
aramid
nanofibers
eicosane/MXene
form
anisotropically
oriented
conductive
network.
By
two
synergies
of
negative
temperature-dependent
eicosane,
which
induces
high-temperature
differential,
directionally
ordered
MXene
that
establishes
network
along
directional
freezing
direction.
The
resultant
ACMCA
exhibited
remarkable
thermoelectric
properties,
S
values
reaching
46.78
μV
K
−1
κ
as
low
0.048
W
m
at
room
temperature.
Moreover,
prepared
electrical
responsiveness
variations,
facilitating
its
application
in
intelligent
systems.
designed
could
be
incorporated
into
layer,
demonstrating
wide
range
(50–400
°C)
rapid
response
time
early
alerts
(~
1.43
s).
This
work
provides
novel
insights
design
temperature-sensitive
clothing.
Abstract
With
the
advent
of
5G
era,
there
has
been
a
marked
increase
in
research
interest
concerning
electromagnetic
wave‐absorbing
materials.
A
critical
challenge
remains
improving
properties
these
materials
while
satisfying
diverse
application
demands.
MXenes,
identified
as
prominent
“emerging”
2D
for
wave
absorption,
offer
unique
advantages
that
are
expected
to
drive
advancements
and
innovations
this
field.
This
review
emphasizes
synthesis
benefits
provided
by
structural
characteristics
MXenes
performance
enhancements
achieved
through
their
combination
with
other
absorbing
Material
requirements,
approaches,
conceptual
frameworks
integrated
underscore
advantages.
The
study
provides
thorough
analysis
MXene‐absorbing
composites,
going
beyond
basic
classification
address
preparation
modification
processes
affecting
absorption
composites.
Attention
is
directed
techniques,
design
principles,
influence
on
composite
performance.
Additionally,
potential
applications
devices
summarized.
concludes
addressing
challenges
currently
confronting
MXene
outlining
developmental
trends,
aiming
guidance
subsequent
domain.
Efficient
microwave
absorbers
are
needed
to
address
the
electromagnetic
pollution
caused
by
proliferation
of
new
radio
technologies
and
equipment.
Excellent
absorption
performance
can
be
achieved
controlling
dielectric
constant.
Heteroatom-doped
bimetallic
materials
promising
wave
(EMA)
due
their
tunable
structures
low
cost.
In
particular,
presence
anionic
sites
significantly
affects
constant
electrical
conductivity.
Herein,
a
one-dimensional
carbon
nanofiber
material
is
prepared
encapsulating
FeCo
nanoparticles
in
fiber
cavity
electrostatic
spinning.
Subsequently,
tellurization,
vulcanization,
selenization
processes
carried
out.
FeTe2/
CoTe2@C
exhibits
stronger
conductivity
loss
lower
electronegativity
Te.
The
clever
configuration
FeTe2,
CoTe2,
C
heterostructures
obtained
Te
doping
generates
multi-heterogeneous
interfaces
that
facilitate
charge
migration
enhance
loss,
optimizing
EMA
performance.
FeTe2/CoTe2@C
an
optimum
minimum
reflection
(RLmin)
−51.1
dB
with
matching
thickness
2.0
mm,
effective
bandwidth
(EAB)
reaches
4.2
GHz.
Radar
cross-section
(RCS)
calculations
show
great
potential
for
practical
military
stealth
technology.
This
study
offers
novel
guidance
improving
properties
transition
metal
matrix
composites
via
coordination
modulation.
ACS Applied Materials & Interfaces,
Год журнала:
2025,
Номер
unknown
Опубликована: Март 20, 2025
Graphene
has
been
one
of
the
most
widely
explored
two-dimensional
(2D)
assemblies
due
to
its
outstanding
mechanical,
electrical,
and
thermal
properties
resulting
from
unique
characteristics
high
anisotropy
strong
carbon-carbon
bonds.
Aerogels,
characterized
by
their
ultralow
density
ultrahigh
specific
surface
area,
stand
out
as
leading
porous
materials.
Therefore,
integration
graphene
aerogels
would
boost
development
multifunctional
Among
various
methods
for
fabrication
aerogels,
ice-templating
received
significant
interest
ecofriendly
nature
a
physical
process,
broad
applicability
across
material
systems,
proficiency
in
constructing
abundant
structures
multifunctionalities.
Consequently,
become
prevalent
technique
efficient
assembly
nanosheets
into
with
inherited
graphene,
multifunctionality
derived
diverse
constituents,
well-controlled
architecture.
In
this
review,
we
systematically
summarize
progress
ice-templated
graphene-based
aerogels.
Initially,
introduce
process
these
elaborating
each
step
precursor
preparation
freezing,
drying,
post-treatment.
Subsequently,
demonstrate
applications
macroarchitectures
microstructures.
Finally,
review
concludes
straightforward
summary,
highlighting
challenges
opportunities
associated
This
systematic
aims
offer
new
insights
design
innovative
multiscale
architecture
multifunctionalities,
which
are
crucial
variety
engineering
applications.
Abstract
Efficient
microwave
absorbers
are
needed
to
address
the
electromagnetic
pollution
caused
by
proliferation
of
new
radio
technologies
and
equipment.
Excellent
absorption
performance
can
be
achieved
controlling
dielectric
constant.
Heteroatom‐doped
bimetallic
materials
promising
wave
(EMA)
due
their
tunable
structures
low
cost.
In
particular,
presence
anionic
sites
significantly
affects
constant
electrical
conductivity.
Herein,
a
1D
carbon
nanofiber
material
is
prepared
encapsulating
FeCo
nanoparticles
in
fiber
cavity
electrostatic
spinning.
Subsequently,
tellurization,
vulcanization,
selenization
processes
carried
out.
FeTe
2
/
CoTe
@C
exhibits
stronger
conductivity
loss
lower
electronegativity
Te.
The
clever
configuration
,
C
heterostructures
obtained
Te
doping
generates
multi‐heterogeneous
interfaces
that
facilitate
charge
migration
enhance
interfacial
polarization,
obtaining
excellent
EMA
performance.
/CoTe
an
optimum
minimum
reflection
(RL
min
)
−51.1
dB
with
matching
thickness
2.0
mm,
effective
bandwidth
(EAB)
reaches
4.2
GHz.
Radar
cross‐section
(RCS)
calculations
show
great
potential
for
practical
military
stealth
technology.
This
study
offers
novel
guidance
improving
properties
transition
metal
matrix
composites
via
coordination
modulation.