Inorganic Chemistry Frontiers,
Год журнала:
2024,
Номер
11(13), С. 3786 - 3798
Опубликована: Янв. 1, 2024
Medium-entropy
oxides
are
commonly
employed
as
electrocatalysts
for
the
oxygen
evolution
reaction
(OER)
in
electrolysers
aimed
at
producing
sustainable
hydrogen.
Advanced Energy Materials,
Год журнала:
2024,
Номер
14(30)
Опубликована: Май 27, 2024
Abstract
Electrochemical
water
splitting
is
a
promising
technique
for
the
production
of
high‐purity
hydrogen.
Substituting
slow
anodic
oxygen
evolution
reaction
with
an
oxidation
that
thermodynamically
more
favorable
enables
energy‐efficient
Moreover,
this
approach
facilitates
degradation
environmental
pollutants
and
synthesis
value‐added
chemicals
through
rational
selection
small
molecules
as
substrates.
Strategies
small‐molecule
electrocatalyst
design
are
critical
to
electrocatalytic
performance,
focus
on
achieving
high
current
density,
selectivity,
Faradaic
efficiency,
operational
durability.
This
perspective
discusses
key
factors
required
further
advancement,
including
technoeconomic
analysis,
new
reactor
system
design,
meeting
requirements
industrial
applications,
bridging
gap
between
fundamental
research
practical
product
detection
separation.
aims
advance
development
hybrid
electrolysis
applications.
Current Opinion in Green and Sustainable Chemistry,
Год журнала:
2024,
Номер
47, С. 100932 - 100932
Опубликована: Май 3, 2024
The
scientific
and
industrial
communities
worldwide
have
recently
achieved
impressive
technical
advances
in
developing
innovative
electrocatalysts
electrolysers
for
water
seawater
splitting.
viability
of
electrolysis
commercial
applications,
however,
remains
elusive,
the
key
barriers
are
durability,
cost,
performance,
materials,
manufacturing,
system
simplicity,
especially
with
regard
to
running
on
practical
sources
like
seawater.
This
paper,
therefore,
primarily
aims
provide
a
concise
overview
most
recent
disruptive
water-splitting
technologies
materials
that
could
reshape
future
green
hydrogen
production.
Starting
from
fundamentals,
durable
efficient
modern
types
electrolysers,
such
as
decoupled
unconventional
hybrid
been
represented
precisely
annotated
this
report.
Outlining
splitting,
paper
can
help
quick
guide
identifying
gap
knowledge
while
pointing
out
solutions
cost-effective
production
meet
zero-carbon
targets
short
near
term.
Advanced Materials,
Год журнала:
2024,
Номер
36(31)
Опубликована: Июнь 6, 2024
Abstract
Water
electrolysis
to
produce
hydrogen
(H
2
)
using
renewable
energy
is
one
of
the
most
promising
candidates
for
realizing
carbon
neutrality,
but
its
reaction
kinetics
hindered
by
sluggish
anodic
oxygen
evolution
(OER).
Ruthenium
(Ru)
in
high‐valence
state
(oxide)
provides
active
OER
sites
and
less
costly,
thermodynamically
unstable.
The
strong
interaction
between
Ru
nanoparticles
(NPs)
nickel
hydroxide
(Ni(OH)
leveraged
directly
form
Ru–Ni(OH)
on
surface
a
porous
foam
(NF)
electrode
via
spontaneous
galvanic
replacement
reaction.
formation
Ru─O─Ni
bonds
at
interface
NPs
Ni(OH)
(Ru–Ni(OH)
oxidized
NF
significantly
enhance
stability
/NF
electrode.
In
addition
OER,
catalyst
enough
(HER).
As
result,
it
able
deliver
overpotentials
228
15
mV
reach
10
mA
cm
−2
HER,
respectively.
An
industry‐scale
evaluation
as
both
HER
electrodes
demonstrates
high
current
density
1500
(OER:
410
mV;
HER:
240
mV),
surpassing
commercial
RuO
600
mV)
Pt/C
based
performance
(HER:
265
mV).
Journal of the American Chemical Society,
Год журнала:
2024,
Номер
146(29), С. 20251 - 20262
Опубликована: Июль 12, 2024
A
strain
engineering
strategy
is
crucial
for
designing
a
high-performance
catalyst.
However,
how
to
control
the
in
metastable
phase
two-dimensional
(2D)
materials
technically
challenging
due
their
nanoscale
sizes.
Here,
we
report
that
cerium
dioxide
(CeO